Catalyst supports, supported metallocene catalysts and their use for the preparation of polyolefins

The prodn. of a catalyst support (I) comprises: (a) drying hydrophilic, macroporous, disperse Al2O3, SiO2, titanium oxide or zirconium oxide, or mixts. or mixed oxides thereof (II), at 110-800 degrees C; (b) reacting with an aluminoxane (III); and then (c) reacting with polyfunctional organic crossl...

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Bibliographische Detailangaben
Hauptverfasser: WOLFGANG NEIBL, EBERHARD ERNST, JENS REUBNER
Format: Patent
Sprache:eng
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Zusammenfassung:The prodn. of a catalyst support (I) comprises: (a) drying hydrophilic, macroporous, disperse Al2O3, SiO2, titanium oxide or zirconium oxide, or mixts. or mixed oxides thereof (II), at 110-800 degrees C; (b) reacting with an aluminoxane (III); and then (c) reacting with polyfunctional organic crosslinkers (IV). Also claimed is a catalyst support (I) based on (II) and (III), crosslinked with (IV). Also claimed are supported metallocene catalysts contg. the reaction prods. of (I) with the reaction prods. of metallocene and activators, pref. aluminoxane. Also claimed is a process for the prodn. of polyolefins by (co)polymerisation of olefins using the above supported metallocene catalysts, pref. in the presence of aluminium alkyl.