Water-stable methylene blue adsorption material and preparation method and application thereof
The invention discloses a water-stable methylene blue adsorption material and a preparation method and application thereof. A chemical formula of the adsorption material is [Zn3(C21H15O6N)2(C10H8N2)].A main ligand namely 4,4',4''-triformic acid triphenylamine is subjected to coordinat...
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| creator | XUE HUI DING YAN HENG SHANGJIE PENG BO WANG XINZE LIN YAQIAN |
| description | The invention discloses a water-stable methylene blue adsorption material and a preparation method and application thereof. A chemical formula of the adsorption material is [Zn3(C21H15O6N)2(C10H8N2)].A main ligand namely 4,4',4''-triformic acid triphenylamine is subjected to coordination with metal Zn ions to form a two-dimensional laminar planar structure; by an auxiliary ligand namely 4,4'-dipyridyl, the two-dimensional laminar structure is connected into a three-dimensional network framework under the action of terminal group N atoms and Zn ions, the zinc ions form a metal center, and theporosity is 65.2%. The material is high in thermal stability and chemical stability and keeps structural integrity in water solution in pH of 2-12, and selectivity adsorption of methylene blue in a water phase can be realized.
本发明公开了种水稳定的亚甲基蓝吸附材料及其制备方法和应用。该吸附材料化学式为[Zn(CHON)(CHN)]，以4,4',4"-三甲酸三苯胺为主配体，4,4'-联吡啶为辅助配体，锌离子为金属中心，主配体通过羧酸基团和金属Zn离子配位，形成二维层状的平面结构，辅助配体4,4'-联吡啶利用端基N原子与Zn离子作用，将二维层状的结构连接为三维网络框架，孔隙率为65.2％。该材料表现出良好的热稳定性和化学 |
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本发明公开了种水稳定的亚甲基蓝吸附材料及其制备方法和应用。该吸附材料化学式为[Zn(CHON)(CHN)]，以4,4',4"-三甲酸三苯胺为主配体，4,4'-联吡啶为辅助配体，锌离子为金属中心，主配体通过羧酸基团和金属Zn离子配位，形成二维层状的平面结构，辅助配体4,4'-联吡啶利用端基N原子与Zn离子作用，将二维层状的结构连接为三维网络框架，孔隙率为65.2％。该材料表现出良好的热稳定性和化学</description><language>chi ; eng</language><subject>CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY ; CHEMISTRY ; METALLURGY ; PERFORMING OPERATIONS ; PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL ; THEIR RELEVANT APPARATUS ; TRANSPORTING ; TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE</subject><creationdate>2019</creationdate><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://worldwide.espacenet.com/publicationDetails/biblio?FT=D&date=20190219&DB=EPODOC&CC=CN&NR=109351334A$$EHTML$$P50$$Gepo$$Hfree_for_read</linktohtml><link.rule.ids>230,308,776,881,25542,76289</link.rule.ids><linktorsrc>$$Uhttps://worldwide.espacenet.com/publicationDetails/biblio?FT=D&date=20190219&DB=EPODOC&CC=CN&NR=109351334A$$EView_record_in_European_Patent_Office$$FView_record_in_$$GEuropean_Patent_Office$$Hfree_for_read</linktorsrc></links><search><creatorcontrib>XUE HUI</creatorcontrib><creatorcontrib>DING YAN</creatorcontrib><creatorcontrib>HENG SHANGJIE</creatorcontrib><creatorcontrib>PENG BO</creatorcontrib><creatorcontrib>WANG XINZE</creatorcontrib><creatorcontrib>LIN YAQIAN</creatorcontrib><title>Water-stable methylene blue adsorption material and preparation method and application thereof</title><description>The invention discloses a water-stable methylene blue adsorption material and a preparation method and application thereof. A chemical formula of the adsorption material is [Zn3(C21H15O6N)2(C10H8N2)].A main ligand namely 4,4',4''-triformic acid triphenylamine is subjected to coordination with metal Zn ions to form a two-dimensional laminar planar structure; by an auxiliary ligand namely 4,4'-dipyridyl, the two-dimensional laminar structure is connected into a three-dimensional network framework under the action of terminal group N atoms and Zn ions, the zinc ions form a metal center, and theporosity is 65.2%. The material is high in thermal stability and chemical stability and keeps structural integrity in water solution in pH of 2-12, and selectivity adsorption of methylene blue in a water phase can be realized.
本发明公开了种水稳定的亚甲基蓝吸附材料及其制备方法和应用。该吸附材料化学式为[Zn(CHON)(CHN)]，以4,4',4"-三甲酸三苯胺为主配体，4,4'-联吡啶为辅助配体，锌离子为金属中心，主配体通过羧酸基团和金属Zn离子配位，形成二维层状的平面结构，辅助配体4,4'-联吡啶利用端基N原子与Zn离子作用，将二维层状的结构连接为三维网络框架，孔隙率为65.2％。该材料表现出良好的热稳定性和化学</description><subject>CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY</subject><subject>CHEMISTRY</subject><subject>METALLURGY</subject><subject>PERFORMING OPERATIONS</subject><subject>PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL</subject><subject>THEIR RELEVANT APPARATUS</subject><subject>TRANSPORTING</subject><subject>TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE</subject><fulltext>true</fulltext><rsrctype>patent</rsrctype><creationdate>2019</creationdate><recordtype>patent</recordtype><sourceid>EVB</sourceid><recordid>eNrjZIgLTyxJLdItLklMyklVyE0tyajMSc1LVUjKKU1VSEwpzi8qKMnMz1PIBSnLTMxRSMxLUSgoSi1ILEqESAC15KeAhRMLCnIykyHCJRmpRan5aTwMrGmJOcWpvFCam0HRzTXE2UM3tSA_PrW4IDEZaFlJvLOfoYGlsamhsbGJozExagCWXT08</recordid><startdate>20190219</startdate><enddate>20190219</enddate><creator>XUE HUI</creator><creator>DING YAN</creator><creator>HENG SHANGJIE</creator><creator>PENG BO</creator><creator>WANG XINZE</creator><creator>LIN YAQIAN</creator><scope>EVB</scope></search><sort><creationdate>20190219</creationdate><title>Water-stable methylene blue adsorption material and preparation method and application thereof</title><author>XUE HUI ; DING YAN ; HENG SHANGJIE ; PENG BO ; WANG XINZE ; LIN YAQIAN</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-epo_espacenet_CN109351334A3</frbrgroupid><rsrctype>patents</rsrctype><prefilter>patents</prefilter><language>chi ; eng</language><creationdate>2019</creationdate><topic>CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY</topic><topic>CHEMISTRY</topic><topic>METALLURGY</topic><topic>PERFORMING OPERATIONS</topic><topic>PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL</topic><topic>THEIR RELEVANT APPARATUS</topic><topic>TRANSPORTING</topic><topic>TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE</topic><toplevel>online_resources</toplevel><creatorcontrib>XUE HUI</creatorcontrib><creatorcontrib>DING YAN</creatorcontrib><creatorcontrib>HENG SHANGJIE</creatorcontrib><creatorcontrib>PENG BO</creatorcontrib><creatorcontrib>WANG XINZE</creatorcontrib><creatorcontrib>LIN YAQIAN</creatorcontrib><collection>esp@cenet</collection></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext_linktorsrc</fulltext></delivery><addata><au>XUE HUI</au><au>DING YAN</au><au>HENG SHANGJIE</au><au>PENG BO</au><au>WANG XINZE</au><au>LIN YAQIAN</au><format>patent</format><genre>patent</genre><ristype>GEN</ristype><title>Water-stable methylene blue adsorption material and preparation method and application thereof</title><date>2019-02-19</date><risdate>2019</risdate><abstract>The invention discloses a water-stable methylene blue adsorption material and a preparation method and application thereof. A chemical formula of the adsorption material is [Zn3(C21H15O6N)2(C10H8N2)].A main ligand namely 4,4',4''-triformic acid triphenylamine is subjected to coordination with metal Zn ions to form a two-dimensional laminar planar structure; by an auxiliary ligand namely 4,4'-dipyridyl, the two-dimensional laminar structure is connected into a three-dimensional network framework under the action of terminal group N atoms and Zn ions, the zinc ions form a metal center, and theporosity is 65.2%. The material is high in thermal stability and chemical stability and keeps structural integrity in water solution in pH of 2-12, and selectivity adsorption of methylene blue in a water phase can be realized.
本发明公开了种水稳定的亚甲基蓝吸附材料及其制备方法和应用。该吸附材料化学式为[Zn(CHON)(CHN)]，以4,4',4"-三甲酸三苯胺为主配体，4,4'-联吡啶为辅助配体，锌离子为金属中心，主配体通过羧酸基团和金属Zn离子配位，形成二维层状的平面结构，辅助配体4,4'-联吡啶利用端基N原子与Zn离子作用，将二维层状的结构连接为三维网络框架，孔隙率为65.2％。该材料表现出良好的热稳定性和化学</abstract><oa>free_for_read</oa></addata></record> |
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| title | Water-stable methylene blue adsorption material and preparation method and application thereof |
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