MOLECULARLY IMPRINTED POLYMER BEADS FOR EXTRACTION OF METALS AND USES THEREOF

A plurality of macroreticular polymer beads include a copolymer having a plurality of complexing cavities which selectively bind a target metal ion. The copolymer is prepared from a ligand monomer which is cationic or anionic and is complexed to a non-metal surrogate ion, a non-ligand monomer, and a...

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Hauptverfasser: GLUCKMAN, JONATHAN P, SOUTHARD, GLEN E
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creator GLUCKMAN, JONATHAN P
SOUTHARD, GLEN E
description A plurality of macroreticular polymer beads include a copolymer having a plurality of complexing cavities which selectively bind a target metal ion. The copolymer is prepared from a ligand monomer which is cationic or anionic and is complexed to a non-metal surrogate ion, a non-ligand monomer, and a crosslinking monomer. The charge of the copolymer in the complexing cavity is opposite the charge of the target metal ion, and the non-metal surrogate ion has substantially the same shape and charge as the target metal ion. Il est décrit plusieurs billes polymériques macroréticulaires qui comprennent un copolymère comportant plusieurs cavités de complexation, lesquelles cavités se lient à un ion métallique cible de manière sélective. On prépare le copolymère à partir d'un monomère ligand complexé à un ion non métallique substitut, un monomère non-ligand et un monomère de réticulation, lequel monomère ligand comprend in ion positif ou négatif. La charge du copolymère situé dans la cavité de complexation est contraire à la charge de l'ion métallique cible, tandis que l'ion substitut non métallique comporte essentiellement la même forme et la même charge que l'ion métallique cible.
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subjects CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY
CHEMISTRY
FERROUS OR NON-FERROUS ALLOYS
METALLURGY
PERFORMING OPERATIONS
PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
PRETREATMENT OF RAW MATERIALS
PRODUCTION AND REFINING OF METALS
SEPARATION
THEIR RELEVANT APPARATUS
TRANSPORTING
TREATMENT OF ALLOYS OR NON-FERROUS METALS
title MOLECULARLY IMPRINTED POLYMER BEADS FOR EXTRACTION OF METALS AND USES THEREOF
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