METHOD FOR ALCOHOLYSIS OF POLYCARBONATE COMPOSITIONS CONTAINING FLAME RETARDANT OR ACRYLONITRILE-BUTADIENE-STYRENE

The disclosure provides a method for alcoholysis of a polycarbonate-containing composition comprising a polycarbonate and a component comprising a phosphorus-containing flame retardant, an acrylonitrile-butadiene-styrene, or a combination of the phosphorus-containing flame retardant and acrylonitril...

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Bibliographische Detailangaben
Hauptverfasser: STANISLAUS ALEXANDER, MAHALINGAM RATHINAM JOTHI, BHOTLA VENKATA RAMANARAYANAN GANAPATHY, BELL PHILIP WESLEY
Format: Patent
Sprache:eng
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Zusammenfassung:The disclosure provides a method for alcoholysis of a polycarbonate-containing composition comprising a polycarbonate and a component comprising a phosphorus-containing flame retardant, an acrylonitrile-butadiene-styrene, or a combination of the phosphorus-containing flame retardant and acrylonitrile-butadiene-styrene. The method comprises contacting the composition with a solvent that forms a solution or a filterable suspension of the component but not the polycarbonate; separating the solution or the filterable suspension from the polycarbonate; and heating the polycarbonate in the presence of an alcohol and a catalyst at a temperature from 70 DEG C to 200 DEG C, and a pressure from 5 mbar to 40 bar for a time sufficient to depolymerize the polycarbonate and produce a dihydroxy aromatic compound and a dialkyl carbonate.