Siloxy thio-metal compound nanometer material and preparation method thereof
The invention provides a siloxy thio-metal compound nanometer material which has the structural formula as shown in the specification, wherein M refers to one of Zn, Cu and Fe, and R1 and R2 are independently selected from one of alkylene with the carbon atom number of 1-10. Compared with the prior...
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creator | DONG DONG ZHEN BOMING ZHAO LILI YAO JUFENG |
description | The invention provides a siloxy thio-metal compound nanometer material which has the structural formula as shown in the specification, wherein M refers to one of Zn, Cu and Fe, and R1 and R2 are independently selected from one of alkylene with the carbon atom number of 1-10. Compared with the prior art, the siloxy thio-metal compound nanometer material provided by the invention has the effects of reinforcing agents and vulcanizing agents. On one hand, S-M-S in the molecular formula can achieve an activating effect in the rubber vulcanizing process, and the rubber vulcanizing speed is improved; on the other hand, after Si-OH at the end group of the compound is dehydrated, a Si-O-Si group can be formed, and the reinforcing effects of the fillers can be achieved. Meanwhile, because the Si-O-Si group is connected with organic groups R1 and R2, the compatibility between the Si-O-Si and rubber macromolecules can be improved, the dispersing performance of the siloxy thio-metal compound nanometer material is improved, and the processability and mechanical properties of the rubber are improved. |
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Compared with the prior art, the siloxy thio-metal compound nanometer material provided by the invention has the effects of reinforcing agents and vulcanizing agents. On one hand, S-M-S in the molecular formula can achieve an activating effect in the rubber vulcanizing process, and the rubber vulcanizing speed is improved; on the other hand, after Si-OH at the end group of the compound is dehydrated, a Si-O-Si group can be formed, and the reinforcing effects of the fillers can be achieved. Meanwhile, because the Si-O-Si group is connected with organic groups R1 and R2, the compatibility between the Si-O-Si and rubber macromolecules can be improved, the dispersing performance of the siloxy thio-metal compound nanometer material is improved, and the processability and mechanical properties of the rubber are improved.</description><language>eng</language><subject>ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAININGELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN,SULFUR, SELENIUM OR TELLURIUM ; CHEMISTRY ; COMPOSITIONS BASED THEREON ; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES ; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES ; METALLURGY ; NANOTECHNOLOGY ; ORGANIC CHEMISTRY ; ORGANIC MACROMOLECULAR COMPOUNDS ; PERFORMING OPERATIONS ; SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES ; THEIR PREPARATION OR CHEMICAL WORKING-UP ; TRANSPORTING ; USE OF INORGANIC OR NON-MACROMOLECULAR ORGANIC SUBSTANCES ASCOMPOUNDING INGREDIENTS</subject><creationdate>2015</creationdate><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://worldwide.espacenet.com/publicationDetails/biblio?FT=D&date=20150506&DB=EPODOC&CC=CN&NR=104592315A$$EHTML$$P50$$Gepo$$Hfree_for_read</linktohtml><link.rule.ids>230,308,778,883,25553,76306</link.rule.ids><linktorsrc>$$Uhttps://worldwide.espacenet.com/publicationDetails/biblio?FT=D&date=20150506&DB=EPODOC&CC=CN&NR=104592315A$$EView_record_in_European_Patent_Office$$FView_record_in_$$GEuropean_Patent_Office$$Hfree_for_read</linktorsrc></links><search><creatorcontrib>DONG DONG</creatorcontrib><creatorcontrib>ZHEN BOMING</creatorcontrib><creatorcontrib>ZHAO LILI</creatorcontrib><creatorcontrib>YAO JUFENG</creatorcontrib><title>Siloxy thio-metal compound nanometer material and preparation method thereof</title><description>The invention provides a siloxy thio-metal compound nanometer material which has the structural formula as shown in the specification, wherein M refers to one of Zn, Cu and Fe, and R1 and R2 are independently selected from one of alkylene with the carbon atom number of 1-10. Compared with the prior art, the siloxy thio-metal compound nanometer material provided by the invention has the effects of reinforcing agents and vulcanizing agents. On one hand, S-M-S in the molecular formula can achieve an activating effect in the rubber vulcanizing process, and the rubber vulcanizing speed is improved; on the other hand, after Si-OH at the end group of the compound is dehydrated, a Si-O-Si group can be formed, and the reinforcing effects of the fillers can be achieved. Meanwhile, because the Si-O-Si group is connected with organic groups R1 and R2, the compatibility between the Si-O-Si and rubber macromolecules can be improved, the dispersing performance of the siloxy thio-metal compound nanometer material is improved, and the processability and mechanical properties of the rubber are improved.</description><subject>ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAININGELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN,SULFUR, SELENIUM OR TELLURIUM</subject><subject>CHEMISTRY</subject><subject>COMPOSITIONS BASED THEREON</subject><subject>MANUFACTURE OR TREATMENT OF NANOSTRUCTURES</subject><subject>MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES</subject><subject>METALLURGY</subject><subject>NANOTECHNOLOGY</subject><subject>ORGANIC CHEMISTRY</subject><subject>ORGANIC MACROMOLECULAR COMPOUNDS</subject><subject>PERFORMING OPERATIONS</subject><subject>SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES</subject><subject>THEIR PREPARATION OR CHEMICAL WORKING-UP</subject><subject>TRANSPORTING</subject><subject>USE OF INORGANIC OR NON-MACROMOLECULAR ORGANIC SUBSTANCES ASCOMPOUNDING INGREDIENTS</subject><fulltext>true</fulltext><rsrctype>patent</rsrctype><creationdate>2015</creationdate><recordtype>patent</recordtype><sourceid>EVB</sourceid><recordid>eNrjZPAJzszJr6hUKMnIzNfNTS1JzFFIzs8tyC_NS1HIS8zLBwqlFinkJgLJTKBcIlC4oCi1ILEosSQzP08BKJ2RnwLUnVqUmp_Gw8CalphTnMoLpbkZFN1cQ5w9dFML8uNTiwsSk1PzUkvinf0MDUxMLY2MDU0djYlRAwDscjZu</recordid><startdate>20150506</startdate><enddate>20150506</enddate><creator>DONG DONG</creator><creator>ZHEN BOMING</creator><creator>ZHAO LILI</creator><creator>YAO JUFENG</creator><scope>EVB</scope></search><sort><creationdate>20150506</creationdate><title>Siloxy thio-metal compound nanometer material and preparation method thereof</title><author>DONG DONG ; ZHEN BOMING ; ZHAO LILI ; YAO JUFENG</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-epo_espacenet_CN104592315A3</frbrgroupid><rsrctype>patents</rsrctype><prefilter>patents</prefilter><language>eng</language><creationdate>2015</creationdate><topic>ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAININGELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN,SULFUR, SELENIUM OR TELLURIUM</topic><topic>CHEMISTRY</topic><topic>COMPOSITIONS BASED THEREON</topic><topic>MANUFACTURE OR TREATMENT OF NANOSTRUCTURES</topic><topic>MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES</topic><topic>METALLURGY</topic><topic>NANOTECHNOLOGY</topic><topic>ORGANIC CHEMISTRY</topic><topic>ORGANIC MACROMOLECULAR COMPOUNDS</topic><topic>PERFORMING OPERATIONS</topic><topic>SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES</topic><topic>THEIR PREPARATION OR CHEMICAL WORKING-UP</topic><topic>TRANSPORTING</topic><topic>USE OF INORGANIC OR NON-MACROMOLECULAR ORGANIC SUBSTANCES ASCOMPOUNDING INGREDIENTS</topic><toplevel>online_resources</toplevel><creatorcontrib>DONG DONG</creatorcontrib><creatorcontrib>ZHEN BOMING</creatorcontrib><creatorcontrib>ZHAO LILI</creatorcontrib><creatorcontrib>YAO JUFENG</creatorcontrib><collection>esp@cenet</collection></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext_linktorsrc</fulltext></delivery><addata><au>DONG DONG</au><au>ZHEN BOMING</au><au>ZHAO LILI</au><au>YAO JUFENG</au><format>patent</format><genre>patent</genre><ristype>GEN</ristype><title>Siloxy thio-metal compound nanometer material and preparation method thereof</title><date>2015-05-06</date><risdate>2015</risdate><abstract>The invention provides a siloxy thio-metal compound nanometer material which has the structural formula as shown in the specification, wherein M refers to one of Zn, Cu and Fe, and R1 and R2 are independently selected from one of alkylene with the carbon atom number of 1-10. Compared with the prior art, the siloxy thio-metal compound nanometer material provided by the invention has the effects of reinforcing agents and vulcanizing agents. On one hand, S-M-S in the molecular formula can achieve an activating effect in the rubber vulcanizing process, and the rubber vulcanizing speed is improved; on the other hand, after Si-OH at the end group of the compound is dehydrated, a Si-O-Si group can be formed, and the reinforcing effects of the fillers can be achieved. Meanwhile, because the Si-O-Si group is connected with organic groups R1 and R2, the compatibility between the Si-O-Si and rubber macromolecules can be improved, the dispersing performance of the siloxy thio-metal compound nanometer material is improved, and the processability and mechanical properties of the rubber are improved.</abstract><oa>free_for_read</oa></addata></record> |
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subjects | ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAININGELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN,SULFUR, SELENIUM OR TELLURIUM CHEMISTRY COMPOSITIONS BASED THEREON MANUFACTURE OR TREATMENT OF NANOSTRUCTURES MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES METALLURGY NANOTECHNOLOGY ORGANIC CHEMISTRY ORGANIC MACROMOLECULAR COMPOUNDS PERFORMING OPERATIONS SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES THEIR PREPARATION OR CHEMICAL WORKING-UP TRANSPORTING USE OF INORGANIC OR NON-MACROMOLECULAR ORGANIC SUBSTANCES ASCOMPOUNDING INGREDIENTS |
title | Siloxy thio-metal compound nanometer material and preparation method thereof |
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