Preparation method of PPS (polyphenylene sulfide)-based N-methylimidazole strong base type ion exchange fiber
The invention discloses a preparation method of a PPS (polyphenylene sulfide)-based N-methylimidazole strong base type ion exchange fiber. The method comprises the following steps of: firstly, on the basis of using polyphenylene sulfide fiber as a basic raw material, adding dichloroethane, chloromet...
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creator | ZHANG JIE YAO HUAJIE CUI LAN ZHANG DENGKE ZHOU DONGJU MA YINCHU HUI GENLEI DAI LIBO YUAN SIGUO |
description | The invention discloses a preparation method of a PPS (polyphenylene sulfide)-based N-methylimidazole strong base type ion exchange fiber. The method comprises the following steps of: firstly, on the basis of using polyphenylene sulfide fiber as a basic raw material, adding dichloroethane, chloromethyl ether and tin chloride for swelling, heating up for reaction after swelling, cooling after reaction, filtering out the product, and processing the product to get the chloromethylated polyphenylene sulfide fiber; then, adding dichloroethane for swelling, adding alcohol, N-methylimidazole and tetrabutylammonium bromide after swelling, heating up for reaction, filtering out the product after reaction, and sequentially washing, extracting, washing with brine and drying the product, thereby obtaining the product PPS -based N-methylimidazole strong base type ion exchange fiber. The PPS-based N-methylimidazole strong base type ion exchange fiber prepared according to the invention has the characteristics of high oxidation resistance, excellent chemical stability, larger adsorbing capacity, excellent absorption and regeneration performance and the like. The preparation method of the PPS -based N-methylimidazole strong base type ion exchange fiber is simple, low in production cost and easy to generalize in industry. |
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The method comprises the following steps of: firstly, on the basis of using polyphenylene sulfide fiber as a basic raw material, adding dichloroethane, chloromethyl ether and tin chloride for swelling, heating up for reaction after swelling, cooling after reaction, filtering out the product, and processing the product to get the chloromethylated polyphenylene sulfide fiber; then, adding dichloroethane for swelling, adding alcohol, N-methylimidazole and tetrabutylammonium bromide after swelling, heating up for reaction, filtering out the product after reaction, and sequentially washing, extracting, washing with brine and drying the product, thereby obtaining the product PPS -based N-methylimidazole strong base type ion exchange fiber. The PPS-based N-methylimidazole strong base type ion exchange fiber prepared according to the invention has the characteristics of high oxidation resistance, excellent chemical stability, larger adsorbing capacity, excellent absorption and regeneration performance and the like. The preparation method of the PPS -based N-methylimidazole strong base type ion exchange fiber is simple, low in production cost and easy to generalize in industry.</description><language>eng</language><subject>CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY ; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR ; LAUNDERING ; PERFORMING OPERATIONS ; PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL ; TEXTILES ; THEIR RELEVANT APPARATUS ; TRANSPORTING ; TREATMENT OF TEXTILES OR THE LIKE ; TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS,FABRICS, FEATHERS, OR FIBROUS GOODS MADE FROM SUCH MATERIALS</subject><creationdate>2015</creationdate><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://worldwide.espacenet.com/publicationDetails/biblio?FT=D&date=20150610&DB=EPODOC&CC=CN&NR=103306133B$$EHTML$$P50$$Gepo$$Hfree_for_read</linktohtml><link.rule.ids>230,308,780,885,25564,76547</link.rule.ids><linktorsrc>$$Uhttps://worldwide.espacenet.com/publicationDetails/biblio?FT=D&date=20150610&DB=EPODOC&CC=CN&NR=103306133B$$EView_record_in_European_Patent_Office$$FView_record_in_$$GEuropean_Patent_Office$$Hfree_for_read</linktorsrc></links><search><creatorcontrib>ZHANG JIE</creatorcontrib><creatorcontrib>YAO HUAJIE</creatorcontrib><creatorcontrib>CUI LAN</creatorcontrib><creatorcontrib>ZHANG DENGKE</creatorcontrib><creatorcontrib>ZHOU DONGJU</creatorcontrib><creatorcontrib>MA YINCHU</creatorcontrib><creatorcontrib>HUI GENLEI</creatorcontrib><creatorcontrib>DAI LIBO</creatorcontrib><creatorcontrib>YUAN SIGUO</creatorcontrib><title>Preparation method of PPS (polyphenylene sulfide)-based N-methylimidazole strong base type ion exchange fiber</title><description>The invention discloses a preparation method of a PPS (polyphenylene sulfide)-based N-methylimidazole strong base type ion exchange fiber. The method comprises the following steps of: firstly, on the basis of using polyphenylene sulfide fiber as a basic raw material, adding dichloroethane, chloromethyl ether and tin chloride for swelling, heating up for reaction after swelling, cooling after reaction, filtering out the product, and processing the product to get the chloromethylated polyphenylene sulfide fiber; then, adding dichloroethane for swelling, adding alcohol, N-methylimidazole and tetrabutylammonium bromide after swelling, heating up for reaction, filtering out the product after reaction, and sequentially washing, extracting, washing with brine and drying the product, thereby obtaining the product PPS -based N-methylimidazole strong base type ion exchange fiber. The PPS-based N-methylimidazole strong base type ion exchange fiber prepared according to the invention has the characteristics of high oxidation resistance, excellent chemical stability, larger adsorbing capacity, excellent absorption and regeneration performance and the like. The preparation method of the PPS -based N-methylimidazole strong base type ion exchange fiber is simple, low in production cost and easy to generalize in industry.</description><subject>CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY</subject><subject>FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR</subject><subject>LAUNDERING</subject><subject>PERFORMING OPERATIONS</subject><subject>PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL</subject><subject>TEXTILES</subject><subject>THEIR RELEVANT APPARATUS</subject><subject>TRANSPORTING</subject><subject>TREATMENT OF TEXTILES OR THE LIKE</subject><subject>TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS,FABRICS, FEATHERS, OR FIBROUS GOODS MADE FROM SUCH MATERIALS</subject><fulltext>true</fulltext><rsrctype>patent</rsrctype><creationdate>2015</creationdate><recordtype>patent</recordtype><sourceid>EVB</sourceid><recordid>eNqNzUEKwjAQBdBuXIh6h8GVLgotAQ_QorgqBd2XaTNpA2kmJBGMp7cFD-DqL_7j_202t54ceoyaLcwUJ5bACtr2ASfHJrmJbDJkCcLLKC3pnPcYSEKTrzoZPWuJHzYLiJ7tCGsNMTmCdZLew4R2JFC6J7_PNgpNoMMvd9nxdn3W95wcdxQcDstT7OqmLIQoLqUQVSX-Ql_MSUJe</recordid><startdate>20150610</startdate><enddate>20150610</enddate><creator>ZHANG JIE</creator><creator>YAO HUAJIE</creator><creator>CUI LAN</creator><creator>ZHANG DENGKE</creator><creator>ZHOU DONGJU</creator><creator>MA YINCHU</creator><creator>HUI GENLEI</creator><creator>DAI LIBO</creator><creator>YUAN SIGUO</creator><scope>EVB</scope></search><sort><creationdate>20150610</creationdate><title>Preparation method of PPS (polyphenylene sulfide)-based N-methylimidazole strong base type ion exchange fiber</title><author>ZHANG JIE ; YAO HUAJIE ; CUI LAN ; ZHANG DENGKE ; ZHOU DONGJU ; MA YINCHU ; HUI GENLEI ; DAI LIBO ; YUAN SIGUO</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-epo_espacenet_CN103306133BB3</frbrgroupid><rsrctype>patents</rsrctype><prefilter>patents</prefilter><language>eng</language><creationdate>2015</creationdate><topic>CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY</topic><topic>FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR</topic><topic>LAUNDERING</topic><topic>PERFORMING OPERATIONS</topic><topic>PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL</topic><topic>TEXTILES</topic><topic>THEIR RELEVANT APPARATUS</topic><topic>TRANSPORTING</topic><topic>TREATMENT OF TEXTILES OR THE LIKE</topic><topic>TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS,FABRICS, FEATHERS, OR FIBROUS GOODS MADE FROM SUCH MATERIALS</topic><toplevel>online_resources</toplevel><creatorcontrib>ZHANG JIE</creatorcontrib><creatorcontrib>YAO HUAJIE</creatorcontrib><creatorcontrib>CUI LAN</creatorcontrib><creatorcontrib>ZHANG DENGKE</creatorcontrib><creatorcontrib>ZHOU DONGJU</creatorcontrib><creatorcontrib>MA YINCHU</creatorcontrib><creatorcontrib>HUI GENLEI</creatorcontrib><creatorcontrib>DAI LIBO</creatorcontrib><creatorcontrib>YUAN SIGUO</creatorcontrib><collection>esp@cenet</collection></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext_linktorsrc</fulltext></delivery><addata><au>ZHANG JIE</au><au>YAO HUAJIE</au><au>CUI LAN</au><au>ZHANG DENGKE</au><au>ZHOU DONGJU</au><au>MA YINCHU</au><au>HUI GENLEI</au><au>DAI LIBO</au><au>YUAN SIGUO</au><format>patent</format><genre>patent</genre><ristype>GEN</ristype><title>Preparation method of PPS (polyphenylene sulfide)-based N-methylimidazole strong base type ion exchange fiber</title><date>2015-06-10</date><risdate>2015</risdate><abstract>The invention discloses a preparation method of a PPS (polyphenylene sulfide)-based N-methylimidazole strong base type ion exchange fiber. The method comprises the following steps of: firstly, on the basis of using polyphenylene sulfide fiber as a basic raw material, adding dichloroethane, chloromethyl ether and tin chloride for swelling, heating up for reaction after swelling, cooling after reaction, filtering out the product, and processing the product to get the chloromethylated polyphenylene sulfide fiber; then, adding dichloroethane for swelling, adding alcohol, N-methylimidazole and tetrabutylammonium bromide after swelling, heating up for reaction, filtering out the product after reaction, and sequentially washing, extracting, washing with brine and drying the product, thereby obtaining the product PPS -based N-methylimidazole strong base type ion exchange fiber. The PPS-based N-methylimidazole strong base type ion exchange fiber prepared according to the invention has the characteristics of high oxidation resistance, excellent chemical stability, larger adsorbing capacity, excellent absorption and regeneration performance and the like. The preparation method of the PPS -based N-methylimidazole strong base type ion exchange fiber is simple, low in production cost and easy to generalize in industry.</abstract><oa>free_for_read</oa></addata></record> |
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subjects | CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR LAUNDERING PERFORMING OPERATIONS PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL TEXTILES THEIR RELEVANT APPARATUS TRANSPORTING TREATMENT OF TEXTILES OR THE LIKE TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS,FABRICS, FEATHERS, OR FIBROUS GOODS MADE FROM SUCH MATERIALS |
title | Preparation method of PPS (polyphenylene sulfide)-based N-methylimidazole strong base type ion exchange fiber |
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