Method for treating salt-containing unsymmetrical dimethylhydrazine production wastewater

The invention relates to the field of unsymmetrical dimethylhydrazine wastewater treatment, and discloses a method for treating high-salt-content unsymmetrical dimethylhydrazine production wastewater, which comprises the following steps: (1) adjusting the pH value of the salt-containing unsymmetrica...

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Bibliographische Detailangaben
Hauptverfasser: DONG ZHENHAI, ZHANG LIJUN, TIAN HONGCHAO, ZHOU BAOYUE, WU JUNLIANG, YAO HUIQIANG
Format: Patent
Sprache:chi ; eng
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Zusammenfassung:The invention relates to the field of unsymmetrical dimethylhydrazine wastewater treatment, and discloses a method for treating high-salt-content unsymmetrical dimethylhydrazine production wastewater, which comprises the following steps: (1) adjusting the pH value of the salt-containing unsymmetrical dimethylhydrazine production wastewater and the concentration of a homogeneous catalyst, so that the adjusted wastewater is acidic, and the concentration of metal ions of the homogeneous catalyst is more than or equal to 50mg/L; (2) mixing the adjusted wastewater with hydrogen peroxide for catalytic oxidation; (3) adsorbing the oxidation liquid subjected to catalytic oxidation by using resin to recover the homogeneous catalyst; and (4) denitrifying the permeate liquid adsorbed by the resin. 本发明涉及偏二甲肼废水处理领域,公开了一种处理高含盐偏二甲肼生产废水的方法,其中,该方法包括:(1)将含盐偏二甲肼生产废水进行pH及均相催化剂浓度调节,使得调节后的废水呈酸性且均相催化剂金属离子的浓度≥50mg/L;(2)将调节后的废水与过氧化氢混合进行催化氧化;(3)经催化氧化后的氧化液采用树脂吸附回收均相催化剂;(4)将树脂吸附的透过液进行脱氮。