Preparation method of linear low density polyethylene
The invention discloses a preparation method of linear low density polyethylene. By using an alkylaluminium-preactivated supported TiCl4/MgCl2 catalyst as a main catalyst, using alkylaluminium as a cocatalyst and using H2 as a molecular weight modifier, ethene and alpha-olefin undergo a slurry polym...
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creator | DA WENZHONG FAN ZHIQIANG FU ZHISHENG WANG XINGREN HU QINGYUN LI DONG MEI LI |
description | The invention discloses a preparation method of linear low density polyethylene. By using an alkylaluminium-preactivated supported TiCl4/MgCl2 catalyst as a main catalyst, using alkylaluminium as a cocatalyst and using H2 as a molecular weight modifier, ethene and alpha-olefin undergo a slurry polymerization reaction so as to obtain the linear low density polyethylene. The preparation method of the linear low density polyethylene is suitable for a production device of linear low density polyethylene with the supported TiCl4/MgCl2 catalyst used as a main catalyst. In comparison with a metallocene catalysis system, the production process of the invention is easy to control, use amount of the cocatalyst is low, production cost is low, insert quantity of alpha-olefin in the prepared linear low density polyethylene is high, composition and distribution of a copolymer are uniform, tensile property of the copolymer is good, and the copolymer has better application characteristics. |
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By using an alkylaluminium-preactivated supported TiCl4/MgCl2 catalyst as a main catalyst, using alkylaluminium as a cocatalyst and using H2 as a molecular weight modifier, ethene and alpha-olefin undergo a slurry polymerization reaction so as to obtain the linear low density polyethylene. The preparation method of the linear low density polyethylene is suitable for a production device of linear low density polyethylene with the supported TiCl4/MgCl2 catalyst used as a main catalyst. In comparison with a metallocene catalysis system, the production process of the invention is easy to control, use amount of the cocatalyst is low, production cost is low, insert quantity of alpha-olefin in the prepared linear low density polyethylene is high, composition and distribution of a copolymer are uniform, tensile property of the copolymer is good, and the copolymer has better application characteristics.</description><language>eng</language><subject>CHEMISTRY ; COMPOSITIONS BASED THEREON ; MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVINGCARBON-TO-CARBON UNSATURATED BONDS ; METALLURGY ; ORGANIC MACROMOLECULAR COMPOUNDS ; THEIR PREPARATION OR CHEMICAL WORKING-UP</subject><creationdate>2015</creationdate><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://worldwide.espacenet.com/publicationDetails/biblio?FT=D&date=20151104&DB=EPODOC&CC=CN&NR=105017454A$$EHTML$$P50$$Gepo$$Hfree_for_read</linktohtml><link.rule.ids>230,309,781,886,25569,76552</link.rule.ids><linktorsrc>$$Uhttps://worldwide.espacenet.com/publicationDetails/biblio?FT=D&date=20151104&DB=EPODOC&CC=CN&NR=105017454A$$EView_record_in_European_Patent_Office$$FView_record_in_$$GEuropean_Patent_Office$$Hfree_for_read</linktorsrc></links><search><creatorcontrib>DA WENZHONG</creatorcontrib><creatorcontrib>FAN ZHIQIANG</creatorcontrib><creatorcontrib>FU ZHISHENG</creatorcontrib><creatorcontrib>WANG XINGREN</creatorcontrib><creatorcontrib>HU QINGYUN</creatorcontrib><creatorcontrib>LI DONG</creatorcontrib><creatorcontrib>MEI LI</creatorcontrib><title>Preparation method of linear low density polyethylene</title><description>The invention discloses a preparation method of linear low density polyethylene. By using an alkylaluminium-preactivated supported TiCl4/MgCl2 catalyst as a main catalyst, using alkylaluminium as a cocatalyst and using H2 as a molecular weight modifier, ethene and alpha-olefin undergo a slurry polymerization reaction so as to obtain the linear low density polyethylene. The preparation method of the linear low density polyethylene is suitable for a production device of linear low density polyethylene with the supported TiCl4/MgCl2 catalyst used as a main catalyst. In comparison with a metallocene catalysis system, the production process of the invention is easy to control, use amount of the cocatalyst is low, production cost is low, insert quantity of alpha-olefin in the prepared linear low density polyethylene is high, composition and distribution of a copolymer are uniform, tensile property of the copolymer is good, and the copolymer has better application characteristics.</description><subject>CHEMISTRY</subject><subject>COMPOSITIONS BASED THEREON</subject><subject>MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVINGCARBON-TO-CARBON UNSATURATED BONDS</subject><subject>METALLURGY</subject><subject>ORGANIC MACROMOLECULAR COMPOUNDS</subject><subject>THEIR PREPARATION OR CHEMICAL WORKING-UP</subject><fulltext>true</fulltext><rsrctype>patent</rsrctype><creationdate>2015</creationdate><recordtype>patent</recordtype><sourceid>EVB</sourceid><recordid>eNrjZDANKEotSCxKLMnMz1PITS3JyE9RyE9TyMnMS00sUsjJL1dISc0rziypVCjIz6kEylfmpOal8jCwpiXmFKfyQmluBkU31xBnD93Ugvz41OKCxGSgopJ4Zz9DA1MDQ3MTUxNHY2LUAACYDC2c</recordid><startdate>20151104</startdate><enddate>20151104</enddate><creator>DA WENZHONG</creator><creator>FAN ZHIQIANG</creator><creator>FU ZHISHENG</creator><creator>WANG XINGREN</creator><creator>HU QINGYUN</creator><creator>LI DONG</creator><creator>MEI LI</creator><scope>EVB</scope></search><sort><creationdate>20151104</creationdate><title>Preparation method of linear low density polyethylene</title><author>DA WENZHONG ; FAN ZHIQIANG ; FU ZHISHENG ; WANG XINGREN ; HU QINGYUN ; LI DONG ; MEI LI</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-epo_espacenet_CN105017454A3</frbrgroupid><rsrctype>patents</rsrctype><prefilter>patents</prefilter><language>eng</language><creationdate>2015</creationdate><topic>CHEMISTRY</topic><topic>COMPOSITIONS BASED THEREON</topic><topic>MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVINGCARBON-TO-CARBON UNSATURATED BONDS</topic><topic>METALLURGY</topic><topic>ORGANIC MACROMOLECULAR COMPOUNDS</topic><topic>THEIR PREPARATION OR CHEMICAL WORKING-UP</topic><toplevel>online_resources</toplevel><creatorcontrib>DA WENZHONG</creatorcontrib><creatorcontrib>FAN ZHIQIANG</creatorcontrib><creatorcontrib>FU ZHISHENG</creatorcontrib><creatorcontrib>WANG XINGREN</creatorcontrib><creatorcontrib>HU QINGYUN</creatorcontrib><creatorcontrib>LI DONG</creatorcontrib><creatorcontrib>MEI LI</creatorcontrib><collection>esp@cenet</collection></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext_linktorsrc</fulltext></delivery><addata><au>DA WENZHONG</au><au>FAN ZHIQIANG</au><au>FU ZHISHENG</au><au>WANG XINGREN</au><au>HU QINGYUN</au><au>LI DONG</au><au>MEI LI</au><format>patent</format><genre>patent</genre><ristype>GEN</ristype><title>Preparation method of linear low density polyethylene</title><date>2015-11-04</date><risdate>2015</risdate><abstract>The invention discloses a preparation method of linear low density polyethylene. By using an alkylaluminium-preactivated supported TiCl4/MgCl2 catalyst as a main catalyst, using alkylaluminium as a cocatalyst and using H2 as a molecular weight modifier, ethene and alpha-olefin undergo a slurry polymerization reaction so as to obtain the linear low density polyethylene. The preparation method of the linear low density polyethylene is suitable for a production device of linear low density polyethylene with the supported TiCl4/MgCl2 catalyst used as a main catalyst. In comparison with a metallocene catalysis system, the production process of the invention is easy to control, use amount of the cocatalyst is low, production cost is low, insert quantity of alpha-olefin in the prepared linear low density polyethylene is high, composition and distribution of a copolymer are uniform, tensile property of the copolymer is good, and the copolymer has better application characteristics.</abstract><oa>free_for_read</oa></addata></record> |
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title | Preparation method of linear low density polyethylene |
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