SEPARATION OF HYDROGEN SULFIDE FROM NATURAL GAS

A process for increasing the selectivity of an alkanolamine absorption process for selectively removing hydrogen sulfide (H2S) from a gas mixture which also contains carbon dioxide (C02) and possibly other acidic gases such as COS, HCN, CS2 and sulfur derivatives of C1 to C4 hydrocarbons, comprises...

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Hauptverfasser: KORTUNOV, PAVEL, SISKIN, MICHAEL, FEDICH, ROBERT B
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creator KORTUNOV, PAVEL
SISKIN, MICHAEL
FEDICH, ROBERT B
description A process for increasing the selectivity of an alkanolamine absorption process for selectively removing hydrogen sulfide (H2S) from a gas mixture which also contains carbon dioxide (C02) and possibly other acidic gases such as COS, HCN, CS2 and sulfur derivatives of C1 to C4 hydrocarbons, comprises contacting the gas mixture with a liquid absorbent which is a severely sterically hindered capped alkanolamine or more basic sterically hindered secondary and tertiary amine. The improvement in selectivity is achieved at the high(er) pressures, typically least about 10 bara at conditions nearing the H2S/C02 equilibrium at which C02 begins to displace absorbed hydrosulfide species from the absorbent solution.
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subjects ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE ORUNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL
CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSEGASES [GHG]
CHEMISTRY
FIRELIGHTERS
FUELS
FUELS NOT OTHERWISE PROVIDED FOR
GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS
LIQUEFIED PETROLEUM GAS
LUBRICANTS
METALLURGY
NATURAL GAS
PEAT
PERFORMING OPERATIONS
PETROLEUM, GAS OR COKE INDUSTRIES
PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
SEPARATION
SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BYSUBCLASSES C10G, C10K
TECHNICAL GASES CONTAINING CARBON MONOXIDE
TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINSTCLIMATE CHANGE
TRANSPORTING
title SEPARATION OF HYDROGEN SULFIDE FROM NATURAL GAS
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