Method for preparing fluorine-containing nitrile rubber through low-temperature emulsion polymerization

The invention provides a method for preparing fluorine-containing nitrile rubber by adopting a low-temperature emulsion polymerization method and a product obtained by using the method. The fluorine-containing nitrile rubber is prepared by adopting a fluorine-containing monomer emulsion polymerizati...

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Hauptverfasser: WANG ZHENQIN, LIU PENG, CAO FENGXIA, ZHANG ZHIQIANG, LI HUAINING, LI JING, HU YULIN, TIAN LI, ZHENG HONGBING, SHAO WEI, ZHENG JUCHENG, FU HANQI, GAO ZHIXING, GUI QIANG, ZHONG QILIN, GONG GUANGBI, YANG QIBO, SONG TONGJIANG, LIANG TAO, ZHANG YUANSHOU
Format: Patent
Sprache:chi ; eng
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Zusammenfassung:The invention provides a method for preparing fluorine-containing nitrile rubber by adopting a low-temperature emulsion polymerization method and a product obtained by using the method. The fluorine-containing nitrile rubber is prepared by adopting a fluorine-containing monomer emulsion polymerization method. In the polymerization process, a chelating titanate coupling agent is adopted, so that the ternary copolymerization efficiency of a fluorine-containing monomer and acrylonitrile and butadiene can be remarkably improved. A molecular weight regulator needs to be added for multiple times, and preferably, at the first time, 0.2-1 part of the molecular weight regulator is added; and when the conversion rate reaches 40%-65%, 0.05-0.2 part of the molecular weight regulator is supplemented. The comprehensive performance of the fluorine-containing nitrile rubber prepared according to the method is improved, the prepared fluorine-containing nitrile rubber is high in oil resistance and highin tensile strength, comp