Conversion and utilization method of perfluorinated iodide as well as obtained product and application
The invention discloses a conversion and utilization method of perfluorinated iodide, an obtained product and application. The method includes carrying out nucleophilic substitution reaction on the perfluoroiodide intermediate and azide, and carrying out 1, 3-dipolar cycloaddition click reaction on...
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| creator | LENG CHANGSONG LI XINGJIAN |
| description | The invention discloses a conversion and utilization method of perfluorinated iodide, an obtained product and application. The method includes carrying out nucleophilic substitution reaction on the perfluoroiodide intermediate and azide, and carrying out 1, 3-dipolar cycloaddition click reaction on the obtained perfluoroalkyl azide serving as a fluorine-containing monomer and an alkynyl functionalized high polymer material after the reaction is finished, so as to obtain the fluorine-containing 1, 2, 3-triazole high polymer compound. The method provided by the invention has universality, is suitable for any perfluoroiodide, and has the advantages of simple preparation process, high monomer conversion efficiency and mild synthesis conditions, and the obtained product can be a solution type or an aqueous emulsion, and can be used as a low surface energy coating and a fabric finishing agent.
本发明公开了一种全氟碘化物的转化利用方法及所得产品和应用，将全氟碘化物中间体与叠氮化物进行亲核取代反应，反应完成后将所得的全氟烷基叠氮化物为含氟单体和炔基功能化的高分子材料进行1,3-偶极环加成点击反应，得到含氟1,2,3-三唑高分子化合物。本发 |
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本发明公开了一种全氟碘化物的转化利用方法及所得产品和应用，将全氟碘化物中间体与叠氮化物进行亲核取代反应，反应完成后将所得的全氟烷基叠氮化物为含氟单体和炔基功能化的高分子材料进行1,3-偶极环加成点击反应，得到含氟1,2,3-三唑高分子化合物。本发</description><language>chi ; eng</language><subject>ACYCLIC OR CARBOCYCLIC COMPOUNDS ; ADHESIVES ; CHEMICAL PAINT OR INK REMOVERS ; CHEMISTRY ; COATING COMPOSITIONS, e.g. PAINTS, VARNISHES ORLACQUERS ; COMPOSITIONS BASED THEREON ; CORRECTING FLUIDS ; DYES ; FILLING PASTES ; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR ; INKS ; LAUNDERING ; MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONSONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS ; METALLURGY ; MISCELLANEOUS APPLICATIONS OF MATERIALS ; MISCELLANEOUS COMPOSITIONS ; NATURAL RESINS ; ORGANIC CHEMISTRY ; ORGANIC MACROMOLECULAR COMPOUNDS ; PAINTS ; PASTES OR SOLIDS FOR COLOURING OR PRINTING ; POLISHES ; TEXTILES ; THEIR PREPARATION OR CHEMICAL WORKING-UP ; TREATMENT OF TEXTILES OR THE LIKE ; TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS,FABRICS, FEATHERS, OR FIBROUS GOODS MADE FROM SUCH MATERIALS ; USE OF MATERIALS THEREFOR ; WOODSTAINS</subject><creationdate>2020</creationdate><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://worldwide.espacenet.com/publicationDetails/biblio?FT=D&date=20200807&DB=EPODOC&CC=CN&NR=111499836A$$EHTML$$P50$$Gepo$$Hfree_for_read</linktohtml><link.rule.ids>230,308,780,885,25564,76547</link.rule.ids><linktorsrc>$$Uhttps://worldwide.espacenet.com/publicationDetails/biblio?FT=D&date=20200807&DB=EPODOC&CC=CN&NR=111499836A$$EView_record_in_European_Patent_Office$$FView_record_in_$$GEuropean_Patent_Office$$Hfree_for_read</linktorsrc></links><search><creatorcontrib>LENG CHANGSONG</creatorcontrib><creatorcontrib>LI XINGJIAN</creatorcontrib><title>Conversion and utilization method of perfluorinated iodide as well as obtained product and application</title><description>The invention discloses a conversion and utilization method of perfluorinated iodide, an obtained product and application. The method includes carrying out nucleophilic substitution reaction on the perfluoroiodide intermediate and azide, and carrying out 1, 3-dipolar cycloaddition click reaction on the obtained perfluoroalkyl azide serving as a fluorine-containing monomer and an alkynyl functionalized high polymer material after the reaction is finished, so as to obtain the fluorine-containing 1, 2, 3-triazole high polymer compound. The method provided by the invention has universality, is suitable for any perfluoroiodide, and has the advantages of simple preparation process, high monomer conversion efficiency and mild synthesis conditions, and the obtained product can be a solution type or an aqueous emulsion, and can be used as a low surface energy coating and a fabric finishing agent.
本发明公开了一种全氟碘化物的转化利用方法及所得产品和应用，将全氟碘化物中间体与叠氮化物进行亲核取代反应，反应完成后将所得的全氟烷基叠氮化物为含氟单体和炔基功能化的高分子材料进行1,3-偶极环加成点击反应，得到含氟1,2,3-三唑高分子化合物。本发</description><subject>ACYCLIC OR CARBOCYCLIC COMPOUNDS</subject><subject>ADHESIVES</subject><subject>CHEMICAL PAINT OR INK REMOVERS</subject><subject>CHEMISTRY</subject><subject>COATING COMPOSITIONS, e.g. PAINTS, VARNISHES ORLACQUERS</subject><subject>COMPOSITIONS BASED THEREON</subject><subject>CORRECTING FLUIDS</subject><subject>DYES</subject><subject>FILLING PASTES</subject><subject>FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR</subject><subject>INKS</subject><subject>LAUNDERING</subject><subject>MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONSONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS</subject><subject>METALLURGY</subject><subject>MISCELLANEOUS APPLICATIONS OF MATERIALS</subject><subject>MISCELLANEOUS COMPOSITIONS</subject><subject>NATURAL RESINS</subject><subject>ORGANIC CHEMISTRY</subject><subject>ORGANIC MACROMOLECULAR COMPOUNDS</subject><subject>PAINTS</subject><subject>PASTES OR SOLIDS FOR COLOURING OR PRINTING</subject><subject>POLISHES</subject><subject>TEXTILES</subject><subject>THEIR PREPARATION OR CHEMICAL WORKING-UP</subject><subject>TREATMENT OF TEXTILES OR THE LIKE</subject><subject>TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS,FABRICS, FEATHERS, OR FIBROUS GOODS MADE FROM SUCH MATERIALS</subject><subject>USE OF MATERIALS THEREFOR</subject><subject>WOODSTAINS</subject><fulltext>true</fulltext><rsrctype>patent</rsrctype><creationdate>2020</creationdate><recordtype>patent</recordtype><sourceid>EVB</sourceid><recordid>eNqNjDEKAjEQRdNYiHqH8QAWy4q4pQTFysp-GZMJDsRMSGYVPL3u4gGsHp__eHMTrKQnlcqSAJOHQTnyG3XcD9K7eJAAmUqIgxROqOSBxbMnwAovinGk3BQ5fa9cxA9OpxbmHNlNraWZBYyVVj8uzPp0vNrzhrL0VDM6SqS9vTRNs-26fbs7tP84H8RXQCg</recordid><startdate>20200807</startdate><enddate>20200807</enddate><creator>LENG CHANGSONG</creator><creator>LI XINGJIAN</creator><scope>EVB</scope></search><sort><creationdate>20200807</creationdate><title>Conversion and utilization method of perfluorinated iodide as well as obtained product and application</title><author>LENG CHANGSONG ; LI XINGJIAN</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-epo_espacenet_CN111499836A3</frbrgroupid><rsrctype>patents</rsrctype><prefilter>patents</prefilter><language>chi ; eng</language><creationdate>2020</creationdate><topic>ACYCLIC OR CARBOCYCLIC COMPOUNDS</topic><topic>ADHESIVES</topic><topic>CHEMICAL PAINT OR INK REMOVERS</topic><topic>CHEMISTRY</topic><topic>COATING COMPOSITIONS, e.g. PAINTS, VARNISHES ORLACQUERS</topic><topic>COMPOSITIONS BASED THEREON</topic><topic>CORRECTING FLUIDS</topic><topic>DYES</topic><topic>FILLING PASTES</topic><topic>FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR</topic><topic>INKS</topic><topic>LAUNDERING</topic><topic>MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONSONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS</topic><topic>METALLURGY</topic><topic>MISCELLANEOUS APPLICATIONS OF MATERIALS</topic><topic>MISCELLANEOUS COMPOSITIONS</topic><topic>NATURAL RESINS</topic><topic>ORGANIC CHEMISTRY</topic><topic>ORGANIC MACROMOLECULAR COMPOUNDS</topic><topic>PAINTS</topic><topic>PASTES OR SOLIDS FOR COLOURING OR PRINTING</topic><topic>POLISHES</topic><topic>TEXTILES</topic><topic>THEIR PREPARATION OR CHEMICAL WORKING-UP</topic><topic>TREATMENT OF TEXTILES OR THE LIKE</topic><topic>TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS,FABRICS, FEATHERS, OR FIBROUS GOODS MADE FROM SUCH MATERIALS</topic><topic>USE OF MATERIALS THEREFOR</topic><topic>WOODSTAINS</topic><toplevel>online_resources</toplevel><creatorcontrib>LENG CHANGSONG</creatorcontrib><creatorcontrib>LI XINGJIAN</creatorcontrib><collection>esp@cenet</collection></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext_linktorsrc</fulltext></delivery><addata><au>LENG CHANGSONG</au><au>LI XINGJIAN</au><format>patent</format><genre>patent</genre><ristype>GEN</ristype><title>Conversion and utilization method of perfluorinated iodide as well as obtained product and application</title><date>2020-08-07</date><risdate>2020</risdate><abstract>The invention discloses a conversion and utilization method of perfluorinated iodide, an obtained product and application. The method includes carrying out nucleophilic substitution reaction on the perfluoroiodide intermediate and azide, and carrying out 1, 3-dipolar cycloaddition click reaction on the obtained perfluoroalkyl azide serving as a fluorine-containing monomer and an alkynyl functionalized high polymer material after the reaction is finished, so as to obtain the fluorine-containing 1, 2, 3-triazole high polymer compound. The method provided by the invention has universality, is suitable for any perfluoroiodide, and has the advantages of simple preparation process, high monomer conversion efficiency and mild synthesis conditions, and the obtained product can be a solution type or an aqueous emulsion, and can be used as a low surface energy coating and a fabric finishing agent.
本发明公开了一种全氟碘化物的转化利用方法及所得产品和应用，将全氟碘化物中间体与叠氮化物进行亲核取代反应，反应完成后将所得的全氟烷基叠氮化物为含氟单体和炔基功能化的高分子材料进行1,3-偶极环加成点击反应，得到含氟1,2,3-三唑高分子化合物。本发</abstract><oa>free_for_read</oa></addata></record> |
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| subjects | ACYCLIC OR CARBOCYCLIC COMPOUNDS ADHESIVES CHEMICAL PAINT OR INK REMOVERS CHEMISTRY COATING COMPOSITIONS, e.g. PAINTS, VARNISHES ORLACQUERS COMPOSITIONS BASED THEREON CORRECTING FLUIDS DYES FILLING PASTES FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR INKS LAUNDERING MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONSONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS METALLURGY MISCELLANEOUS APPLICATIONS OF MATERIALS MISCELLANEOUS COMPOSITIONS NATURAL RESINS ORGANIC CHEMISTRY ORGANIC MACROMOLECULAR COMPOUNDS PAINTS PASTES OR SOLIDS FOR COLOURING OR PRINTING POLISHES TEXTILES THEIR PREPARATION OR CHEMICAL WORKING-UP TREATMENT OF TEXTILES OR THE LIKE TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS,FABRICS, FEATHERS, OR FIBROUS GOODS MADE FROM SUCH MATERIALS USE OF MATERIALS THEREFOR WOODSTAINS |
| title | Conversion and utilization method of perfluorinated iodide as well as obtained product and application |
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