Oxalate synthesis catalyst
A new type Pd-Zr/Al2O3 catalyst for synthesizing oxalate is developed by using Zr as adjuvant and adopting pickling process. Said invention adopts a fixed-bed reactor, and uses said catalyst in gas-phase catalytic synthesis reaction of oxalate by using carbonic oxide and nitrous acid ester. In the c...
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creator | CUNPING HUANG BINGKAI ZHANG TINGHUANG GUO |
description | A new type Pd-Zr/Al2O3 catalyst for synthesizing oxalate is developed by using Zr as adjuvant and adopting pickling process. Said invention adopts a fixed-bed reactor, and uses said catalyst in gas-phase catalytic synthesis reaction of oxalate by using carbonic oxide and nitrous acid ester. In the course of carbon monoxide catalytic coupling reaction to synthesize dimethyl oxalate and diethyl oxalate said catalyst possesses highest reactive activity, and can operate for a long period, and its reaction property is stable. |
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Said invention adopts a fixed-bed reactor, and uses said catalyst in gas-phase catalytic synthesis reaction of oxalate by using carbonic oxide and nitrous acid ester. In the course of carbon monoxide catalytic coupling reaction to synthesize dimethyl oxalate and diethyl oxalate said catalyst possesses highest reactive activity, and can operate for a long period, and its reaction property is stable.</description><edition>6</edition><language>eng</language><subject>ACYCLIC OR CARBOCYCLIC COMPOUNDS ; CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY ; CHEMISTRY ; METALLURGY ; ORGANIC CHEMISTRY ; PERFORMING OPERATIONS ; PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL ; THEIR RELEVANT APPARATUS ; TRANSPORTING</subject><creationdate>1997</creationdate><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://worldwide.espacenet.com/publicationDetails/biblio?FT=D&date=19970430&DB=EPODOC&CC=CN&NR=1148589A$$EHTML$$P50$$Gepo$$Hfree_for_read</linktohtml><link.rule.ids>230,308,780,885,25564,76547</link.rule.ids><linktorsrc>$$Uhttps://worldwide.espacenet.com/publicationDetails/biblio?FT=D&date=19970430&DB=EPODOC&CC=CN&NR=1148589A$$EView_record_in_European_Patent_Office$$FView_record_in_$$GEuropean_Patent_Office$$Hfree_for_read</linktorsrc></links><search><creatorcontrib>CUNPING HUANG</creatorcontrib><creatorcontrib>BINGKAI ZHANG</creatorcontrib><creatorcontrib>TINGHUANG GUO</creatorcontrib><title>Oxalate synthesis catalyst</title><description>A new type Pd-Zr/Al2O3 catalyst for synthesizing oxalate is developed by using Zr as adjuvant and adopting pickling process. Said invention adopts a fixed-bed reactor, and uses said catalyst in gas-phase catalytic synthesis reaction of oxalate by using carbonic oxide and nitrous acid ester. In the course of carbon monoxide catalytic coupling reaction to synthesize dimethyl oxalate and diethyl oxalate said catalyst possesses highest reactive activity, and can operate for a long period, and its reaction property is stable.</description><subject>ACYCLIC OR CARBOCYCLIC COMPOUNDS</subject><subject>CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY</subject><subject>CHEMISTRY</subject><subject>METALLURGY</subject><subject>ORGANIC CHEMISTRY</subject><subject>PERFORMING OPERATIONS</subject><subject>PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL</subject><subject>THEIR RELEVANT APPARATUS</subject><subject>TRANSPORTING</subject><fulltext>true</fulltext><rsrctype>patent</rsrctype><creationdate>1997</creationdate><recordtype>patent</recordtype><sourceid>EVB</sourceid><recordid>eNrjZJDyr0jMSSxJVSiuzCvJSC3OLFZITixJzKksLuFhYE1LzClO5YXS3Azybq4hzh66qQX58anFBYnJqXmpJfHOfoaGJhamFpaOxoRVAADoMyKi</recordid><startdate>19970430</startdate><enddate>19970430</enddate><creator>CUNPING HUANG</creator><creator>BINGKAI ZHANG</creator><creator>TINGHUANG GUO</creator><scope>EVB</scope></search><sort><creationdate>19970430</creationdate><title>Oxalate synthesis catalyst</title><author>CUNPING HUANG ; BINGKAI ZHANG ; TINGHUANG GUO</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-epo_espacenet_CN1148589A3</frbrgroupid><rsrctype>patents</rsrctype><prefilter>patents</prefilter><language>eng</language><creationdate>1997</creationdate><topic>ACYCLIC OR CARBOCYCLIC COMPOUNDS</topic><topic>CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY</topic><topic>CHEMISTRY</topic><topic>METALLURGY</topic><topic>ORGANIC CHEMISTRY</topic><topic>PERFORMING OPERATIONS</topic><topic>PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL</topic><topic>THEIR RELEVANT APPARATUS</topic><topic>TRANSPORTING</topic><toplevel>online_resources</toplevel><creatorcontrib>CUNPING HUANG</creatorcontrib><creatorcontrib>BINGKAI ZHANG</creatorcontrib><creatorcontrib>TINGHUANG GUO</creatorcontrib><collection>esp@cenet</collection></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext_linktorsrc</fulltext></delivery><addata><au>CUNPING HUANG</au><au>BINGKAI ZHANG</au><au>TINGHUANG GUO</au><format>patent</format><genre>patent</genre><ristype>GEN</ristype><title>Oxalate synthesis catalyst</title><date>1997-04-30</date><risdate>1997</risdate><abstract>A new type Pd-Zr/Al2O3 catalyst for synthesizing oxalate is developed by using Zr as adjuvant and adopting pickling process. Said invention adopts a fixed-bed reactor, and uses said catalyst in gas-phase catalytic synthesis reaction of oxalate by using carbonic oxide and nitrous acid ester. In the course of carbon monoxide catalytic coupling reaction to synthesize dimethyl oxalate and diethyl oxalate said catalyst possesses highest reactive activity, and can operate for a long period, and its reaction property is stable.</abstract><edition>6</edition><oa>free_for_read</oa></addata></record> |
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subjects | ACYCLIC OR CARBOCYCLIC COMPOUNDS CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY CHEMISTRY METALLURGY ORGANIC CHEMISTRY PERFORMING OPERATIONS PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL THEIR RELEVANT APPARATUS TRANSPORTING |
title | Oxalate synthesis catalyst |
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