Preparation method of calcium terephthalate, and application of calcium terephthalate in lithium ion battery
The invention provides a preparation method of an organic negative material calcium terephthalate, and an application of the organic negative material calcium terephthalate in a lithium ion battery. The preparation method of calcium terephthalate comprises the following steps: 1, reacting terephthal...
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creator | WANG LIPING HUANG ZONGLING LI JINGZE MOU CHENGXU |
description | The invention provides a preparation method of an organic negative material calcium terephthalate, and an application of the organic negative material calcium terephthalate in a lithium ion battery. The preparation method of calcium terephthalate comprises the following steps: 1, reacting terephthalic acid with LiOH or NaOH or KOH to obtain a terephthalate solution; 2, reacting the terephthalate salt solution with CaCl2 or Ca (NO3)2 to obtain a mixed solution containing calcium terephthalate; 3, separating the mixed solution, and drying the solid obtained separation to obtain calcium terephthalate trihydrate; and 4, drying the calcium terephthalate trihydrate in a vacuum drying box to remove crystal water in order to obtain calcium terephthalate. The calcium terephthalate has a reversible capacity of 231mAh/g, has the advantages of excellent stability in an electrolyte, good rate capability, slow specific capacity attenuation, and maintenance of high capacity of 93% after cycling for 120 weeks, and is a lithium ion battery organic negative material with excellent performances. |
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The preparation method of calcium terephthalate comprises the following steps: 1, reacting terephthalic acid with LiOH or NaOH or KOH to obtain a terephthalate solution; 2, reacting the terephthalate salt solution with CaCl2 or Ca (NO3)2 to obtain a mixed solution containing calcium terephthalate; 3, separating the mixed solution, and drying the solid obtained separation to obtain calcium terephthalate trihydrate; and 4, drying the calcium terephthalate trihydrate in a vacuum drying box to remove crystal water in order to obtain calcium terephthalate. The calcium terephthalate has a reversible capacity of 231mAh/g, has the advantages of excellent stability in an electrolyte, good rate capability, slow specific capacity attenuation, and maintenance of high capacity of 93% after cycling for 120 weeks, and is a lithium ion battery organic negative material with excellent performances.</description><language>eng</language><subject>ACYCLIC OR CARBOCYCLIC COMPOUNDS ; BASIC ELECTRIC ELEMENTS ; CHEMISTRY ; ELECTRICITY ; METALLURGY ; ORGANIC CHEMISTRY ; PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSIONOF CHEMICAL INTO ELECTRICAL ENERGY</subject><creationdate>2015</creationdate><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://worldwide.espacenet.com/publicationDetails/biblio?FT=D&date=20150121&DB=EPODOC&CC=CN&NR=104292100A$$EHTML$$P50$$Gepo$$Hfree_for_read</linktohtml><link.rule.ids>230,308,776,881,25542,76290</link.rule.ids><linktorsrc>$$Uhttps://worldwide.espacenet.com/publicationDetails/biblio?FT=D&date=20150121&DB=EPODOC&CC=CN&NR=104292100A$$EView_record_in_European_Patent_Office$$FView_record_in_$$GEuropean_Patent_Office$$Hfree_for_read</linktorsrc></links><search><creatorcontrib>WANG LIPING</creatorcontrib><creatorcontrib>HUANG ZONGLING</creatorcontrib><creatorcontrib>LI JINGZE</creatorcontrib><creatorcontrib>MOU CHENGXU</creatorcontrib><title>Preparation method of calcium terephthalate, and application of calcium terephthalate in lithium ion battery</title><description>The invention provides a preparation method of an organic negative material calcium terephthalate, and an application of the organic negative material calcium terephthalate in a lithium ion battery. The preparation method of calcium terephthalate comprises the following steps: 1, reacting terephthalic acid with LiOH or NaOH or KOH to obtain a terephthalate solution; 2, reacting the terephthalate salt solution with CaCl2 or Ca (NO3)2 to obtain a mixed solution containing calcium terephthalate; 3, separating the mixed solution, and drying the solid obtained separation to obtain calcium terephthalate trihydrate; and 4, drying the calcium terephthalate trihydrate in a vacuum drying box to remove crystal water in order to obtain calcium terephthalate. The calcium terephthalate has a reversible capacity of 231mAh/g, has the advantages of excellent stability in an electrolyte, good rate capability, slow specific capacity attenuation, and maintenance of high capacity of 93% after cycling for 120 weeks, and is a lithium ion battery organic negative material with excellent performances.</description><subject>ACYCLIC OR CARBOCYCLIC COMPOUNDS</subject><subject>BASIC ELECTRIC ELEMENTS</subject><subject>CHEMISTRY</subject><subject>ELECTRICITY</subject><subject>METALLURGY</subject><subject>ORGANIC CHEMISTRY</subject><subject>PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSIONOF CHEMICAL INTO ELECTRICAL ENERGY</subject><fulltext>true</fulltext><rsrctype>patent</rsrctype><creationdate>2015</creationdate><recordtype>patent</recordtype><sourceid>EVB</sourceid><recordid>eNqNyzELwkAMhuFbHET9D3FXuFYXRymKkzi4l3hNuUB6F9o4-O9t0VVw-obn_eZObj0p9micE3RkMTeQWwgogZ8dGI0cLaKg0QYwNYCqwuFz-FUCJxC2OMHUPdBGfy3drEUZaPXdhVufT_fqsiXNNQ2KgRJZXV0Lvy8PZeH9cfdP8wZfKUIi</recordid><startdate>20150121</startdate><enddate>20150121</enddate><creator>WANG LIPING</creator><creator>HUANG ZONGLING</creator><creator>LI JINGZE</creator><creator>MOU CHENGXU</creator><scope>EVB</scope></search><sort><creationdate>20150121</creationdate><title>Preparation method of calcium terephthalate, and application of calcium terephthalate in lithium ion battery</title><author>WANG LIPING ; HUANG ZONGLING ; LI JINGZE ; MOU CHENGXU</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-epo_espacenet_CN104292100A3</frbrgroupid><rsrctype>patents</rsrctype><prefilter>patents</prefilter><language>eng</language><creationdate>2015</creationdate><topic>ACYCLIC OR CARBOCYCLIC COMPOUNDS</topic><topic>BASIC ELECTRIC ELEMENTS</topic><topic>CHEMISTRY</topic><topic>ELECTRICITY</topic><topic>METALLURGY</topic><topic>ORGANIC CHEMISTRY</topic><topic>PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSIONOF CHEMICAL INTO ELECTRICAL ENERGY</topic><toplevel>online_resources</toplevel><creatorcontrib>WANG LIPING</creatorcontrib><creatorcontrib>HUANG ZONGLING</creatorcontrib><creatorcontrib>LI JINGZE</creatorcontrib><creatorcontrib>MOU CHENGXU</creatorcontrib><collection>esp@cenet</collection></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext_linktorsrc</fulltext></delivery><addata><au>WANG LIPING</au><au>HUANG ZONGLING</au><au>LI JINGZE</au><au>MOU CHENGXU</au><format>patent</format><genre>patent</genre><ristype>GEN</ristype><title>Preparation method of calcium terephthalate, and application of calcium terephthalate in lithium ion battery</title><date>2015-01-21</date><risdate>2015</risdate><abstract>The invention provides a preparation method of an organic negative material calcium terephthalate, and an application of the organic negative material calcium terephthalate in a lithium ion battery. The preparation method of calcium terephthalate comprises the following steps: 1, reacting terephthalic acid with LiOH or NaOH or KOH to obtain a terephthalate solution; 2, reacting the terephthalate salt solution with CaCl2 or Ca (NO3)2 to obtain a mixed solution containing calcium terephthalate; 3, separating the mixed solution, and drying the solid obtained separation to obtain calcium terephthalate trihydrate; and 4, drying the calcium terephthalate trihydrate in a vacuum drying box to remove crystal water in order to obtain calcium terephthalate. The calcium terephthalate has a reversible capacity of 231mAh/g, has the advantages of excellent stability in an electrolyte, good rate capability, slow specific capacity attenuation, and maintenance of high capacity of 93% after cycling for 120 weeks, and is a lithium ion battery organic negative material with excellent performances.</abstract><oa>free_for_read</oa></addata></record> |
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title | Preparation method of calcium terephthalate, and application of calcium terephthalate in lithium ion battery |
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