Oxalate synthesis catalyst

A new type Pd-Zr/Al2O3 catalyst for synthesizing oxalate is developed by using Zr as adjuvant and adopting pickling process. Said invention adopts a fixed-bed reactor, and uses said catalyst in gas-phase catalytic synthesis reaction of oxalate by using carbonic oxide and nitrous acid ester. In the c...

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Hauptverfasser: CUNPING HUANG, BINGKAI ZHANG, TINGHUANG GUO
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creator CUNPING HUANG
BINGKAI ZHANG
TINGHUANG GUO
description A new type Pd-Zr/Al2O3 catalyst for synthesizing oxalate is developed by using Zr as adjuvant and adopting pickling process. Said invention adopts a fixed-bed reactor, and uses said catalyst in gas-phase catalytic synthesis reaction of oxalate by using carbonic oxide and nitrous acid ester. In the course of carbon monoxide catalytic coupling reaction to synthesize dimethyl oxalate and diethyl oxalate said catalyst possesses highest reactive activity, and can operate for a long period, and its reaction property is stable.
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Said invention adopts a fixed-bed reactor, and uses said catalyst in gas-phase catalytic synthesis reaction of oxalate by using carbonic oxide and nitrous acid ester. 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subjects ACYCLIC OR CARBOCYCLIC COMPOUNDS
CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY
CHEMISTRY
METALLURGY
ORGANIC CHEMISTRY
PERFORMING OPERATIONS
PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
THEIR RELEVANT APPARATUS
TRANSPORTING
title Oxalate synthesis catalyst
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