METHODS FOR DESIGNING POLYISOCYANURATE FOAM-FORMING COMPOSITIONS, RELATED POLYISOCYANURATE FOAM-FORMING COMPOSITIONS, AND FOAMS PRODUCED THEREBY

Disclosed are methods for designing a polyisocyanurate foam-forming composition with good low temperature insulation performance. The methods include: (a) measuring the LTTR of a first polyisocyanurate faced foam laminate prepared from a first polyisocyanurate foam-forming composition comprising a b...

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Hauptverfasser: COMBS, GEORGE, PHELAN, GERALD W
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PHELAN, GERALD W
description Disclosed are methods for designing a polyisocyanurate foam-forming composition with good low temperature insulation performance. The methods include: (a) measuring the LTTR of a first polyisocyanurate faced foam laminate prepared from a first polyisocyanurate foam-forming composition comprising a blowing agent composition comprising one or more hydrocarbon blowing agents with an atmospheric pressure boiling point of at least 68ºF (20°C), wherein the LTTR is measured according to CAN/UL S770-09 at a plurality of temperatures to identify a calculated inflection point temperature below which defines a first mathematical correlation between temperature and the LTTR of the first polyisocyanurate faced foam laminate and above which defines a second mathematical correlation between temperature and the LTTR of the first polyisocyanurate faced foam laminate; (b) identifying a plurality of predicted mathematical correlations between temperature and the LTTR of the first polyisocyanurate faced foam laminate at a plurality of reduced inflection point temperatures below the calculated inflection point temperature; and (c) using the plurality of predicted mathematical correlations identified in step (b) to design a second polyisocyanurate foam-forming composition that is different from the first polyisocyanurate foam-forming composition and which comprises a blowing agent composition comprising one or more hydrocarbon blowing agents with an atmospheric pressure boiling point of at least 68ºF (20ºC), wherein the second polyisocyanurate foam-forming composition produces a second polyisocyanurate faced foam laminate that has a LTTR of at least 5.4 ft2hrºF/BTUinch (0.936 m2ºC/WP25 mm) at all mean insulation temperatures within a temperature range of 10ºF to 75ºF (-12.2ºC to 23.9ºC), when measured according to CAN/UL S770-09.
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The methods include: (a) measuring the LTTR of a first polyisocyanurate faced foam laminate prepared from a first polyisocyanurate foam-forming composition comprising a blowing agent composition comprising one or more hydrocarbon blowing agents with an atmospheric pressure boiling point of at least 68ºF (20°C), wherein the LTTR is measured according to CAN/UL S770-09 at a plurality of temperatures to identify a calculated inflection point temperature below which defines a first mathematical correlation between temperature and the LTTR of the first polyisocyanurate faced foam laminate and above which defines a second mathematical correlation between temperature and the LTTR of the first polyisocyanurate faced foam laminate; (b) identifying a plurality of predicted mathematical correlations between temperature and the LTTR of the first polyisocyanurate faced foam laminate at a plurality of reduced inflection point temperatures below the calculated inflection point temperature; and (c) using the plurality of predicted mathematical correlations identified in step (b) to design a second polyisocyanurate foam-forming composition that is different from the first polyisocyanurate foam-forming composition and which comprises a blowing agent composition comprising one or more hydrocarbon blowing agents with an atmospheric pressure boiling point of at least 68ºF (20ºC), wherein the second polyisocyanurate foam-forming composition produces a second polyisocyanurate faced foam laminate that has a LTTR of at least 5.4 ft2hrºF/BTUinch (0.936 m2ºC/WP25 mm) at all mean insulation temperatures within a temperature range of 10ºF to 75ºF (-12.2ºC to 23.9ºC), when measured according to CAN/UL S770-09.</abstract><oa>free_for_read</oa></addata></record>
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subjects AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F,C08G
BUILDING
BUILDING MATERIALS
CEILINGS
CHEMISTRY
COMPOSITIONS BASED THEREON
FIXED CONSTRUCTIONS
FLOORS
GENERAL BUILDING CONSTRUCTIONS
GENERAL PROCESSES OF COMPOUNDING
INSULATION OR OTHER PROTECTION OF BUILDINGS
INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIRCHEMICAL OR PHYSICAL PROPERTIES
LAYERED PRODUCTS
LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT ORNON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONSONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
MEASURING
METALLURGY
ORGANIC MACROMOLECULAR COMPOUNDS
PERFORMING OPERATIONS
PHYSICS
ROOFS
STRUCTURAL ELEMENTS
TESTING
THEIR PREPARATION OR CHEMICAL WORKING-UP
TRANSPORTING
WALLS, e.g. PARTITIONS
WORKING-UP
title METHODS FOR DESIGNING POLYISOCYANURATE FOAM-FORMING COMPOSITIONS, RELATED POLYISOCYANURATE FOAM-FORMING COMPOSITIONS, AND FOAMS PRODUCED THEREBY
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