Technology for preparing ammonium tungstate solution
The invention discloses a technology for preparing an ammonium tungstate solution. The technology is characterized in that a (AO)x(WO3)y(BO)z-containing material is used as a raw material, A and B represents divalent metals, (x+z)/y=3, raw material granularity is less than or equal to 200 micrometer...
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creator | QI TIANGUI LIU GUIHUA LI XIAOBIN LI JIANPU LI JIHONG XU XIANGMING PENG ZHIHONG WANG YILIN ZHOU QIUSHENG XU SHUANG LIN GUORONG CUI YUANFA |
description | The invention discloses a technology for preparing an ammonium tungstate solution. The technology is characterized in that a (AO)x(WO3)y(BO)z-containing material is used as a raw material, A and B represents divalent metals, (x+z)/y=3, raw material granularity is less than or equal to 200 micrometers, a seed crystal use amount is in a range of 0-15g/L, a leaching agent solution selection principle at least comprises that raw material reactants contain substances capable of re-synthesizing the leaching agent and the leaching agent contains NH4 and has a concentration greater than 10g-NH4/100g-H2O, a use amount of the leaching agent is at least 1.0 times a required amount (theoretical amount) of the leaching agent for transforming clinker AO and BO into corresponding difficultly soluble salts, a leaching system pH value is controlled to greater than or equal to 8, a leaching process is carried out under enclosed conditions, leaching system absolute pressure is greater than or equal to 1atm, a leaching temperature is in a range of 15-100 DEG C, leaching time is in a range of 0.1-10.0h, an initial liquid-solid ratio of the leaching system is greater than or equal to 3: 1mL/g, through a multistage feeding method, the final liquid-solid ratio of the leaching system is reduced, and after leaching, leaching slurry is subjected to separation and washing to form an ammonium tungstate solution. The technology realizes low-cost, no waste water discharge and high-efficiency preparation of the high-concentration ammonium tungstate solution. |
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The technology is characterized in that a (AO)x(WO3)y(BO)z-containing material is used as a raw material, A and B represents divalent metals, (x+z)/y=3, raw material granularity is less than or equal to 200 micrometers, a seed crystal use amount is in a range of 0-15g/L, a leaching agent solution selection principle at least comprises that raw material reactants contain substances capable of re-synthesizing the leaching agent and the leaching agent contains NH4<+> and has a concentration greater than 10g-NH4<+>/100g-H2O, a use amount of the leaching agent is at least 1.0 times a required amount (theoretical amount) of the leaching agent for transforming clinker AO and BO into corresponding difficultly soluble salts, a leaching system pH value is controlled to greater than or equal to 8, a leaching process is carried out under enclosed conditions, leaching system absolute pressure is greater than or equal to 1atm, a leaching temperature is in a range of 15-100 DEG C, leaching time is in a range of 0.1-10.0h, an initial liquid-solid ratio of the leaching system is greater than or equal to 3: 1mL/g, through a multistage feeding method, the final liquid-solid ratio of the leaching system is reduced, and after leaching, leaching slurry is subjected to separation and washing to form an ammonium tungstate solution. 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The technology is characterized in that a (AO)x(WO3)y(BO)z-containing material is used as a raw material, A and B represents divalent metals, (x+z)/y=3, raw material granularity is less than or equal to 200 micrometers, a seed crystal use amount is in a range of 0-15g/L, a leaching agent solution selection principle at least comprises that raw material reactants contain substances capable of re-synthesizing the leaching agent and the leaching agent contains NH4<+> and has a concentration greater than 10g-NH4<+>/100g-H2O, a use amount of the leaching agent is at least 1.0 times a required amount (theoretical amount) of the leaching agent for transforming clinker AO and BO into corresponding difficultly soluble salts, a leaching system pH value is controlled to greater than or equal to 8, a leaching process is carried out under enclosed conditions, leaching system absolute pressure is greater than or equal to 1atm, a leaching temperature is in a range of 15-100 DEG C, leaching time is in a range of 0.1-10.0h, an initial liquid-solid ratio of the leaching system is greater than or equal to 3: 1mL/g, through a multistage feeding method, the final liquid-solid ratio of the leaching system is reduced, and after leaching, leaching slurry is subjected to separation and washing to form an ammonium tungstate solution. The technology realizes low-cost, no waste water discharge and high-efficiency preparation of the high-concentration ammonium tungstate solution.</description><subject>CHEMISTRY</subject><subject>COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSESC01D OR C01F</subject><subject>INORGANIC CHEMISTRY</subject><subject>METALLURGY</subject><fulltext>true</fulltext><rsrctype>patent</rsrctype><creationdate>2015</creationdate><recordtype>patent</recordtype><sourceid>EVB</sourceid><recordid>eNrjZDAJSU3OyMvPyU-vVEjLL1IoKEotSCzKzEtXSMzNzc_LLM1VKCnNSy8uSSxJVSjOzyktyczP42FgTUvMKU7lhdLcDIpuriHOHrqpBfnxqcUFicmpeakl8c5-hgYmxhZm5qYmjsbEqAEAj0ctsQ</recordid><startdate>20150304</startdate><enddate>20150304</enddate><creator>QI TIANGUI</creator><creator>LIU GUIHUA</creator><creator>LI XIAOBIN</creator><creator>LI JIANPU</creator><creator>LI JIHONG</creator><creator>XU XIANGMING</creator><creator>PENG ZHIHONG</creator><creator>WANG YILIN</creator><creator>ZHOU QIUSHENG</creator><creator>XU SHUANG</creator><creator>LIN GUORONG</creator><creator>CUI YUANFA</creator><scope>EVB</scope></search><sort><creationdate>20150304</creationdate><title>Technology for preparing ammonium tungstate solution</title><author>QI TIANGUI ; LIU GUIHUA ; LI XIAOBIN ; LI JIANPU ; LI JIHONG ; XU XIANGMING ; PENG ZHIHONG ; WANG YILIN ; ZHOU QIUSHENG ; XU SHUANG ; LIN GUORONG ; CUI YUANFA</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-epo_espacenet_CN104386754A3</frbrgroupid><rsrctype>patents</rsrctype><prefilter>patents</prefilter><language>eng</language><creationdate>2015</creationdate><topic>CHEMISTRY</topic><topic>COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSESC01D OR C01F</topic><topic>INORGANIC CHEMISTRY</topic><topic>METALLURGY</topic><toplevel>online_resources</toplevel><creatorcontrib>QI TIANGUI</creatorcontrib><creatorcontrib>LIU GUIHUA</creatorcontrib><creatorcontrib>LI XIAOBIN</creatorcontrib><creatorcontrib>LI JIANPU</creatorcontrib><creatorcontrib>LI JIHONG</creatorcontrib><creatorcontrib>XU XIANGMING</creatorcontrib><creatorcontrib>PENG ZHIHONG</creatorcontrib><creatorcontrib>WANG YILIN</creatorcontrib><creatorcontrib>ZHOU QIUSHENG</creatorcontrib><creatorcontrib>XU SHUANG</creatorcontrib><creatorcontrib>LIN GUORONG</creatorcontrib><creatorcontrib>CUI YUANFA</creatorcontrib><collection>esp@cenet</collection></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext_linktorsrc</fulltext></delivery><addata><au>QI TIANGUI</au><au>LIU GUIHUA</au><au>LI XIAOBIN</au><au>LI JIANPU</au><au>LI JIHONG</au><au>XU XIANGMING</au><au>PENG ZHIHONG</au><au>WANG YILIN</au><au>ZHOU QIUSHENG</au><au>XU SHUANG</au><au>LIN GUORONG</au><au>CUI YUANFA</au><format>patent</format><genre>patent</genre><ristype>GEN</ristype><title>Technology for preparing ammonium tungstate solution</title><date>2015-03-04</date><risdate>2015</risdate><abstract>The invention discloses a technology for preparing an ammonium tungstate solution. The technology is characterized in that a (AO)x(WO3)y(BO)z-containing material is used as a raw material, A and B represents divalent metals, (x+z)/y=3, raw material granularity is less than or equal to 200 micrometers, a seed crystal use amount is in a range of 0-15g/L, a leaching agent solution selection principle at least comprises that raw material reactants contain substances capable of re-synthesizing the leaching agent and the leaching agent contains NH4<+> and has a concentration greater than 10g-NH4<+>/100g-H2O, a use amount of the leaching agent is at least 1.0 times a required amount (theoretical amount) of the leaching agent for transforming clinker AO and BO into corresponding difficultly soluble salts, a leaching system pH value is controlled to greater than or equal to 8, a leaching process is carried out under enclosed conditions, leaching system absolute pressure is greater than or equal to 1atm, a leaching temperature is in a range of 15-100 DEG C, leaching time is in a range of 0.1-10.0h, an initial liquid-solid ratio of the leaching system is greater than or equal to 3: 1mL/g, through a multistage feeding method, the final liquid-solid ratio of the leaching system is reduced, and after leaching, leaching slurry is subjected to separation and washing to form an ammonium tungstate solution. The technology realizes low-cost, no waste water discharge and high-efficiency preparation of the high-concentration ammonium tungstate solution.</abstract><oa>free_for_read</oa></addata></record> |
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title | Technology for preparing ammonium tungstate solution |
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