Preparation method of supramolecular flame retardant network with graphite-like structure

The invention relates to a preparation method of a supramolecular flame retardant network with a graphite-like structure, which comprises the following steps: reacting organic amine containing a s-triazine structure with cyanuric acid in a solvent at the reaction temperature of 30-150 DEG C to obtai...

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Hauptverfasser: PENG ZHIHAN, LI YINGYING, ZHAO YONGSHUAI, GUO CHENGXIN, CHEN SHUAI, YI ZHIXING, JI GUICHEN
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creator PENG ZHIHAN
LI YINGYING
ZHAO YONGSHUAI
GUO CHENGXIN
CHEN SHUAI
YI ZHIXING
JI GUICHEN
description The invention relates to a preparation method of a supramolecular flame retardant network with a graphite-like structure, which comprises the following steps: reacting organic amine containing a s-triazine structure with cyanuric acid in a solvent at the reaction temperature of 30-150 DEG C to obtain a target product, or reacting the organic amine containing the s-triazine structure with cyanuric acid under a solid phase condition at the temperature of 150-350 DEG C to obtain a target product. According to the invention, the supramolecular flame retardant network is not only connected by covalent bonds and hydrogen bonds in layers, but also tightly controlled by Van der Waals force among the layers, and has a long-range ordered structure; in the initial stage of combustion, the graphite-like structure of the flame-retardant polymer material can relatively slip to form a tight smoke shielding layer, and meanwhile, heat accumulated in the polymer material can be quickly transferred along covalent bonds, hydroge
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According to the invention, the supramolecular flame retardant network is not only connected by covalent bonds and hydrogen bonds in layers, but also tightly controlled by Van der Waals force among the layers, and has a long-range ordered structure; in the initial stage of combustion, the graphite-like structure of the flame-retardant polymer material can relatively slip to form a tight smoke shielding layer, and meanwhile, heat accumulated in the polymer material can be quickly transferred along covalent bonds, hydroge</abstract><oa>free_for_read</oa></addata></record>
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subjects ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE
ADHESIVES
APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBONFILAMENTS
CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS,THREADS, FIBRES, BRISTLES OR RIBBONS
CHEMISTRY
COMPOSITIONS BASED THEREON
COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
DYES
METALLURGY
MISCELLANEOUS APPLICATIONS OF MATERIALS
MISCELLANEOUS COMPOSITIONS
NATURAL OR ARTIFICIAL THREADS OR FIBRES
NATURAL RESINS
NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL
ORGANIC MACROMOLECULAR COMPOUNDS
PAINTS
POLISHES
SPINNING
TEXTILES
THEIR PREPARATION OR CHEMICAL WORKING-UP
USE OF INORGANIC OR NON-MACROMOLECULAR ORGANIC SUBSTANCES ASCOMPOUNDING INGREDIENTS
USE OF MATERIALS AS ADHESIVES
title Preparation method of supramolecular flame retardant network with graphite-like structure
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