Catalyst, preparation method thereof and method for synthesizing cumene hydroperoxide through oxidation of cumene by using catalyst

The invention discloses a catalyst, a preparation method and a method for synthesizing cumene hydroperoxide through cumene oxidation, the catalyst is a zinc oxide/copper oxide composite catalyst derived from a metal organic framework, and the catalyst can be used for a reaction for synthesizing cume...

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Hauptverfasser: TIAN YU, YU GENHAI, LI TENG, KIM JEONG-SOON, KONG XIANGMING, ZOU WENYI
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creator TIAN YU
YU GENHAI
LI TENG
KIM JEONG-SOON
KONG XIANGMING
ZOU WENYI
description The invention discloses a catalyst, a preparation method and a method for synthesizing cumene hydroperoxide through cumene oxidation, the catalyst is a zinc oxide/copper oxide composite catalyst derived from a metal organic framework, and the catalyst can be used for a reaction for synthesizing cumene hydroperoxide through cumene oxidation. Compared with single copper-based and zinc-based catalysts, the solid catalyst disclosed by the invention has the advantages of higher reaction conversion rate, high selectivity of the reaction product cumene hydroperoxide and the like, few byproducts are generated in the reaction, and the solid catalyst is long in service life and long in service cycle. 本发明公开了一种催化剂、制备方法及其用于异丙苯氧化合成异丙苯过氧化氢的方法,所述催化剂为金属有机框架衍生的氧化锌/氧化铜复合催化剂,本发明的催化剂可用于异丙苯氧化合成异丙苯过氧化氢的反应。本发明的固体催化剂与单独的铜基、锌基催化剂相比具有反应转化率较高,反应产物异丙苯过氧化氢选择性高等优势,同时反应产生的副产物少,固体催化剂寿命长、使用周期长。
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subjects ACYCLIC OR CARBOCYCLIC COMPOUNDS
CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY
CHEMISTRY
METALLURGY
ORGANIC CHEMISTRY
PERFORMING OPERATIONS
PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
THEIR RELEVANT APPARATUS
TRANSPORTING
title Catalyst, preparation method thereof and method for synthesizing cumene hydroperoxide through oxidation of cumene by using catalyst
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