Poly-p-phenylene terephthamide liquid crystal polymer and preparation method thereof
The invention discloses a poly-p-phenylene terephthamide liquid crystal polymer and a preparation method thereof. According to the invention, a series of novel poly-p-phenylene terephthamide are obtained through copolymerization of functionalized aromatic diether diamine, paraphthaloyl chloride and...
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creator | HUANG WENGANG WANG XIANWEN HUANG SHAN RAO XIANHUA HUANG HUAPENG |
description | The invention discloses a poly-p-phenylene terephthamide liquid crystal polymer and a preparation method thereof. According to the invention, a series of novel poly-p-phenylene terephthamide are obtained through copolymerization of functionalized aromatic diether diamine, paraphthaloyl chloride and p-phenylenediamine, the intrinsic viscosity of the prepared polymer is 1.37-2.44 dL/g, and the polymer can be completely dissolved in NMP under a heating condition; in a N2 atmosphere, the 5% thermal decomposition temperature of the polymer is 472 DEG C or above, and the glass-transition temperatureis 235-292 DEG C, so that the heat resistance of polyarylamide is maintained, and the processing formability of PPTA is improved; the prepared polymer has excellent heat resistance and mechanical properties, is good in solubility, can form a high-transparency nematic main chain type thermotropic liquid crystal polymer, and is easy to process and mold; and due to conjugation of aromatic groups, the dielectric constant of |
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According to the invention, a series of novel poly-p-phenylene terephthamide are obtained through copolymerization of functionalized aromatic diether diamine, paraphthaloyl chloride and p-phenylenediamine, the intrinsic viscosity of the prepared polymer is 1.37-2.44 dL/g, and the polymer can be completely dissolved in NMP under a heating condition; in a N2 atmosphere, the 5% thermal decomposition temperature of the polymer is 472 DEG C or above, and the glass-transition temperatureis 235-292 DEG C, so that the heat resistance of polyarylamide is maintained, and the processing formability of PPTA is improved; the prepared polymer has excellent heat resistance and mechanical properties, is good in solubility, can form a high-transparency nematic main chain type thermotropic liquid crystal polymer, and is easy to process and mold; and due to conjugation of aromatic groups, the dielectric constant of</description><language>chi ; eng</language><subject>ADHESIVES ; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F,C08G ; CHEMISTRY ; COMPOSITIONS BASED THEREON ; COMPOSITIONS OF MACROMOLECULAR COMPOUNDS ; DYES ; GENERAL PROCESSES OF COMPOUNDING ; MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONSONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS ; MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FORELSEWHERE ; METALLURGY ; MISCELLANEOUS APPLICATIONS OF MATERIALS ; MISCELLANEOUS COMPOSITIONS ; NATURAL RESINS ; ORGANIC MACROMOLECULAR COMPOUNDS ; PAINTS ; POLISHES ; THEIR PREPARATION OR CHEMICAL WORKING-UP ; WORKING-UP</subject><creationdate>2020</creationdate><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://worldwide.espacenet.com/publicationDetails/biblio?FT=D&date=20200522&DB=EPODOC&CC=CN&NR=111187410A$$EHTML$$P50$$Gepo$$Hfree_for_read</linktohtml><link.rule.ids>230,308,780,885,25564,76547</link.rule.ids><linktorsrc>$$Uhttps://worldwide.espacenet.com/publicationDetails/biblio?FT=D&date=20200522&DB=EPODOC&CC=CN&NR=111187410A$$EView_record_in_European_Patent_Office$$FView_record_in_$$GEuropean_Patent_Office$$Hfree_for_read</linktorsrc></links><search><creatorcontrib>HUANG WENGANG</creatorcontrib><creatorcontrib>WANG XIANWEN</creatorcontrib><creatorcontrib>HUANG SHAN</creatorcontrib><creatorcontrib>RAO XIANHUA</creatorcontrib><creatorcontrib>HUANG HUAPENG</creatorcontrib><title>Poly-p-phenylene terephthamide liquid crystal polymer and preparation method thereof</title><description>The invention discloses a poly-p-phenylene terephthamide liquid crystal polymer and a preparation method thereof. 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subjects | ADHESIVES AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F,C08G CHEMISTRY COMPOSITIONS BASED THEREON COMPOSITIONS OF MACROMOLECULAR COMPOUNDS DYES GENERAL PROCESSES OF COMPOUNDING MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONSONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FORELSEWHERE METALLURGY MISCELLANEOUS APPLICATIONS OF MATERIALS MISCELLANEOUS COMPOSITIONS NATURAL RESINS ORGANIC MACROMOLECULAR COMPOUNDS PAINTS POLISHES THEIR PREPARATION OR CHEMICAL WORKING-UP WORKING-UP |
title | Poly-p-phenylene terephthamide liquid crystal polymer and preparation method thereof |
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