Preparation process for core-shell nanoparticle emulsion for impact modification of aqueous epoxy resin

The present invention discloses a preparation process for a core-shell nanoparticle emulsion for impact modification of aqueous epoxy resin. The preparation method comprises the following steps of: step A, using a sol-gel method to prepare uniformly dispersed nanosilica, and using a silane coupling...

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Hauptverfasser: LI QIN, SHI DEAN, ZHAO HUI, JIANG TAO, JIANG HAI, WANG GUOCHENG, ZHANG QUNCHAO, ZOU HANG, REN XIAOMING, JIANG LILI, ZHANG GANGSHEN, ZHANG JING
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creator LI QIN
SHI DEAN
ZHAO HUI
JIANG TAO
JIANG HAI
WANG GUOCHENG
ZHANG QUNCHAO
ZOU HANG
REN XIAOMING
JIANG LILI
ZHANG GANGSHEN
ZHANG JING
description The present invention discloses a preparation process for a core-shell nanoparticle emulsion for impact modification of aqueous epoxy resin. The preparation method comprises the following steps of: step A, using a sol-gel method to prepare uniformly dispersed nanosilica, and using a silane coupling agent to conduct surface hydrophobic modification on the nanosilica to obtain hydrophobic nanosilica; and step B, using a micro-suspended seed emulsion polymerization method and the hydrophobic nanosilica obtained in step A as a core structure, and using methacrylate and a glycidyl methacrylate monomer to conduct polymer coating to obtain the product. Core-shell structure nanoparticles prepared by the preparation process, using silica as the core with the surface coated with polymers, have the advantages of high coating rate, uniform size and same shell thickness.
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subjects CHEMISTRY
COMPOSITIONS BASED THEREON
COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVINGCARBON-TO-CARBON UNSATURATED BONDS
METALLURGY
ORGANIC MACROMOLECULAR COMPOUNDS
THEIR PREPARATION OR CHEMICAL WORKING-UP
USE OF INORGANIC OR NON-MACROMOLECULAR ORGANIC SUBSTANCES ASCOMPOUNDING INGREDIENTS
title Preparation process for core-shell nanoparticle emulsion for impact modification of aqueous epoxy resin
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