Metal-organic framework material based on TbII, and preparation method and application thereof
The invention relates to a metal-organic framework material based on TbII, and a preparation method and application thereof. The metal-organic framework material based on TbII belongs to a monoclinic system and a P2/c space group, and is a crystal with a two-dimensional network structure. The prepar...
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creator | HAN ZHENGBO CUI LI LIU LIN WEI ZHONGYUE |
description | The invention relates to a metal-organic framework material based on TbII, and a preparation method and application thereof. The metal-organic framework material based on TbII belongs to a monoclinic system and a P2/c space group, and is a crystal with a two-dimensional network structure. The preparation method comprises the steps of adding Tb(NO3)2.6H2O, 4'-(1H-tetrazole-5)-biphenyl-3,5-dicarboxylic acid, ethyl alcohol and N,N'-dimethylformamide into a container, and stirring for 15 minutes at normal temperature; sealing the container, putting in a drying oven, and keeping for 36 hours under 358K. The material synthesized by the invention can be used as a sensor applied in detection of aluminum ions. The metal-organic framework material based on TbII can be used for sensitively and quickly detecting trace aluminum ions, the fluorescence intensity of the metal-organic framework material based on TbII can be gradually quenched along with the increase of aluminum ion concentration, and the metal-organic framewo |
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The metal-organic framework material based on TbII belongs to a monoclinic system and a P2/c space group, and is a crystal with a two-dimensional network structure. The preparation method comprises the steps of adding Tb(NO3)2.6H2O, 4'-(1H-tetrazole-5)-biphenyl-3,5-dicarboxylic acid, ethyl alcohol and N,N'-dimethylformamide into a container, and stirring for 15 minutes at normal temperature; sealing the container, putting in a drying oven, and keeping for 36 hours under 358K. The material synthesized by the invention can be used as a sensor applied in detection of aluminum ions. The metal-organic framework material based on TbII can be used for sensitively and quickly detecting trace aluminum ions, the fluorescence intensity of the metal-organic framework material based on TbII can be gradually quenched along with the increase of aluminum ion concentration, and the metal-organic framewo</description><language>chi ; eng</language><subject>ADHESIVES ; CHEMISTRY ; COMPOSITIONS BASED THEREON ; DYES ; INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIRCHEMICAL OR PHYSICAL PROPERTIES ; MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONSONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS ; MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FORELSEWHERE ; MEASURING ; METALLURGY ; MISCELLANEOUS APPLICATIONS OF MATERIALS ; MISCELLANEOUS COMPOSITIONS ; NATURAL RESINS ; ORGANIC MACROMOLECULAR COMPOUNDS ; PAINTS ; PHYSICS ; POLISHES ; TESTING ; THEIR PREPARATION OR CHEMICAL WORKING-UP</subject><creationdate>2017</creationdate><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://worldwide.espacenet.com/publicationDetails/biblio?FT=D&date=20170613&DB=EPODOC&CC=CN&NR=106832320A$$EHTML$$P50$$Gepo$$Hfree_for_read</linktohtml><link.rule.ids>230,308,780,885,25564,76547</link.rule.ids><linktorsrc>$$Uhttps://worldwide.espacenet.com/publicationDetails/biblio?FT=D&date=20170613&DB=EPODOC&CC=CN&NR=106832320A$$EView_record_in_European_Patent_Office$$FView_record_in_$$GEuropean_Patent_Office$$Hfree_for_read</linktorsrc></links><search><creatorcontrib>HAN ZHENGBO</creatorcontrib><creatorcontrib>CUI LI</creatorcontrib><creatorcontrib>LIU LIN</creatorcontrib><creatorcontrib>WEI ZHONGYUE</creatorcontrib><title>Metal-organic framework material based on TbII, and preparation method and application thereof</title><description>The invention relates to a metal-organic framework material based on TbII, and a preparation method and application thereof. 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The metal-organic framework material based on TbII belongs to a monoclinic system and a P2/c space group, and is a crystal with a two-dimensional network structure. The preparation method comprises the steps of adding Tb(NO3)2.6H2O, 4'-(1H-tetrazole-5)-biphenyl-3,5-dicarboxylic acid, ethyl alcohol and N,N'-dimethylformamide into a container, and stirring for 15 minutes at normal temperature; sealing the container, putting in a drying oven, and keeping for 36 hours under 358K. The material synthesized by the invention can be used as a sensor applied in detection of aluminum ions. The metal-organic framework material based on TbII can be used for sensitively and quickly detecting trace aluminum ions, the fluorescence intensity of the metal-organic framework material based on TbII can be gradually quenched along with the increase of aluminum ion concentration, and the metal-organic framewo</abstract><oa>free_for_read</oa></addata></record> |
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subjects | ADHESIVES CHEMISTRY COMPOSITIONS BASED THEREON DYES INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIRCHEMICAL OR PHYSICAL PROPERTIES MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONSONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FORELSEWHERE MEASURING METALLURGY MISCELLANEOUS APPLICATIONS OF MATERIALS MISCELLANEOUS COMPOSITIONS NATURAL RESINS ORGANIC MACROMOLECULAR COMPOUNDS PAINTS PHYSICS POLISHES TESTING THEIR PREPARATION OR CHEMICAL WORKING-UP |
title | Metal-organic framework material based on TbII, and preparation method and application thereof |
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