Preparation method and application of photocatalytic olefin fluorine-containing group functionalized anthraquinone-based metal organic framework photocatalyst
The invention belongs to the technical field of photocatalytic materials, and relates to a preparation method and application of an anthraquinone-based metal organic framework photocatalyst oriented to photocatalysis olefin fluorine-containing group functionalization. According to the preparation me...
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| creator | WANG YING DUAN CHUNYING LI MOCHEN MA LINWANG ZHANG TIEXIN |
| description | The invention belongs to the technical field of photocatalytic materials, and relates to a preparation method and application of an anthraquinone-based metal organic framework photocatalyst oriented to photocatalysis olefin fluorine-containing group functionalization. According to the preparation method, triazolyl anthraquinone AQN-triazole is used as a ligand, Zn < 2 + > in metal zinc salt is used as a metal node, the anthraquinone-based metal organic framework photocatalyst oriented to photocatalysis olefin fluorine-containing group functionalization is prepared through a solvothermal method, and the synthesis route of the anthraquinone-based metal organic framework photocatalyst is as follows: AQN-triazole + Zn < 2 + >-Zn-AQN-triazole; the preparation method is simple, the obtained photocatalyst material fuses a catalytic active center anthraquinone photosensitizer and a metal node Zn Lewis acid, and some fluorine-containing groups which are difficult to reduce participate in a free radical reaction by inc |
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| subjects | ACYCLIC OR CARBOCYCLIC COMPOUNDS CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY CHEMISTRY COMPOSITIONS BASED THEREON HETEROCYCLIC COMPOUNDS MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONSONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS METALLURGY ORGANIC CHEMISTRY ORGANIC MACROMOLECULAR COMPOUNDS PERFORMING OPERATIONS PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL THEIR PREPARATION OR CHEMICAL WORKING-UP THEIR RELEVANT APPARATUS TRANSPORTING |
| title | Preparation method and application of photocatalytic olefin fluorine-containing group functionalized anthraquinone-based metal organic framework photocatalyst |
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