SEPARATION OF HYDROGEN SULFIDE FROM NATURAL GAS
A process for increasing the selectivity of an alkanolamine absorption process for selectively removing hydrogen sulfide (H2S) from a gas mixture which also contains carbon dioxide (C02) and possibly other acidic gases such as COS, HCN, CS2 and sulfur derivatives of C1 to C4 hydrocarbons, comprises...
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creator | KORTUNOV, PAVEL SISKIN, MICHAEL FEDICH, ROBERT B |
description | A process for increasing the selectivity of an alkanolamine absorption process for selectively removing hydrogen sulfide (H2S) from a gas mixture which also contains carbon dioxide (C02) and possibly other acidic gases such as COS, HCN, CS2 and sulfur derivatives of C1 to C4 hydrocarbons, comprises contacting the gas mixture with a liquid absorbent which is a severely sterically hindered capped alkanolamine or more basic sterically hindered secondary and tertiary amine. The improvement in selectivity is achieved at the high(er) pressures, typically least about 10 bara at conditions nearing the H2S/C02 equilibrium at which C02 begins to displace absorbed hydrosulfide species from the absorbent solution. |
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subjects | ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE ORUNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSEGASES [GHG] CHEMISTRY FIRELIGHTERS FUELS FUELS NOT OTHERWISE PROVIDED FOR GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS LIQUEFIED PETROLEUM GAS LUBRICANTS METALLURGY NATURAL GAS PEAT PERFORMING OPERATIONS PETROLEUM, GAS OR COKE INDUSTRIES PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL SEPARATION SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BYSUBCLASSES C10G, C10K TECHNICAL GASES CONTAINING CARBON MONOXIDE TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINSTCLIMATE CHANGE TRANSPORTING |
title | SEPARATION OF HYDROGEN SULFIDE FROM NATURAL GAS |
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