Preparation method of PPS (polyphenylene sulfide)-based N-methylimidazole strong base type ion exchange fiber

The invention discloses a preparation method of a PPS (polyphenylene sulfide)-based N-methylimidazole strong base type ion exchange fiber. The method comprises the following steps of: firstly, on the basis of using polyphenylene sulfide fiber as a basic raw material, adding dichloroethane, chloromet...

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Hauptverfasser: ZHANG JIE, YAO HUAJIE, CUI LAN, ZHANG DENGKE, ZHOU DONGJU, MA YINCHU, HUI GENLEI, DAI LIBO, YUAN SIGUO
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creator ZHANG JIE
YAO HUAJIE
CUI LAN
ZHANG DENGKE
ZHOU DONGJU
MA YINCHU
HUI GENLEI
DAI LIBO
YUAN SIGUO
description The invention discloses a preparation method of a PPS (polyphenylene sulfide)-based N-methylimidazole strong base type ion exchange fiber. The method comprises the following steps of: firstly, on the basis of using polyphenylene sulfide fiber as a basic raw material, adding dichloroethane, chloromethyl ether and tin chloride for swelling, heating up for reaction after swelling, cooling after reaction, filtering out the product, and processing the product to get the chloromethylated polyphenylene sulfide fiber; then, adding dichloroethane for swelling, adding alcohol, N-methylimidazole and tetrabutylammonium bromide after swelling, heating up for reaction, filtering out the product after reaction, and sequentially washing, extracting, washing with brine and drying the product, thereby obtaining the product PPS -based N-methylimidazole strong base type ion exchange fiber. The PPS-based N-methylimidazole strong base type ion exchange fiber prepared according to the invention has the characteristics of high oxidation resistance, excellent chemical stability, larger adsorbing capacity, excellent absorption and regeneration performance and the like. The preparation method of the PPS -based N-methylimidazole strong base type ion exchange fiber is simple, low in production cost and easy to generalize in industry.
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The method comprises the following steps of: firstly, on the basis of using polyphenylene sulfide fiber as a basic raw material, adding dichloroethane, chloromethyl ether and tin chloride for swelling, heating up for reaction after swelling, cooling after reaction, filtering out the product, and processing the product to get the chloromethylated polyphenylene sulfide fiber; then, adding dichloroethane for swelling, adding alcohol, N-methylimidazole and tetrabutylammonium bromide after swelling, heating up for reaction, filtering out the product after reaction, and sequentially washing, extracting, washing with brine and drying the product, thereby obtaining the product PPS -based N-methylimidazole strong base type ion exchange fiber. The PPS-based N-methylimidazole strong base type ion exchange fiber prepared according to the invention has the characteristics of high oxidation resistance, excellent chemical stability, larger adsorbing capacity, excellent absorption and regeneration performance and the like. 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The method comprises the following steps of: firstly, on the basis of using polyphenylene sulfide fiber as a basic raw material, adding dichloroethane, chloromethyl ether and tin chloride for swelling, heating up for reaction after swelling, cooling after reaction, filtering out the product, and processing the product to get the chloromethylated polyphenylene sulfide fiber; then, adding dichloroethane for swelling, adding alcohol, N-methylimidazole and tetrabutylammonium bromide after swelling, heating up for reaction, filtering out the product after reaction, and sequentially washing, extracting, washing with brine and drying the product, thereby obtaining the product PPS -based N-methylimidazole strong base type ion exchange fiber. The PPS-based N-methylimidazole strong base type ion exchange fiber prepared according to the invention has the characteristics of high oxidation resistance, excellent chemical stability, larger adsorbing capacity, excellent absorption and regeneration performance and the like. The preparation method of the PPS -based N-methylimidazole strong base type ion exchange fiber is simple, low in production cost and easy to generalize in industry.</abstract><oa>free_for_read</oa></addata></record>
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subjects CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY
FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
LAUNDERING
PERFORMING OPERATIONS
PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
TEXTILES
THEIR RELEVANT APPARATUS
TRANSPORTING
TREATMENT OF TEXTILES OR THE LIKE
TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS,FABRICS, FEATHERS, OR FIBROUS GOODS MADE FROM SUCH MATERIALS
title Preparation method of PPS (polyphenylene sulfide)-based N-methylimidazole strong base type ion exchange fiber
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