Preparation method of 2-methylcyclopentadecanon

Preparation method of 2-methylcyclopentadecanon

The invention discloses a preparation method of 2-methylcyclopentadecanon. The method comprises the following steps: cyclizing a raw material dimethyl pentadecanedioate, adding a thiophenylmethylene group, dehydroxylating, and removing athiophenyl group to obtain 2-methylcyclopentadecanon. The raw m...

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Hauptverfasser: BAO JINLONG, TIAN CHAOSHUANG, ZOU XINZHUO
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Sprache:eng
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ACYCLIC OR CARBOCYCLIC COMPOUNDS
CHEMISTRY
METALLURGY
ORGANIC CHEMISTRY
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creator BAO JINLONG
TIAN CHAOSHUANG
ZOU XINZHUO
description The invention discloses a preparation method of 2-methylcyclopentadecanon. The method comprises the following steps: cyclizing a raw material dimethyl pentadecanedioate, adding a thiophenylmethylene group, dehydroxylating, and removing athiophenyl group to obtain 2-methylcyclopentadecanon. The raw material can be industrially produced and easily obtained. The method using cheap methyl phenylthio acetate to carry out a methylation reaction avoids the difficult industrial production of a methyl Grignard reaction, the method not using expensive iodide or bromide saves the cost and also avoids the use of ether solvents with production safety problems, and the method also has the advantages of milder reaction condition and easy industrialization.
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The method using cheap methyl phenylthio acetate to carry out a methylation reaction avoids the difficult industrial production of a methyl Grignard reaction, the method not using expensive iodide or bromide saves the cost and also avoids the use of ether solvents with production safety problems, and the method also has the advantages of milder reaction condition and easy industrialization.</description><language>eng</language><subject>ACYCLIC OR CARBOCYCLIC COMPOUNDS ; CHEMISTRY ; METALLURGY ; ORGANIC CHEMISTRY</subject><creationdate>2015</creationdate><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://worldwide.espacenet.com/publicationDetails/biblio?FT=D&amp;date=20150225&amp;DB=EPODOC&amp;CC=CN&amp;NR=104370714A$$EHTML$$P50$$Gepo$$Hfree_for_read</linktohtml><link.rule.ids>230,308,776,881,25543,76294</link.rule.ids><linktorsrc>$$Uhttps://worldwide.espacenet.com/publicationDetails/biblio?FT=D&amp;date=20150225&amp;DB=EPODOC&amp;CC=CN&amp;NR=104370714A$$EView_record_in_European_Patent_Office$$FView_record_in_$$GEuropean_Patent_Office$$Hfree_for_read</linktorsrc></links><search><creatorcontrib>BAO JINLONG</creatorcontrib><creatorcontrib>TIAN CHAOSHUANG</creatorcontrib><creatorcontrib>ZOU XINZHUO</creatorcontrib><title>Preparation method of 2-methylcyclopentadecanon</title><description>The invention discloses a preparation method of 2-methylcyclopentadecanon. 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CHEMISTRY
METALLURGY
ORGANIC CHEMISTRY
title Preparation method of 2-methylcyclopentadecanon
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