Low-odor emulsion, preparation method and application
The invention discloses a low-odor emulsion as well as a preparation method and application thereof. The emulsion is prepared from the following monomer components in percentage by mass through emulsion polymerization: a, 35-70wt% of ethyl acrylate; b, 1.3 to 10wt% of an olefinic unsaturated monomer...
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| creator | JIA GUIYU ZHANG WEIHUI JIA YUANFENG JI XUESHUN JING CHUANMING MA JIQUAN |
| description | The invention discloses a low-odor emulsion as well as a preparation method and application thereof. The emulsion is prepared from the following monomer components in percentage by mass through emulsion polymerization: a, 35-70wt% of ethyl acrylate; b, 1.3 to 10wt% of an olefinic unsaturated monomer containing an acetoacetate functional group; c, 0.5 to 5 weight percent of unsaturated hydrophilic monomer; d, 0.2 to 5 percent of a reaction type silane coupling agent; e, 10%-40% of dodecadecyl (methyl) acrylate to tetradecyl (methyl) acrylate; and f, 10-40% of other olefinic unsaturated monomers. Under the condition of not adding a coalescing agent and an anti-freezing agent, the emulsion for the latex paint, which is ultralow in odor and excellent in scrubbing resistance and freeze-thaw stability, is prepared.
本发明公开了一种低气味乳液、制备方法及应用，所述乳液由包括以下质量百分比的单体组分通过乳液聚合制备得到：a、35-70wt％的丙烯酸乙酯；b、1.3-10wt％的含有乙酰乙酸酯官能团的烯属不饱和单体；c、0.5-5wt％的不饱和亲水单体；d、0.2-5％的反应型硅烷偶联剂；e、10-40％的十二至十四烷基的(甲基)丙烯酸酯；f、10-40％的其它烯属不饱和单体。本发明在不添加成膜助剂及抗冻剂的情况下，制 |
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本发明公开了一种低气味乳液、制备方法及应用，所述乳液由包括以下质量百分比的单体组分通过乳液聚合制备得到：a、35-70wt％的丙烯酸乙酯；b、1.3-10wt％的含有乙酰乙酸酯官能团的烯属不饱和单体；c、0.5-5wt％的不饱和亲水单体；d、0.2-5％的反应型硅烷偶联剂；e、10-40％的十二至十四烷基的(甲基)丙烯酸酯；f、10-40％的其它烯属不饱和单体。本发明在不添加成膜助剂及抗冻剂的情况下，制</description><language>chi ; eng</language><subject>ADHESIVES ; CHEMICAL PAINT OR INK REMOVERS ; CHEMISTRY ; COATING COMPOSITIONS, e.g. PAINTS, VARNISHES ORLACQUERS ; COMPOSITIONS BASED THEREON ; CORRECTING FLUIDS ; DYES ; FILLING PASTES ; INKS ; MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVINGCARBON-TO-CARBON UNSATURATED BONDS ; METALLURGY ; MISCELLANEOUS APPLICATIONS OF MATERIALS ; MISCELLANEOUS COMPOSITIONS ; NATURAL RESINS ; ORGANIC MACROMOLECULAR COMPOUNDS ; PAINTS ; PASTES OR SOLIDS FOR COLOURING OR PRINTING ; POLISHES ; THEIR PREPARATION OR CHEMICAL WORKING-UP ; USE OF MATERIALS THEREFOR ; WOODSTAINS</subject><creationdate>2022</creationdate><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://worldwide.espacenet.com/publicationDetails/biblio?FT=D&date=20220506&DB=EPODOC&CC=CN&NR=114437283A$$EHTML$$P50$$Gepo$$Hfree_for_read</linktohtml><link.rule.ids>230,308,778,883,25551,76304</link.rule.ids><linktorsrc>$$Uhttps://worldwide.espacenet.com/publicationDetails/biblio?FT=D&date=20220506&DB=EPODOC&CC=CN&NR=114437283A$$EView_record_in_European_Patent_Office$$FView_record_in_$$GEuropean_Patent_Office$$Hfree_for_read</linktorsrc></links><search><creatorcontrib>JIA GUIYU</creatorcontrib><creatorcontrib>ZHANG WEIHUI</creatorcontrib><creatorcontrib>JIA YUANFENG</creatorcontrib><creatorcontrib>JI XUESHUN</creatorcontrib><creatorcontrib>JING CHUANMING</creatorcontrib><creatorcontrib>MA JIQUAN</creatorcontrib><title>Low-odor emulsion, preparation method and application</title><description>The invention discloses a low-odor emulsion as well as a preparation method and application thereof. The emulsion is prepared from the following monomer components in percentage by mass through emulsion polymerization: a, 35-70wt% of ethyl acrylate; b, 1.3 to 10wt% of an olefinic unsaturated monomer containing an acetoacetate functional group; c, 0.5 to 5 weight percent of unsaturated hydrophilic monomer; d, 0.2 to 5 percent of a reaction type silane coupling agent; e, 10%-40% of dodecadecyl (methyl) acrylate to tetradecyl (methyl) acrylate; and f, 10-40% of other olefinic unsaturated monomers. Under the condition of not adding a coalescing agent and an anti-freezing agent, the emulsion for the latex paint, which is ultralow in odor and excellent in scrubbing resistance and freeze-thaw stability, is prepared.
本发明公开了一种低气味乳液、制备方法及应用，所述乳液由包括以下质量百分比的单体组分通过乳液聚合制备得到：a、35-70wt％的丙烯酸乙酯；b、1.3-10wt％的含有乙酰乙酸酯官能团的烯属不饱和单体；c、0.5-5wt％的不饱和亲水单体；d、0.2-5％的反应型硅烷偶联剂；e、10-40％的十二至十四烷基的(甲基)丙烯酸酯；f、10-40％的其它烯属不饱和单体。本发明在不添加成膜助剂及抗冻剂的情况下，制</description><subject>ADHESIVES</subject><subject>CHEMICAL PAINT OR INK REMOVERS</subject><subject>CHEMISTRY</subject><subject>COATING COMPOSITIONS, e.g. PAINTS, VARNISHES ORLACQUERS</subject><subject>COMPOSITIONS BASED THEREON</subject><subject>CORRECTING FLUIDS</subject><subject>DYES</subject><subject>FILLING PASTES</subject><subject>INKS</subject><subject>MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVINGCARBON-TO-CARBON UNSATURATED BONDS</subject><subject>METALLURGY</subject><subject>MISCELLANEOUS APPLICATIONS OF MATERIALS</subject><subject>MISCELLANEOUS COMPOSITIONS</subject><subject>NATURAL RESINS</subject><subject>ORGANIC MACROMOLECULAR COMPOUNDS</subject><subject>PAINTS</subject><subject>PASTES OR SOLIDS FOR COLOURING OR PRINTING</subject><subject>POLISHES</subject><subject>THEIR PREPARATION OR CHEMICAL WORKING-UP</subject><subject>USE OF MATERIALS THEREFOR</subject><subject>WOODSTAINS</subject><fulltext>true</fulltext><rsrctype>patent</rsrctype><creationdate>2022</creationdate><recordtype>patent</recordtype><sourceid>EVB</sourceid><recordid>eNrjZDD1yS_XzU_JL1JIzS3NKc7Mz9NRKChKLUgsSiwBchRyU0sy8lMUEvOAuKAgJzMZLMzDwJqWmFOcyguluRkU3VxDnD10Uwvy41OLCxKTU_NSS-Kd_QwNTUyMzY0sjB2NiVEDAHZPLVY</recordid><startdate>20220506</startdate><enddate>20220506</enddate><creator>JIA GUIYU</creator><creator>ZHANG WEIHUI</creator><creator>JIA YUANFENG</creator><creator>JI XUESHUN</creator><creator>JING CHUANMING</creator><creator>MA JIQUAN</creator><scope>EVB</scope></search><sort><creationdate>20220506</creationdate><title>Low-odor emulsion, preparation method and application</title><author>JIA GUIYU ; ZHANG WEIHUI ; JIA YUANFENG ; JI XUESHUN ; JING CHUANMING ; MA JIQUAN</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-epo_espacenet_CN114437283A3</frbrgroupid><rsrctype>patents</rsrctype><prefilter>patents</prefilter><language>chi ; eng</language><creationdate>2022</creationdate><topic>ADHESIVES</topic><topic>CHEMICAL PAINT OR INK REMOVERS</topic><topic>CHEMISTRY</topic><topic>COATING COMPOSITIONS, e.g. PAINTS, VARNISHES ORLACQUERS</topic><topic>COMPOSITIONS BASED THEREON</topic><topic>CORRECTING FLUIDS</topic><topic>DYES</topic><topic>FILLING PASTES</topic><topic>INKS</topic><topic>MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVINGCARBON-TO-CARBON UNSATURATED BONDS</topic><topic>METALLURGY</topic><topic>MISCELLANEOUS APPLICATIONS OF MATERIALS</topic><topic>MISCELLANEOUS COMPOSITIONS</topic><topic>NATURAL RESINS</topic><topic>ORGANIC MACROMOLECULAR COMPOUNDS</topic><topic>PAINTS</topic><topic>PASTES OR SOLIDS FOR COLOURING OR PRINTING</topic><topic>POLISHES</topic><topic>THEIR PREPARATION OR CHEMICAL WORKING-UP</topic><topic>USE OF MATERIALS THEREFOR</topic><topic>WOODSTAINS</topic><toplevel>online_resources</toplevel><creatorcontrib>JIA GUIYU</creatorcontrib><creatorcontrib>ZHANG WEIHUI</creatorcontrib><creatorcontrib>JIA YUANFENG</creatorcontrib><creatorcontrib>JI XUESHUN</creatorcontrib><creatorcontrib>JING CHUANMING</creatorcontrib><creatorcontrib>MA JIQUAN</creatorcontrib><collection>esp@cenet</collection></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext_linktorsrc</fulltext></delivery><addata><au>JIA GUIYU</au><au>ZHANG WEIHUI</au><au>JIA YUANFENG</au><au>JI XUESHUN</au><au>JING CHUANMING</au><au>MA JIQUAN</au><format>patent</format><genre>patent</genre><ristype>GEN</ristype><title>Low-odor emulsion, preparation method and application</title><date>2022-05-06</date><risdate>2022</risdate><abstract>The invention discloses a low-odor emulsion as well as a preparation method and application thereof. The emulsion is prepared from the following monomer components in percentage by mass through emulsion polymerization: a, 35-70wt% of ethyl acrylate; b, 1.3 to 10wt% of an olefinic unsaturated monomer containing an acetoacetate functional group; c, 0.5 to 5 weight percent of unsaturated hydrophilic monomer; d, 0.2 to 5 percent of a reaction type silane coupling agent; e, 10%-40% of dodecadecyl (methyl) acrylate to tetradecyl (methyl) acrylate; and f, 10-40% of other olefinic unsaturated monomers. Under the condition of not adding a coalescing agent and an anti-freezing agent, the emulsion for the latex paint, which is ultralow in odor and excellent in scrubbing resistance and freeze-thaw stability, is prepared.
本发明公开了一种低气味乳液、制备方法及应用，所述乳液由包括以下质量百分比的单体组分通过乳液聚合制备得到：a、35-70wt％的丙烯酸乙酯；b、1.3-10wt％的含有乙酰乙酸酯官能团的烯属不饱和单体；c、0.5-5wt％的不饱和亲水单体；d、0.2-5％的反应型硅烷偶联剂；e、10-40％的十二至十四烷基的(甲基)丙烯酸酯；f、10-40％的其它烯属不饱和单体。本发明在不添加成膜助剂及抗冻剂的情况下，制</abstract><oa>free_for_read</oa></addata></record> |
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| subjects | ADHESIVES CHEMICAL PAINT OR INK REMOVERS CHEMISTRY COATING COMPOSITIONS, e.g. PAINTS, VARNISHES ORLACQUERS COMPOSITIONS BASED THEREON CORRECTING FLUIDS DYES FILLING PASTES INKS MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVINGCARBON-TO-CARBON UNSATURATED BONDS METALLURGY MISCELLANEOUS APPLICATIONS OF MATERIALS MISCELLANEOUS COMPOSITIONS NATURAL RESINS ORGANIC MACROMOLECULAR COMPOUNDS PAINTS PASTES OR SOLIDS FOR COLOURING OR PRINTING POLISHES THEIR PREPARATION OR CHEMICAL WORKING-UP USE OF MATERIALS THEREFOR WOODSTAINS |
| title | Low-odor emulsion, preparation method and application |
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