Novel nickel-manganese-based layered sodium ion battery positive electrode material

The invention belongs to the technical field of electrochemistry, and particularly discloses a novel nickel-manganese-based layered sodium ion battery positive electrode material, the general formula of which is NaxNiyMnzM1-y-zO2, in the general formula, M comprises at least one of iron, zinc, nicke...

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description The invention belongs to the technical field of electrochemistry, and particularly discloses a novel nickel-manganese-based layered sodium ion battery positive electrode material, the general formula of which is NaxNiyMnzM1-y-zO2, in the general formula, M comprises at least one of iron, zinc, nickel, copper, lithium and titanium, 0.5 < = x < = 1.0, 0 < y < 1.0, and 0 < z < 1.0. One or more metal ions are doped in a TM layer of a nickel-manganese-based layered positive electrode oxide, occupation of two different Wyckoff sites is regulated and controlled, rearrangement of Na < + > is successfully induced, the Nae/Naf proportion is regulated and controlled, after the metal ions are doped in the TM layer, Na < + > preferentially occupies the Nae sites, the original arrangement mode of Na < + > is changed, and ordered arrangement of TMn < + > and Na < + >/vacancies is disturbed. The unordered Na < + > distribution and the preferential occupation of Nae sites not only provide a new coordination environment for ef
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One or more metal ions are doped in a TM layer of a nickel-manganese-based layered positive electrode oxide, occupation of two different Wyckoff sites is regulated and controlled, rearrangement of Na < + > is successfully induced, the Nae/Naf proportion is regulated and controlled, after the metal ions are doped in the TM layer, Na < + > preferentially occupies the Nae sites, the original arrangement mode of Na < + > is changed, and ordered arrangement of TMn < + > and Na < + >/vacancies is disturbed. The unordered Na < + > distribution and the preferential occupation of Nae sites not only provide a new coordination environment for ef]]></abstract><oa>free_for_read</oa></addata></record>
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subjects BASIC ELECTRIC ELEMENTS
CHEMISTRY
COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSESC01D OR C01F
ELECTRICITY
INORGANIC CHEMISTRY
METALLURGY
PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSIONOF CHEMICAL INTO ELECTRICAL ENERGY
title Novel nickel-manganese-based layered sodium ion battery positive electrode material
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