Cellulose-based battery diaphragm with flame retardant property and preparation method thereof

The invention discloses a cellulose-based battery diaphragm with flame retardant property and a preparation method thereof. The preparation method comprises the following steps: adding cellulose and a polyvinyl alcohol solution into a sodium hydroxide/urea/aqueous solution, stirring and dissolving,...

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Hauptverfasser: JANG DO-HWAN, LI CHENCHEN, LUO XIAOGANG, LIU GENYAN, MIAO WENWEN, FAN YULIN, XIAO JIAN, WU FENGSHOU
Format: Patent
Sprache:chi ; eng
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Zusammenfassung:The invention discloses a cellulose-based battery diaphragm with flame retardant property and a preparation method thereof. The preparation method comprises the following steps: adding cellulose and a polyvinyl alcohol solution into a sodium hydroxide/urea/aqueous solution, stirring and dissolving, then carrying out ultrasonic dispersion and centrifugation, casting the obtained membrane casting solution on a substrate, obtaining a gelatinous sheet through a tape casting method, then sequentially immersing the gelatinous sheet into a coagulating bath for curing and regeneration and washing in deionized water, and drying to obtain the cellulose/urea composite membrane. And then loading nano aluminum oxide on the surface of the wet membrane by adopting a suction filtration mode, washing, and carrying out vacuum freeze drying to obtain the flame-retardant cellulose-based composite membrane. The battery diaphragm prepared by the invention has excellent flame retardant property, good mechanical property, thermal st