Potassium-doped sodium-manganese-iron-based Prussian white material as well as preparation method and application thereof

The invention discloses a potassium-doped sodium-manganese-iron-based Prussian white material as well as a preparation method and application thereof. The chemical formula of the material is NaxKyMn [Fe (CN) 6] z-1-z.nH2O (x + y is greater than or equal to 1 and less than or equal to 2, z is greater...

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Hauptverfasser: LIU YAN, LI MING, MING XIANQUAN, NA CHANG-RI, LI CHUNLIU, LI GUILIANG, LI WEIJIAN, YANG MAOFENG, BI WEINING, HUANG GUANHAN, WU XUEHANG, LI JUNJI, HUANG BINGXING, LI CHUNXIA, WU WENWEI
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creator LIU YAN
LI MING
MING XIANQUAN
NA CHANG-RI
LI CHUNLIU
LI GUILIANG
LI WEIJIAN
YANG MAOFENG
BI WEINING
HUANG GUANHAN
WU XUEHANG
LI JUNJI
HUANG BINGXING
LI CHUNXIA
WU WENWEI
description The invention discloses a potassium-doped sodium-manganese-iron-based Prussian white material as well as a preparation method and application thereof. The chemical formula of the material is NaxKyMn [Fe (CN) 6] z-1-z.nH2O (x + y is greater than or equal to 1 and less than or equal to 2, z is greater than or equal to 0 and less than or equal to 0.2, n is greater than or equal to 0 and less than or equal to 5, and represents a [Fe (CN) 6] 4-vacancy defect). The potassium-doped sodium-manganese-iron-based Prussian white is prepared by taking manganese salt, sodium citrate, sodium ferrocyanide and potassium ferrocyanide as raw materials through a coprecipitation method. The potassium doping amount can be regulated and controlled by changing the proportion of sodium ferricyanide to potassium ferrocyanide in the raw materials. The NaxKyMn [Fe (CN) 6] z-1-z.nH2O is a two-phase compound and has a sodium-based Prussian white phase (NaxMn [Fe (CN) 6] z-1-z.nH2O) and a potassium-based Prussian white phase (KyMn [Fe (CN)
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The chemical formula of the material is NaxKyMn [Fe (CN) 6] z-1-z.nH2O (x + y is greater than or equal to 1 and less than or equal to 2, z is greater than or equal to 0 and less than or equal to 0.2, n is greater than or equal to 0 and less than or equal to 5, and represents a [Fe (CN) 6] 4-vacancy defect). The potassium-doped sodium-manganese-iron-based Prussian white is prepared by taking manganese salt, sodium citrate, sodium ferrocyanide and potassium ferrocyanide as raw materials through a coprecipitation method. The potassium doping amount can be regulated and controlled by changing the proportion of sodium ferricyanide to potassium ferrocyanide in the raw materials. 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The chemical formula of the material is NaxKyMn [Fe (CN) 6] z-1-z.nH2O (x + y is greater than or equal to 1 and less than or equal to 2, z is greater than or equal to 0 and less than or equal to 0.2, n is greater than or equal to 0 and less than or equal to 5, and represents a [Fe (CN) 6] 4-vacancy defect). The potassium-doped sodium-manganese-iron-based Prussian white is prepared by taking manganese salt, sodium citrate, sodium ferrocyanide and potassium ferrocyanide as raw materials through a coprecipitation method. The potassium doping amount can be regulated and controlled by changing the proportion of sodium ferricyanide to potassium ferrocyanide in the raw materials. The NaxKyMn [Fe (CN) 6] z-1-z.nH2O is a two-phase compound and has a sodium-based Prussian white phase (NaxMn [Fe (CN) 6] z-1-z.nH2O) and a potassium-based Prussian white phase (KyMn [Fe (CN)</abstract><oa>free_for_read</oa></addata></record>
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subjects AMMONIA
BASIC ELECTRIC ELEMENTS
CHEMISTRY
COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSESC01D OR C01F
COMPOUNDS THEREOF
CYANOGEN
ELECTRICITY
INORGANIC CHEMISTRY
METALLURGY
PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSIONOF CHEMICAL INTO ELECTRICAL ENERGY
title Potassium-doped sodium-manganese-iron-based Prussian white material as well as preparation method and application thereof
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