PROCESS FOR SIMULTANEOUS PREPARATION OF ACETIC ACID AND ACETIC ANHYDRIDE
A process for simultaneous production of acetic acid and acetic anhydride from a starting mixture of methanol and methyl acetate and optionally dimethyl ether by reaction with carbon monoxide in a reaction zone on a catalyst system under anhydrous conditions is specified, which is characterised in t...
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| creator | REINHARD GRADL ERHARD JAGERS HEINZ ERPENBACH |
| description | A process for simultaneous production of acetic acid and acetic anhydride from a starting mixture of methanol and methyl acetate and optionally dimethyl ether by reaction with carbon monoxide in a reaction zone on a catalyst system under anhydrous conditions is specified, which is characterised in that a) the reaction is carried out in the presence of a catalyst system consisting of a base metal of group VIII of the Periodic Table, methyl iodide, an alkali metal, organophosphonium or organoammonium compound as promoter and optionally a compound of a base metal of groups IV to VII of the Periodic Table as co-promoter; b) a molar ratio of methanol to methyl acetate and optionally dimethyl ether of 10 : 1 to 1 : 10 as starting mixture is employed and c) the reaction is carried out under a pressure of 25 to 200 bar and at a temperature of 150 to 250 DEG C. n |
| format | Patent |
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| subjects | ACYCLIC OR CARBOCYCLIC COMPOUNDS APPARATUS THEREFOR CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY CHEMISTRY GENERAL METHODS OF ORGANIC CHEMISTRY METALLURGY ORGANIC CHEMISTRY PERFORMING OPERATIONS PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL THEIR RELEVANT APPARATUS TRANSPORTING |
| title | PROCESS FOR SIMULTANEOUS PREPARATION OF ACETIC ACID AND ACETIC ANHYDRIDE |
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