Sulfide electrolyte, preparation method and application thereof

The invention discloses a sulfide electrolyte, a preparation method and application thereof, and belongs to the technical field of solid-state batteries, the molecular formula of the sulfide electrolyte is as follows: Li < 7 > P < 2-x > M < x > S < 8-y > O < y > X, X is...

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Hauptverfasser: BIE XIAOFEI, ZHAI XIMIN, JIANG TAO
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creator BIE XIAOFEI
ZHAI XIMIN
JIANG TAO
description The invention discloses a sulfide electrolyte, a preparation method and application thereof, and belongs to the technical field of solid-state batteries, the molecular formula of the sulfide electrolyte is as follows: Li < 7 > P < 2-x > M < x > S < 8-y > O < y > X, X is one or more of F, Cl, Br and I; m is one or more of As, Bi and Sb, x is more than or equal to 0.01 and less than or equal to 1, and the ratio of x to y is 2: 5. According to the invention, the M element is adopted to replace a part of P element in the sulfide electrolyte, and the O element is adopted to replace a part of S element in the sulfide electrolyte, so that the electrolyte with higher air stability and higher ion mobility is obtained, and the air stability and high pressure resistance of the sulfide solid electrolyte are improved; the lithium stability is improved, the ionic conductivity is increased, and the problems that the structure is changed and the ionic conductivity is reduced due to irreversible chemical reaction between the
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According to the invention, the M element is adopted to replace a part of P element in the sulfide electrolyte, and the O element is adopted to replace a part of S element in the sulfide electrolyte, so that the electrolyte with higher air stability and higher ion mobility is obtained, and the air stability and high pressure resistance of the sulfide solid electrolyte are improved; the lithium stability is improved, the ionic conductivity is increased, and the problems that the structure is changed and the ionic conductivity is reduced due to irreversible chemical reaction between the</abstract><oa>free_for_read</oa></addata></record>
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subjects BASIC ELECTRIC ELEMENTS
CHEMISTRY
COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSESC01D OR C01F
ELECTRICITY
INORGANIC CHEMISTRY
METALLURGY
PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSIONOF CHEMICAL INTO ELECTRICAL ENERGY
title Sulfide electrolyte, preparation method and application thereof
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