Method for preparing sodium carbonate and ammonium sulfate from sodium sulfate by thermal method

The invention provides a method for preparing sodium carbonate and ammonium sulfate from sodium sulfate by a thermal method, which comprises the following steps: (1) mixing sodium sulfate, a solvent, ammonium bicarbonate or mixed gas of ammonia gas and carbon dioxide, and carrying out double decompo...

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Hauptverfasser: FAN BINGQIANG, SHEN CHANGSHUAI, CHEN PEISONG, ZHANG YANG, ZHENG SHILI, WANG YANHUI, ZHANG HEDONG, ZHANG JING
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creator FAN BINGQIANG
SHEN CHANGSHUAI
CHEN PEISONG
ZHANG YANG
ZHENG SHILI
WANG YANHUI
ZHANG HEDONG
ZHANG JING
description The invention provides a method for preparing sodium carbonate and ammonium sulfate from sodium sulfate by a thermal method, which comprises the following steps: (1) mixing sodium sulfate, a solvent, ammonium bicarbonate or mixed gas of ammonia gas and carbon dioxide, and carrying out double decomposition reaction to obtain sodium bicarbonate and double decomposition mother liquor; calcining the sodium bicarbonate to obtain sodium carbonate; (2) heating the double-decomposition mother liquor obtained in the step (1) to obtain ammonia gas, carbon dioxide and ammonium sulfate-rich mother liquor; the ammonia gas and the carbon dioxide are reused in the step (1); (3) carrying out evaporative crystallization on the ammonium sulfate-rich mother liquor obtained in the step (2) to obtain mixed salt, and carrying out particle grading on the mixed salt to obtain ammonium sulfate and sodium sulfate; the sodium sulfate is reused in the step (1). According to the method, high-valued sodium carbonate and ammonium sulfate p
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subjects AMMONIA
CHEMISTRY
COMPOUNDS OF ALKALI METALS, i.e. LITHIUM, SODIUM, POTASSIUM,RUBIDIUM, CAESIUM, OR FRANCIUM
COMPOUNDS THEREOF
CYANOGEN
INORGANIC CHEMISTRY
METALLURGY
title Method for preparing sodium carbonate and ammonium sulfate from sodium sulfate by thermal method
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