Pentanuclear copper (I) complex with core-shell-like structure as well as preparation method and application of pentanuclear copper (I) complex
The invention relates to a pentanuclear copper (I) complex with a core-shell-like structure and a preparation method and application thereof.The molecular formula of the pentanuclear copper (I) complex with the core-shell-like structure is [C112H82Cu5S4N22P4] PF6, and the molecular weight is 2469.78...
Gespeichert in:
| Hauptverfasser: | , , , , , , , , |
|---|---|
| Format: | Patent |
| Sprache: | chi ; eng |
| Schlagworte: | |
| Online-Zugang: | Volltext bestellen |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | |
|---|---|
| container_issue | |
| container_start_page | |
| container_title | |
| container_volume | |
| creator | YANG HONGZHI HUANG JINGJING YIN GUOJIE ZHANG BIN ZHANG YUYONG QIN FENG LIU ZUCHUANG QI CHEN DU CHENXIA |
| description | The invention relates to a pentanuclear copper (I) complex with a core-shell-like structure and a preparation method and application thereof.The molecular formula of the pentanuclear copper (I) complex with the core-shell-like structure is [C112H82Cu5S4N22P4] PF6, and the molecular weight is 2469.78. The preparation method comprises the steps that a pyridoimidazole diphosphine ligand L and an auxiliary ligand 1-phenyl-1H-tetrazole-5-mercaptan are added into a mixed solvent of CH2Cl2 and CH3OH, stirring is conducted for 1-2 h, and the pentanuclear copper (I) complex with the core-shell-like structure is obtained; uniformly stirring to obtain a mixed solution; adding [Cu (CH3CN) 4] PF6 into the mixed solution, stirring at normal temperature, filtering into a culture bottle, and slowly volatilizing filtrate in the culture bottle at room temperature to obtain transparent faint yellow crystals; and washing the obtained crystal with absolute ethyl alcohol, and performing vacuum drying. The preparation method is mil |
| format | Patent |
| fullrecord | <record><control><sourceid>epo_EVB</sourceid><recordid>TN_cdi_epo_espacenet_CN116947892A</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>CN116947892A</sourcerecordid><originalsourceid>FETCH-epo_espacenet_CN116947892A3</originalsourceid><addsrcrecordid>eNqNjbEKwjAYhLs4iPoOv5sOHaqidpSi6CIO7uUnXmkwTX6SlPoWvrIVncXh-O6OgxsmzwtsZNsqA_aknAg8zU7z3jZi8KBOx7oPHmmoYUxq9B0Uom9VbD2IA3V9_aZ4CHuO2llqEGt3I7a9RIxWn9pVJL__xsmgYhMw-XKUTA_7a3FMIa5EEFawiGVxzrJ1vtps88Vu-c_mBeX7Tnk</addsrcrecordid><sourcetype>Open Access Repository</sourcetype><iscdi>true</iscdi><recordtype>patent</recordtype></control><display><type>patent</type><title>Pentanuclear copper (I) complex with core-shell-like structure as well as preparation method and application of pentanuclear copper (I) complex</title><source>esp@cenet</source><creator>YANG HONGZHI ; HUANG JINGJING ; YIN GUOJIE ; ZHANG BIN ; ZHANG YUYONG ; QIN FENG ; LIU ZUCHUANG ; QI CHEN ; DU CHENXIA</creator><creatorcontrib>YANG HONGZHI ; HUANG JINGJING ; YIN GUOJIE ; ZHANG BIN ; ZHANG YUYONG ; QIN FENG ; LIU ZUCHUANG ; QI CHEN ; DU CHENXIA</creatorcontrib><description>The invention relates to a pentanuclear copper (I) complex with a core-shell-like structure and a preparation method and application thereof.The molecular formula of the pentanuclear copper (I) complex with the core-shell-like structure is [C112H82Cu5S4N22P4] PF6, and the molecular weight is 2469.78. The preparation method comprises the steps that a pyridoimidazole diphosphine ligand L and an auxiliary ligand 1-phenyl-1H-tetrazole-5-mercaptan are added into a mixed solvent of CH2Cl2 and CH3OH, stirring is conducted for 1-2 h, and the pentanuclear copper (I) complex with the core-shell-like structure is obtained; uniformly stirring to obtain a mixed solution; adding [Cu (CH3CN) 4] PF6 into the mixed solution, stirring at normal temperature, filtering into a culture bottle, and slowly volatilizing filtrate in the culture bottle at room temperature to obtain transparent faint yellow crystals; and washing the obtained crystal with absolute ethyl alcohol, and performing vacuum drying. The preparation method is mil</description><language>chi ; eng</language><subject>ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAININGELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN,SULFUR, SELENIUM OR TELLURIUM ; ADHESIVES ; CHEMISTRY ; DYES ; ELECTRICITY ; MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FORELSEWHERE ; METALLURGY ; MISCELLANEOUS APPLICATIONS OF MATERIALS ; MISCELLANEOUS COMPOSITIONS ; NATURAL RESINS ; ORGANIC CHEMISTRY ; PAINTS ; POLISHES</subject><creationdate>2023</creationdate><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://worldwide.espacenet.com/publicationDetails/biblio?FT=D&date=20231027&DB=EPODOC&CC=CN&NR=116947892A$$EHTML$$P50$$Gepo$$Hfree_for_read</linktohtml><link.rule.ids>230,308,780,885,25563,76418</link.rule.ids><linktorsrc>$$Uhttps://worldwide.espacenet.com/publicationDetails/biblio?FT=D&date=20231027&DB=EPODOC&CC=CN&NR=116947892A$$EView_record_in_European_Patent_Office$$FView_record_in_$$GEuropean_Patent_Office$$Hfree_for_read</linktorsrc></links><search><creatorcontrib>YANG HONGZHI</creatorcontrib><creatorcontrib>HUANG JINGJING</creatorcontrib><creatorcontrib>YIN GUOJIE</creatorcontrib><creatorcontrib>ZHANG BIN</creatorcontrib><creatorcontrib>ZHANG YUYONG</creatorcontrib><creatorcontrib>QIN FENG</creatorcontrib><creatorcontrib>LIU ZUCHUANG</creatorcontrib><creatorcontrib>QI CHEN</creatorcontrib><creatorcontrib>DU CHENXIA</creatorcontrib><title>Pentanuclear copper (I) complex with core-shell-like structure as well as preparation method and application of pentanuclear copper (I) complex</title><description>The invention relates to a pentanuclear copper (I) complex with a core-shell-like structure and a preparation method and application thereof.The molecular formula of the pentanuclear copper (I) complex with the core-shell-like structure is [C112H82Cu5S4N22P4] PF6, and the molecular weight is 2469.78. The preparation method comprises the steps that a pyridoimidazole diphosphine ligand L and an auxiliary ligand 1-phenyl-1H-tetrazole-5-mercaptan are added into a mixed solvent of CH2Cl2 and CH3OH, stirring is conducted for 1-2 h, and the pentanuclear copper (I) complex with the core-shell-like structure is obtained; uniformly stirring to obtain a mixed solution; adding [Cu (CH3CN) 4] PF6 into the mixed solution, stirring at normal temperature, filtering into a culture bottle, and slowly volatilizing filtrate in the culture bottle at room temperature to obtain transparent faint yellow crystals; and washing the obtained crystal with absolute ethyl alcohol, and performing vacuum drying. The preparation method is mil</description><subject>ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAININGELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN,SULFUR, SELENIUM OR TELLURIUM</subject><subject>ADHESIVES</subject><subject>CHEMISTRY</subject><subject>DYES</subject><subject>ELECTRICITY</subject><subject>MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FORELSEWHERE</subject><subject>METALLURGY</subject><subject>MISCELLANEOUS APPLICATIONS OF MATERIALS</subject><subject>MISCELLANEOUS COMPOSITIONS</subject><subject>NATURAL RESINS</subject><subject>ORGANIC CHEMISTRY</subject><subject>PAINTS</subject><subject>POLISHES</subject><fulltext>true</fulltext><rsrctype>patent</rsrctype><creationdate>2023</creationdate><recordtype>patent</recordtype><sourceid>EVB</sourceid><recordid>eNqNjbEKwjAYhLs4iPoOv5sOHaqidpSi6CIO7uUnXmkwTX6SlPoWvrIVncXh-O6OgxsmzwtsZNsqA_aknAg8zU7z3jZi8KBOx7oPHmmoYUxq9B0Uom9VbD2IA3V9_aZ4CHuO2llqEGt3I7a9RIxWn9pVJL__xsmgYhMw-XKUTA_7a3FMIa5EEFawiGVxzrJ1vtps88Vu-c_mBeX7Tnk</recordid><startdate>20231027</startdate><enddate>20231027</enddate><creator>YANG HONGZHI</creator><creator>HUANG JINGJING</creator><creator>YIN GUOJIE</creator><creator>ZHANG BIN</creator><creator>ZHANG YUYONG</creator><creator>QIN FENG</creator><creator>LIU ZUCHUANG</creator><creator>QI CHEN</creator><creator>DU CHENXIA</creator><scope>EVB</scope></search><sort><creationdate>20231027</creationdate><title>Pentanuclear copper (I) complex with core-shell-like structure as well as preparation method and application of pentanuclear copper (I) complex</title><author>YANG HONGZHI ; HUANG JINGJING ; YIN GUOJIE ; ZHANG BIN ; ZHANG YUYONG ; QIN FENG ; LIU ZUCHUANG ; QI CHEN ; DU CHENXIA</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-epo_espacenet_CN116947892A3</frbrgroupid><rsrctype>patents</rsrctype><prefilter>patents</prefilter><language>chi ; eng</language><creationdate>2023</creationdate><topic>ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAININGELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN,SULFUR, SELENIUM OR TELLURIUM</topic><topic>ADHESIVES</topic><topic>CHEMISTRY</topic><topic>DYES</topic><topic>ELECTRICITY</topic><topic>MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FORELSEWHERE</topic><topic>METALLURGY</topic><topic>MISCELLANEOUS APPLICATIONS OF MATERIALS</topic><topic>MISCELLANEOUS COMPOSITIONS</topic><topic>NATURAL RESINS</topic><topic>ORGANIC CHEMISTRY</topic><topic>PAINTS</topic><topic>POLISHES</topic><toplevel>online_resources</toplevel><creatorcontrib>YANG HONGZHI</creatorcontrib><creatorcontrib>HUANG JINGJING</creatorcontrib><creatorcontrib>YIN GUOJIE</creatorcontrib><creatorcontrib>ZHANG BIN</creatorcontrib><creatorcontrib>ZHANG YUYONG</creatorcontrib><creatorcontrib>QIN FENG</creatorcontrib><creatorcontrib>LIU ZUCHUANG</creatorcontrib><creatorcontrib>QI CHEN</creatorcontrib><creatorcontrib>DU CHENXIA</creatorcontrib><collection>esp@cenet</collection></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext_linktorsrc</fulltext></delivery><addata><au>YANG HONGZHI</au><au>HUANG JINGJING</au><au>YIN GUOJIE</au><au>ZHANG BIN</au><au>ZHANG YUYONG</au><au>QIN FENG</au><au>LIU ZUCHUANG</au><au>QI CHEN</au><au>DU CHENXIA</au><format>patent</format><genre>patent</genre><ristype>GEN</ristype><title>Pentanuclear copper (I) complex with core-shell-like structure as well as preparation method and application of pentanuclear copper (I) complex</title><date>2023-10-27</date><risdate>2023</risdate><abstract>The invention relates to a pentanuclear copper (I) complex with a core-shell-like structure and a preparation method and application thereof.The molecular formula of the pentanuclear copper (I) complex with the core-shell-like structure is [C112H82Cu5S4N22P4] PF6, and the molecular weight is 2469.78. The preparation method comprises the steps that a pyridoimidazole diphosphine ligand L and an auxiliary ligand 1-phenyl-1H-tetrazole-5-mercaptan are added into a mixed solvent of CH2Cl2 and CH3OH, stirring is conducted for 1-2 h, and the pentanuclear copper (I) complex with the core-shell-like structure is obtained; uniformly stirring to obtain a mixed solution; adding [Cu (CH3CN) 4] PF6 into the mixed solution, stirring at normal temperature, filtering into a culture bottle, and slowly volatilizing filtrate in the culture bottle at room temperature to obtain transparent faint yellow crystals; and washing the obtained crystal with absolute ethyl alcohol, and performing vacuum drying. The preparation method is mil</abstract><oa>free_for_read</oa></addata></record> |
| fulltext | fulltext_linktorsrc |
| identifier | |
| ispartof | |
| issn | |
| language | chi ; eng |
| recordid | cdi_epo_espacenet_CN116947892A |
| source | esp@cenet |
| subjects | ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAININGELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN,SULFUR, SELENIUM OR TELLURIUM ADHESIVES CHEMISTRY DYES ELECTRICITY MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FORELSEWHERE METALLURGY MISCELLANEOUS APPLICATIONS OF MATERIALS MISCELLANEOUS COMPOSITIONS NATURAL RESINS ORGANIC CHEMISTRY PAINTS POLISHES |
| title | Pentanuclear copper (I) complex with core-shell-like structure as well as preparation method and application of pentanuclear copper (I) complex |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-08T13%3A35%3A44IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-epo_EVB&rft_val_fmt=info:ofi/fmt:kev:mtx:patent&rft.genre=patent&rft.au=YANG%20HONGZHI&rft.date=2023-10-27&rft_id=info:doi/&rft_dat=%3Cepo_EVB%3ECN116947892A%3C/epo_EVB%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true |