Metal modified covalent organic framework material as well as preparation method and application thereof
The invention discloses a metal modified covalent organic framework material as well as a preparation method and application thereof, and belongs to the technical field of piezoelectric catalysis. The covalent organic framework material of the metal modified covalent organic framework material is sy...
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| creator | LIU WEIQI LIAN QIYU CAO JING JIAO YIMU XU GUIZHI XIA DEHUA LIANG ZHUOCHENG |
| description | The invention discloses a metal modified covalent organic framework material as well as a preparation method and application thereof, and belongs to the technical field of piezoelectric catalysis. The covalent organic framework material of the metal modified covalent organic framework material is synthesized by using 5, 5 '-diamino-2, 2'-dipyridyl and 2, 4, 6-triformyl phloroglucinol as precursors, the metal is modified to obtain the metal modified covalent organic framework material, and the metal comprises one or more of antimony, molybdenum, chromium, calcium, magnesium, manganese and barium. The metal-modified covalent organic framework M-TfpBpy-COF can generate charge shift after deformation under the stimulation of mechanical vibration, water oxidation and oxygen reduction reaction are simultaneously carried out at the active center of the material surface to generate hydrogen peroxide, the adjustability and selectivity of the covalent organic framework structure provide rich sites for metal loading, an |
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The metal-modified covalent organic framework M-TfpBpy-COF can generate charge shift after deformation under the stimulation of mechanical vibration, water oxidation and oxygen reduction reaction are simultaneously carried out at the active center of the material surface to generate hydrogen peroxide, the adjustability and selectivity of the covalent organic framework structure provide rich sites for metal loading, an</description><language>chi ; eng</language><subject>CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY ; CHEMISTRY ; COMPOSITIONS BASED THEREON ; COMPOUNDS THEREOF ; INORGANIC CHEMISTRY ; MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONSONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS ; METALLURGY ; NON-METALLIC ELEMENTS ; ORGANIC MACROMOLECULAR COMPOUNDS ; PERFORMING OPERATIONS ; PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL ; THEIR PREPARATION OR CHEMICAL WORKING-UP ; THEIR RELEVANT APPARATUS ; TRANSPORTING</subject><creationdate>2023</creationdate><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://worldwide.espacenet.com/publicationDetails/biblio?FT=D&date=20230725&DB=EPODOC&CC=CN&NR=116478354A$$EHTML$$P50$$Gepo$$Hfree_for_read</linktohtml><link.rule.ids>230,308,776,881,25543,76294</link.rule.ids><linktorsrc>$$Uhttps://worldwide.espacenet.com/publicationDetails/biblio?FT=D&date=20230725&DB=EPODOC&CC=CN&NR=116478354A$$EView_record_in_European_Patent_Office$$FView_record_in_$$GEuropean_Patent_Office$$Hfree_for_read</linktorsrc></links><search><creatorcontrib>LIU WEIQI</creatorcontrib><creatorcontrib>LIAN QIYU</creatorcontrib><creatorcontrib>CAO JING</creatorcontrib><creatorcontrib>JIAO YIMU</creatorcontrib><creatorcontrib>XU GUIZHI</creatorcontrib><creatorcontrib>XIA DEHUA</creatorcontrib><creatorcontrib>LIANG ZHUOCHENG</creatorcontrib><title>Metal modified covalent organic framework material as well as preparation method and application thereof</title><description>The invention discloses a metal modified covalent organic framework material as well as a preparation method and application thereof, and belongs to the technical field of piezoelectric catalysis. 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| subjects | CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY CHEMISTRY COMPOSITIONS BASED THEREON COMPOUNDS THEREOF INORGANIC CHEMISTRY MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONSONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS METALLURGY NON-METALLIC ELEMENTS ORGANIC MACROMOLECULAR COMPOUNDS PERFORMING OPERATIONS PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL THEIR PREPARATION OR CHEMICAL WORKING-UP THEIR RELEVANT APPARATUS TRANSPORTING |
| title | Metal modified covalent organic framework material as well as preparation method and application thereof |
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