Preparation method of n-butylamine propyl trimethoxy silane
The invention discloses a preparation method of n-butylamine propyl trimethoxy silane, wherein the preparation method comprises the following steps: (1) putting n-butylamine and chloropropyl trimethoxy silane into a reaction kettle, beginning to a temperature-rising reaction under stirring, and cont...
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creator | LIU LEI SHU YAFEI DAI JIANCAI LU YUNLONG ZHAO SHIYONG ZHU HUI YUE LI |
description | The invention discloses a preparation method of n-butylamine propyl trimethoxy silane, wherein the preparation method comprises the following steps: (1) putting n-butylamine and chloropropyl trimethoxy silane into a reaction kettle, beginning to a temperature-rising reaction under stirring, and controlling the reaction pressure to be 0.5 MPa-2 MPa and the reaction temperature to be 75-120 DEG C; (2) after the reaction of the step (1) is finished, controlling the temperature in the reaction kettle to be 40-50 DEG C, then adding sodium methoxide to the reaction liquid, and continuing a stirring reaction; after the reaction is finished, carrying out solid-liquid separation on the reaction liquid, and separating out a filtrate and a sodium chloride precipitate; and (3) carrying out reduced pressure distillation on the filtrate separated out in the step (2), and separating unreacted n-butylamine, generated alcohol and the required product n-butylamine propyl trimethoxy silane, to obtain the high-purity product n-butylamine propyl trimethoxy silane. The whole preparation method is simple in process, production costs can be greatly reduced, and more than 84% of the molar yield can be obtained. |
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The whole preparation method is simple in process, production costs can be greatly reduced, and more than 84% of the molar yield can be obtained.</description><language>eng</language><subject>ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAININGELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN,SULFUR, SELENIUM OR TELLURIUM ; CHEMISTRY ; METALLURGY ; ORGANIC CHEMISTRY</subject><creationdate>2015</creationdate><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://worldwide.espacenet.com/publicationDetails/biblio?FT=D&date=20150923&DB=EPODOC&CC=CN&NR=104926852A$$EHTML$$P50$$Gepo$$Hfree_for_read</linktohtml><link.rule.ids>230,308,777,882,25545,76296</link.rule.ids><linktorsrc>$$Uhttps://worldwide.espacenet.com/publicationDetails/biblio?FT=D&date=20150923&DB=EPODOC&CC=CN&NR=104926852A$$EView_record_in_European_Patent_Office$$FView_record_in_$$GEuropean_Patent_Office$$Hfree_for_read</linktorsrc></links><search><creatorcontrib>LIU LEI</creatorcontrib><creatorcontrib>SHU YAFEI</creatorcontrib><creatorcontrib>DAI JIANCAI</creatorcontrib><creatorcontrib>LU YUNLONG</creatorcontrib><creatorcontrib>ZHAO SHIYONG</creatorcontrib><creatorcontrib>ZHU HUI</creatorcontrib><creatorcontrib>YUE LI</creatorcontrib><title>Preparation method of n-butylamine propyl trimethoxy silane</title><description>The invention discloses a preparation method of n-butylamine propyl trimethoxy silane, wherein the preparation method comprises the following steps: (1) putting n-butylamine and chloropropyl trimethoxy silane into a reaction kettle, beginning to a temperature-rising reaction under stirring, and controlling the reaction pressure to be 0.5 MPa-2 MPa and the reaction temperature to be 75-120 DEG C; (2) after the reaction of the step (1) is finished, controlling the temperature in the reaction kettle to be 40-50 DEG C, then adding sodium methoxide to the reaction liquid, and continuing a stirring reaction; after the reaction is finished, carrying out solid-liquid separation on the reaction liquid, and separating out a filtrate and a sodium chloride precipitate; and (3) carrying out reduced pressure distillation on the filtrate separated out in the step (2), and separating unreacted n-butylamine, generated alcohol and the required product n-butylamine propyl trimethoxy silane, to obtain the high-purity product n-butylamine propyl trimethoxy silane. The whole preparation method is simple in process, production costs can be greatly reduced, and more than 84% of the molar yield can be obtained.</description><subject>ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAININGELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN,SULFUR, SELENIUM OR TELLURIUM</subject><subject>CHEMISTRY</subject><subject>METALLURGY</subject><subject>ORGANIC CHEMISTRY</subject><fulltext>true</fulltext><rsrctype>patent</rsrctype><creationdate>2015</creationdate><recordtype>patent</recordtype><sourceid>EVB</sourceid><recordid>eNrjZLAOKEotSCxKLMnMz1PITS3JyE9RyE9TyNNNKi2pzEnMzcxLVSgoyi-ozFEoKcoEK6ioVCjOzEnMS-VhYE1LzClO5YXS3AyKbq4hzh66qQX58anFBYnJqXmpJfHOfoYGJpZGZhamRo7GxKgBAPgSMBs</recordid><startdate>20150923</startdate><enddate>20150923</enddate><creator>LIU LEI</creator><creator>SHU YAFEI</creator><creator>DAI JIANCAI</creator><creator>LU YUNLONG</creator><creator>ZHAO SHIYONG</creator><creator>ZHU HUI</creator><creator>YUE LI</creator><scope>EVB</scope></search><sort><creationdate>20150923</creationdate><title>Preparation method of n-butylamine propyl trimethoxy silane</title><author>LIU LEI ; SHU YAFEI ; DAI JIANCAI ; LU YUNLONG ; ZHAO SHIYONG ; ZHU HUI ; YUE LI</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-epo_espacenet_CN104926852A3</frbrgroupid><rsrctype>patents</rsrctype><prefilter>patents</prefilter><language>eng</language><creationdate>2015</creationdate><topic>ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAININGELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN,SULFUR, SELENIUM OR TELLURIUM</topic><topic>CHEMISTRY</topic><topic>METALLURGY</topic><topic>ORGANIC CHEMISTRY</topic><toplevel>online_resources</toplevel><creatorcontrib>LIU LEI</creatorcontrib><creatorcontrib>SHU YAFEI</creatorcontrib><creatorcontrib>DAI JIANCAI</creatorcontrib><creatorcontrib>LU YUNLONG</creatorcontrib><creatorcontrib>ZHAO SHIYONG</creatorcontrib><creatorcontrib>ZHU HUI</creatorcontrib><creatorcontrib>YUE LI</creatorcontrib><collection>esp@cenet</collection></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext_linktorsrc</fulltext></delivery><addata><au>LIU LEI</au><au>SHU YAFEI</au><au>DAI JIANCAI</au><au>LU YUNLONG</au><au>ZHAO SHIYONG</au><au>ZHU HUI</au><au>YUE LI</au><format>patent</format><genre>patent</genre><ristype>GEN</ristype><title>Preparation method of n-butylamine propyl trimethoxy silane</title><date>2015-09-23</date><risdate>2015</risdate><abstract>The invention discloses a preparation method of n-butylamine propyl trimethoxy silane, wherein the preparation method comprises the following steps: (1) putting n-butylamine and chloropropyl trimethoxy silane into a reaction kettle, beginning to a temperature-rising reaction under stirring, and controlling the reaction pressure to be 0.5 MPa-2 MPa and the reaction temperature to be 75-120 DEG C; (2) after the reaction of the step (1) is finished, controlling the temperature in the reaction kettle to be 40-50 DEG C, then adding sodium methoxide to the reaction liquid, and continuing a stirring reaction; after the reaction is finished, carrying out solid-liquid separation on the reaction liquid, and separating out a filtrate and a sodium chloride precipitate; and (3) carrying out reduced pressure distillation on the filtrate separated out in the step (2), and separating unreacted n-butylamine, generated alcohol and the required product n-butylamine propyl trimethoxy silane, to obtain the high-purity product n-butylamine propyl trimethoxy silane. The whole preparation method is simple in process, production costs can be greatly reduced, and more than 84% of the molar yield can be obtained.</abstract><oa>free_for_read</oa></addata></record> |
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subjects | ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAININGELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN,SULFUR, SELENIUM OR TELLURIUM CHEMISTRY METALLURGY ORGANIC CHEMISTRY |
title | Preparation method of n-butylamine propyl trimethoxy silane |
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