Method for synthesizing benzyl acetate by using combined catalytic system
The invention provides a method for synthesizing benzyl acetate by using a combined catalytic system, and belongs to the technical field of fine chemical engineering. According to the synthesis method, by taking dibenzyl ether as a raw material, selecting a combined catalyst comprising three compone...
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creator | HUANG ZHENGWANG CAI FENG ZHANG LONGJI SHU ZHENCAO YUAN FUTAO SUN BO ZHANG YONG CHENG JUAN NIE SHAOCHUN |
description | The invention provides a method for synthesizing benzyl acetate by using a combined catalytic system, and belongs to the technical field of fine chemical engineering. According to the synthesis method, by taking dibenzyl ether as a raw material, selecting a combined catalyst comprising three components, namely a main catalyst, a leaving group and a trapping agent as a catalyst, the raw material reacts with acetic anhydride to obtain a crude product, and then rectification and purification are performed to obtain a benzyl acetate finished product. The main catalyst activates acetic anhydride and promotes formation of a reaction intermediate; the leaving group promotes the leaving of benzyl and inhibits the intramolecular rearrangement of benzyl; the trapping agent traps removed benzyl positive ions, helps elimination of benzyl, promotes the reaction to proceed to a main reaction route and inhibits generation of side reactions, the three components have a synergistic effect, the single-pass reaction yield of be |
format | Patent |
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The main catalyst activates acetic anhydride and promotes formation of a reaction intermediate; the leaving group promotes the leaving of benzyl and inhibits the intramolecular rearrangement of benzyl; the trapping agent traps removed benzyl positive ions, helps elimination of benzyl, promotes the reaction to proceed to a main reaction route and inhibits generation of side reactions, the three components have a synergistic effect, the single-pass reaction yield of be</description><language>chi ; eng</language><subject>ACYCLIC OR CARBOCYCLIC COMPOUNDS ; CHEMISTRY ; METALLURGY ; ORGANIC CHEMISTRY</subject><creationdate>2021</creationdate><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://worldwide.espacenet.com/publicationDetails/biblio?FT=D&date=20210709&DB=EPODOC&CC=CN&NR=113087625A$$EHTML$$P50$$Gepo$$Hfree_for_read</linktohtml><link.rule.ids>230,308,780,885,25564,76547</link.rule.ids><linktorsrc>$$Uhttps://worldwide.espacenet.com/publicationDetails/biblio?FT=D&date=20210709&DB=EPODOC&CC=CN&NR=113087625A$$EView_record_in_European_Patent_Office$$FView_record_in_$$GEuropean_Patent_Office$$Hfree_for_read</linktorsrc></links><search><creatorcontrib>HUANG ZHENGWANG</creatorcontrib><creatorcontrib>CAI FENG</creatorcontrib><creatorcontrib>ZHANG LONGJI</creatorcontrib><creatorcontrib>SHU ZHENCAO</creatorcontrib><creatorcontrib>YUAN FUTAO</creatorcontrib><creatorcontrib>SUN BO</creatorcontrib><creatorcontrib>ZHANG YONG</creatorcontrib><creatorcontrib>CHENG JUAN</creatorcontrib><creatorcontrib>NIE SHAOCHUN</creatorcontrib><title>Method for synthesizing benzyl acetate by using combined catalytic system</title><description>The invention provides a method for synthesizing benzyl acetate by using a combined catalytic system, and belongs to the technical field of fine chemical engineering. 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According to the synthesis method, by taking dibenzyl ether as a raw material, selecting a combined catalyst comprising three components, namely a main catalyst, a leaving group and a trapping agent as a catalyst, the raw material reacts with acetic anhydride to obtain a crude product, and then rectification and purification are performed to obtain a benzyl acetate finished product. The main catalyst activates acetic anhydride and promotes formation of a reaction intermediate; the leaving group promotes the leaving of benzyl and inhibits the intramolecular rearrangement of benzyl; the trapping agent traps removed benzyl positive ions, helps elimination of benzyl, promotes the reaction to proceed to a main reaction route and inhibits generation of side reactions, the three components have a synergistic effect, the single-pass reaction yield of be</abstract><oa>free_for_read</oa></addata></record> |
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title | Method for synthesizing benzyl acetate by using combined catalytic system |
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