Method for catalytically synthesizing tetracyclic[7.3.1.0<2.7>.1<7.11>]tetradecane through solid acid

The invention provides a method for catalytically synthesizing tetracyclic[7.3.1.0.1]tetradecane through solid acid, and aims at solving the problems that in an reaction of the prior art, a large amount of acidic organic wastewater is generated, and a catalyst and reaction liquid are difficult to separate.The method for synthesizing tetracyclic[7.3.1.0.1]tetradecane comprises the steps that under the action of a loaded aluminum trichloride catalyst, tetracyclic[7.4.0.0.1]tetradecane is catalyzed in organic solvent to generate an isomerization reaction to generate tetracyclic[7.3.1.0.1]tetradecane.The compound has the high density and volume combustion heat and can be used in an aircraft by serving as high-density hydrocarbon fuel or an additive. 本发明提供种固体酸催化合成四环[7.3.1.0.1]十四烷的方法，是为了解决现有技术反应中产生大量酸性有机废水、催化剂与反应液难于分离的问题。本发明的四环[7.3.1.0.1]十四烷合成方法为：在负载型三氯化铝催化剂作用下，在有机溶剂中催化四环[7.4.0.0.1]十四烷异构化反应生成四环[7.3.1.0.1]十四烷。该化合物具有较高的密度和体积燃烧热，可作为种高密度烃燃料或添加剂用于飞行器中。