Early-strength polycarboxylate superplasticizer and preparation method thereof

The invention discloses an early-strength polycarboxylate superplasticizer and a preparation method thereof. The water reducer is prepared from raw materials in parts by weight as follows: 200 parts of unsaturated polyether, 10-30 parts of acrylic acid, 1-3 parts of an amide derivative, 0.1-0.5 part...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Hauptverfasser: LAI HUAZHEN, LAI GUANGXING, LIN YANMEI, LIN QIAN, FANG YUNHUI, LIU MULIN, LI GELI, ZHENG RONGPING
Format: Patent
Sprache:eng
Schlagworte:
Online-Zugang:Volltext bestellen
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
container_end_page
container_issue
container_start_page
container_title
container_volume
creator LAI HUAZHEN
LAI GUANGXING
LIN YANMEI
LIN QIAN
FANG YUNHUI
LIU MULIN
LI GELI
ZHENG RONGPING
description The invention discloses an early-strength polycarboxylate superplasticizer and a preparation method thereof. The water reducer is prepared from raw materials in parts by weight as follows: 200 parts of unsaturated polyether, 10-30 parts of acrylic acid, 1-3 parts of an amide derivative, 0.1-0.5 parts of mohr's salt, 0.5-1.5 parts of a chain transfer agent, 0.2-0.8 parts of L-ascorbic acid, 0.8-4 parts of an oxidizing agent, 230 parts of deionized water and 12-20 parts of a 30% sodium hydroxide solution. The unsaturated polyether with a larger molecular weight is used, that is, a long side chain is introduced into a polycarboxylate superplasticizer molecule, quaternary amine and amide functional groups exist on a main chain, early hydration of hydration products, namely C3A and C3S, can be promoted, crystallization of Ca(OH)2 and forming of ettringite can be accelerated, the concrete setting time can be effectively shortened, the compactness of an early microstructure is improved, the early mechanical property of cement grout can be substantially improved, and the polycarboxylate superplasticizer promotes early-strength development of concrete and shows excellent early-strength performance from a macroscopic view.
format Patent
fullrecord <record><control><sourceid>epo_EVB</sourceid><recordid>TN_cdi_epo_espacenet_CN105017491A</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>CN105017491A</sourcerecordid><originalsourceid>FETCH-epo_espacenet_CN105017491A3</originalsourceid><addsrcrecordid>eNqNyrEKwjAQBuAsDqK-Q3yAQouKOEqpOHVyL2f71wRiclxOMD69iw_g9C3f0vQdSShVVkF8qLOcQhlJ7uldAilsfjGEA2X1o_9ALMXJsoBJSH2K9gl1abLqIEjz2ixmChmbnyuzvXS39lqB04DMNCJCh7Zv6kPdHPen5rz753wB3-M4Bw</addsrcrecordid><sourcetype>Open Access Repository</sourcetype><iscdi>true</iscdi><recordtype>patent</recordtype></control><display><type>patent</type><title>Early-strength polycarboxylate superplasticizer and preparation method thereof</title><source>esp@cenet</source><creator>LAI HUAZHEN ; LAI GUANGXING ; LIN YANMEI ; LIN QIAN ; FANG YUNHUI ; LIU MULIN ; LI GELI ; ZHENG RONGPING</creator><creatorcontrib>LAI HUAZHEN ; LAI GUANGXING ; LIN YANMEI ; LIN QIAN ; FANG YUNHUI ; LIU MULIN ; LI GELI ; ZHENG RONGPING</creatorcontrib><description>The invention discloses an early-strength polycarboxylate superplasticizer and a preparation method thereof. The water reducer is prepared from raw materials in parts by weight as follows: 200 parts of unsaturated polyether, 10-30 parts of acrylic acid, 1-3 parts of an amide derivative, 0.1-0.5 parts of mohr's salt, 0.5-1.5 parts of a chain transfer agent, 0.2-0.8 parts of L-ascorbic acid, 0.8-4 parts of an oxidizing agent, 230 parts of deionized water and 12-20 parts of a 30% sodium hydroxide solution. The unsaturated polyether with a larger molecular weight is used, that is, a long side chain is introduced into a polycarboxylate superplasticizer molecule, quaternary amine and amide functional groups exist on a main chain, early hydration of hydration products, namely C3A and C3S, can be promoted, crystallization of Ca(OH)2 and forming of ettringite can be accelerated, the concrete setting time can be effectively shortened, the compactness of an early microstructure is improved, the early mechanical property of cement grout can be substantially improved, and the polycarboxylate superplasticizer promotes early-strength development of concrete and shows excellent early-strength performance from a macroscopic view.</description><language>eng</language><subject>ARTIFICIAL STONE ; CEMENTS ; CERAMICS ; CHEMISTRY ; COMPOSITIONS BASED THEREON ; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDINGMATERIALS ; CONCRETE ; LIME, MAGNESIA ; MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVINGCARBON-TO-CARBON UNSATURATED BONDS ; METALLURGY ; ORGANIC MACROMOLECULAR COMPOUNDS ; REFRACTORIES ; SLAG ; THEIR PREPARATION OR CHEMICAL WORKING-UP ; TREATMENT OF NATURAL STONE</subject><creationdate>2015</creationdate><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://worldwide.espacenet.com/publicationDetails/biblio?FT=D&amp;date=20151104&amp;DB=EPODOC&amp;CC=CN&amp;NR=105017491A$$EHTML$$P50$$Gepo$$Hfree_for_read</linktohtml><link.rule.ids>230,308,780,885,25564,76547</link.rule.ids><linktorsrc>$$Uhttps://worldwide.espacenet.com/publicationDetails/biblio?FT=D&amp;date=20151104&amp;DB=EPODOC&amp;CC=CN&amp;NR=105017491A$$EView_record_in_European_Patent_Office$$FView_record_in_$$GEuropean_Patent_Office$$Hfree_for_read</linktorsrc></links><search><creatorcontrib>LAI HUAZHEN</creatorcontrib><creatorcontrib>LAI GUANGXING</creatorcontrib><creatorcontrib>LIN YANMEI</creatorcontrib><creatorcontrib>LIN QIAN</creatorcontrib><creatorcontrib>FANG YUNHUI</creatorcontrib><creatorcontrib>LIU MULIN</creatorcontrib><creatorcontrib>LI GELI</creatorcontrib><creatorcontrib>ZHENG RONGPING</creatorcontrib><title>Early-strength polycarboxylate superplasticizer and preparation method thereof</title><description>The invention discloses an early-strength polycarboxylate superplasticizer and a preparation method thereof. The water reducer is prepared from raw materials in parts by weight as follows: 200 parts of unsaturated polyether, 10-30 parts of acrylic acid, 1-3 parts of an amide derivative, 0.1-0.5 parts of mohr's salt, 0.5-1.5 parts of a chain transfer agent, 0.2-0.8 parts of L-ascorbic acid, 0.8-4 parts of an oxidizing agent, 230 parts of deionized water and 12-20 parts of a 30% sodium hydroxide solution. The unsaturated polyether with a larger molecular weight is used, that is, a long side chain is introduced into a polycarboxylate superplasticizer molecule, quaternary amine and amide functional groups exist on a main chain, early hydration of hydration products, namely C3A and C3S, can be promoted, crystallization of Ca(OH)2 and forming of ettringite can be accelerated, the concrete setting time can be effectively shortened, the compactness of an early microstructure is improved, the early mechanical property of cement grout can be substantially improved, and the polycarboxylate superplasticizer promotes early-strength development of concrete and shows excellent early-strength performance from a macroscopic view.</description><subject>ARTIFICIAL STONE</subject><subject>CEMENTS</subject><subject>CERAMICS</subject><subject>CHEMISTRY</subject><subject>COMPOSITIONS BASED THEREON</subject><subject>COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDINGMATERIALS</subject><subject>CONCRETE</subject><subject>LIME, MAGNESIA</subject><subject>MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVINGCARBON-TO-CARBON UNSATURATED BONDS</subject><subject>METALLURGY</subject><subject>ORGANIC MACROMOLECULAR COMPOUNDS</subject><subject>REFRACTORIES</subject><subject>SLAG</subject><subject>THEIR PREPARATION OR CHEMICAL WORKING-UP</subject><subject>TREATMENT OF NATURAL STONE</subject><fulltext>true</fulltext><rsrctype>patent</rsrctype><creationdate>2015</creationdate><recordtype>patent</recordtype><sourceid>EVB</sourceid><recordid>eNqNyrEKwjAQBuAsDqK-Q3yAQouKOEqpOHVyL2f71wRiclxOMD69iw_g9C3f0vQdSShVVkF8qLOcQhlJ7uldAilsfjGEA2X1o_9ALMXJsoBJSH2K9gl1abLqIEjz2ixmChmbnyuzvXS39lqB04DMNCJCh7Zv6kPdHPen5rz753wB3-M4Bw</recordid><startdate>20151104</startdate><enddate>20151104</enddate><creator>LAI HUAZHEN</creator><creator>LAI GUANGXING</creator><creator>LIN YANMEI</creator><creator>LIN QIAN</creator><creator>FANG YUNHUI</creator><creator>LIU MULIN</creator><creator>LI GELI</creator><creator>ZHENG RONGPING</creator><scope>EVB</scope></search><sort><creationdate>20151104</creationdate><title>Early-strength polycarboxylate superplasticizer and preparation method thereof</title><author>LAI HUAZHEN ; LAI GUANGXING ; LIN YANMEI ; LIN QIAN ; FANG YUNHUI ; LIU MULIN ; LI GELI ; ZHENG RONGPING</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-epo_espacenet_CN105017491A3</frbrgroupid><rsrctype>patents</rsrctype><prefilter>patents</prefilter><language>eng</language><creationdate>2015</creationdate><topic>ARTIFICIAL STONE</topic><topic>CEMENTS</topic><topic>CERAMICS</topic><topic>CHEMISTRY</topic><topic>COMPOSITIONS BASED THEREON</topic><topic>COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDINGMATERIALS</topic><topic>CONCRETE</topic><topic>LIME, MAGNESIA</topic><topic>MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVINGCARBON-TO-CARBON UNSATURATED BONDS</topic><topic>METALLURGY</topic><topic>ORGANIC MACROMOLECULAR COMPOUNDS</topic><topic>REFRACTORIES</topic><topic>SLAG</topic><topic>THEIR PREPARATION OR CHEMICAL WORKING-UP</topic><topic>TREATMENT OF NATURAL STONE</topic><toplevel>online_resources</toplevel><creatorcontrib>LAI HUAZHEN</creatorcontrib><creatorcontrib>LAI GUANGXING</creatorcontrib><creatorcontrib>LIN YANMEI</creatorcontrib><creatorcontrib>LIN QIAN</creatorcontrib><creatorcontrib>FANG YUNHUI</creatorcontrib><creatorcontrib>LIU MULIN</creatorcontrib><creatorcontrib>LI GELI</creatorcontrib><creatorcontrib>ZHENG RONGPING</creatorcontrib><collection>esp@cenet</collection></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext_linktorsrc</fulltext></delivery><addata><au>LAI HUAZHEN</au><au>LAI GUANGXING</au><au>LIN YANMEI</au><au>LIN QIAN</au><au>FANG YUNHUI</au><au>LIU MULIN</au><au>LI GELI</au><au>ZHENG RONGPING</au><format>patent</format><genre>patent</genre><ristype>GEN</ristype><title>Early-strength polycarboxylate superplasticizer and preparation method thereof</title><date>2015-11-04</date><risdate>2015</risdate><abstract>The invention discloses an early-strength polycarboxylate superplasticizer and a preparation method thereof. The water reducer is prepared from raw materials in parts by weight as follows: 200 parts of unsaturated polyether, 10-30 parts of acrylic acid, 1-3 parts of an amide derivative, 0.1-0.5 parts of mohr's salt, 0.5-1.5 parts of a chain transfer agent, 0.2-0.8 parts of L-ascorbic acid, 0.8-4 parts of an oxidizing agent, 230 parts of deionized water and 12-20 parts of a 30% sodium hydroxide solution. The unsaturated polyether with a larger molecular weight is used, that is, a long side chain is introduced into a polycarboxylate superplasticizer molecule, quaternary amine and amide functional groups exist on a main chain, early hydration of hydration products, namely C3A and C3S, can be promoted, crystallization of Ca(OH)2 and forming of ettringite can be accelerated, the concrete setting time can be effectively shortened, the compactness of an early microstructure is improved, the early mechanical property of cement grout can be substantially improved, and the polycarboxylate superplasticizer promotes early-strength development of concrete and shows excellent early-strength performance from a macroscopic view.</abstract><oa>free_for_read</oa></addata></record>
fulltext fulltext_linktorsrc
identifier
ispartof
issn
language eng
recordid cdi_epo_espacenet_CN105017491A
source esp@cenet
subjects ARTIFICIAL STONE
CEMENTS
CERAMICS
CHEMISTRY
COMPOSITIONS BASED THEREON
COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDINGMATERIALS
CONCRETE
LIME, MAGNESIA
MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVINGCARBON-TO-CARBON UNSATURATED BONDS
METALLURGY
ORGANIC MACROMOLECULAR COMPOUNDS
REFRACTORIES
SLAG
THEIR PREPARATION OR CHEMICAL WORKING-UP
TREATMENT OF NATURAL STONE
title Early-strength polycarboxylate superplasticizer and preparation method thereof
url https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-07T11%3A12%3A03IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-epo_EVB&rft_val_fmt=info:ofi/fmt:kev:mtx:patent&rft.genre=patent&rft.au=LAI%20HUAZHEN&rft.date=2015-11-04&rft_id=info:doi/&rft_dat=%3Cepo_EVB%3ECN105017491A%3C/epo_EVB%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true