Method for preparing vinyl-terminated organosilicon raw rubber

The invention discloses a method for preparing vinyl-terminated organosilicon raw rubber. The method comprises the following steps of: adopting dimethyl siloxane, silica-alkoxides, an acidic compound,vinyl group-containing hydroxy scavenger and a catalyst as raw materials, and performing vacuum dehy...

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Bibliographische Detailangaben
Hauptverfasser: XU LIQUN, REN JIE, LI LONGZHEN, QIU LIYONG
Format: Patent
Sprache:chi ; eng
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Beschreibung
Zusammenfassung:The invention discloses a method for preparing vinyl-terminated organosilicon raw rubber. The method comprises the following steps of: adopting dimethyl siloxane, silica-alkoxides, an acidic compound,vinyl group-containing hydroxy scavenger and a catalyst as raw materials, and performing vacuum dehydration, a polymerization reaction, a neutralization reaction, a hydroxy substitution reaction through vinyl groups and removal of low-boiling substances sequentially so as to obtain a finished product. The prepared vinyl-terminated organosilicon raw rubber does not contain polymer terminated by other groups than vinyl groups, and has a simple polymerization process and a controllable polymerization reaction; the product is uniform, and the method is suitable for large-scale process production;when the raw rubber is applied to preparation of a rubber compound, the powder mixing time is obviously shortened, the crosslinking reaction is more thorough, and the heat resistance and mechanical properties of the rubber co