ETCHING SOLUTION AND ETCHING CONCENTRATE FOR MULTILAYER FILM, AND ETCHING METHOD

Provided is an etching solution which is for etching a multilayer film composed of a copper layer having a large film thickness and a titanium base layer, and can be used even when the concentration of metal ions is 8,000 ppm or higher. The etching solution includes (a) hydrogen peroxide, (b) a fluo...

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Hauptverfasser: SHIRAHAMA YUJI, CHAKUNO MAKOTO
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creator SHIRAHAMA YUJI
CHAKUNO MAKOTO
description Provided is an etching solution which is for etching a multilayer film composed of a copper layer having a large film thickness and a titanium base layer, and can be used even when the concentration of metal ions is 8,000 ppm or higher. The etching solution includes (a) hydrogen peroxide, (b) a fluorine ion supply source, (c) azoles, (d) a hydrogen peroxide stabilizer, (e) an organic acid, (f) amines, and (g) water, wherein a methane sulfonic acid and one organic acid among lactic acid, succinic acid, glutaric acid, and malonic acid are used as the organic acid, or lactic acid is used alone asthe organic acid. 本发明提供一种蚀刻液,用于蚀刻膜厚较厚的铜层和基底钛层的多层膜,该蚀刻液即使在金属离子浓度达到8000ppm以上时也能够使用。该蚀刻液含有(a)过氧化氢、(b)氟离子供给源、(c)唑类、(d)过氧化氢稳定剂、(e)有机酸、(f)胺类和(g)水,所述有机酸使用甲磺酸与选自乳酸、琥珀酸、戊二酸、丙二酸中的一种有机酸,或者单独使用乳酸。
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subjects BASIC ELECTRIC ELEMENTS
CHEMICAL SURFACE TREATMENT
CHEMISTRY
COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATIONOR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
COATING MATERIAL WITH METALLIC MATERIAL
COATING METALLIC MATERIAL
DIFFUSION TREATMENT OF METALLIC MATERIAL
ELECTRIC SOLID STATE DEVICES NOT OTHERWISE PROVIDED FOR
ELECTRICITY
INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION INGENERAL
METALLURGY
MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLICMATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASSC23 AND AT LEAST ONEPROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
NON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE
SEMICONDUCTOR DEVICES
title ETCHING SOLUTION AND ETCHING CONCENTRATE FOR MULTILAYER FILM, AND ETCHING METHOD
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