RECOVERY OF SO2 FROM WASTE GAS EMISSIONS

A process for recovering sulfur values from gas emissions by absorbing SO2 in an aqueous solution comprising a mixture of Na2HPO4 and NaH2PO4 at a pH between about 2.5 and about 5 at an absorption temperature between about 85 DEG and about 200 DEG F., treating the phosphate solution containing absor...

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Hauptverfasser: SHERIF, FAWZY G, HAYFORD, JOHN S, BLANCH, JULIAN E
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creator SHERIF, FAWZY G
HAYFORD, JOHN S
BLANCH, JULIAN E
description A process for recovering sulfur values from gas emissions by absorbing SO2 in an aqueous solution comprising a mixture of Na2HPO4 and NaH2PO4 at a pH between about 2.5 and about 5 at an absorption temperature between about 85 DEG and about 200 DEG F., treating the phosphate solution containing absorbed SO2 with H2S to produce sulfur, separating the sulfur from the phosphate solution and recycling the phosphate solution to the absorber. Provision is made to remove sulfate, which builds up in phosphate absorbent, by crystallizing sulfate from a purge stream. The process is particularly useful in the field of pollution abatement for recovering SO2 from the off-gas obtained from a Claus-type reactor system.
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subjects CHEMISTRY
COMPOUNDS THEREOF
GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS
INORGANIC CHEMISTRY
METALLURGY
NON-METALLIC ELEMENTS
PERFORMING OPERATIONS
PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
SEPARATION
TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINSTCLIMATE CHANGE
TRANSPORTING
title RECOVERY OF SO2 FROM WASTE GAS EMISSIONS
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