COLORED CHARGED SILSESQUIOXANES

The present invention provides salts of a cation and an anion, wherein the cation comprises (i) a silsesquioxane moiety of formula (1) (ii) a chromophoric moiety D, which may which may be substituted with one or more substituents selected from the group consisting of C1-10-alkyl, phenyl, halogen, OC...

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Hauptverfasser: BAISCH, GABRIELE, OHRLEIN, REINHOLD
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creator BAISCH, GABRIELE
OHRLEIN, REINHOLD
description The present invention provides salts of a cation and an anion, wherein the cation comprises (i) a silsesquioxane moiety of formula (1) (ii) a chromophoric moiety D, which may which may be substituted with one or more substituents selected from the group consisting of C1-10-alkyl, phenyl, halogen, OC1-6-alkyl, OH, NH2 and NO2, and (iii) a moiety of formula (2) wherein L4 is C1-20-alkylene, phenylene-C1-20-alkylene or C1-20-alkylene-phenylene-C1-20-alkylene, R11, R12, R13 and R14 are independently from each other hydrogen or C1-4-alkyl, R15, R16, R17 and R18 are independently from each other C1-4-alkyl, R19 is C1-20-alkyl, which may be substituted with phenyl, O-C1-6-alkyl or NO2, and d is an integer from 1 to 25, and electrophoretic devices comprising the salts. L'invention concerne des sels d'un cation et d'un anion, ledit cation comprenant (i) une fraction silsesquioxane de formule (1) (ii) une fraction chromophore D, qui peut être substituée ou non par un ou plusieurs substituants choisis dans le groupe constitué par C1-10-alkyl, phényl, halogène, OC1-6-alkyle, OH, NH2 et NO2, et (iii) une fraction de formule (2), L4 étant C1-20-alkylène, phénylène-C1-20-alkylène ou C1-20-alkylène-phénylène-C1-20-alkylène, R11, R12, R13 et R14 étant indépendamment les uns des autres hydrogène ou C1-4-alkyle, R15, R16, R17 et R18 étant indépendamment les uns des autres C1-4-alkyle, R19 étant C1-20-alkyle, qui peut être substitué par phényle, O-C1-6-alkyle ou NO2, et d un nombre entier compris entre 1 et 25. L'invention concerne également des dispositifs électrophorèse comprenant les sels.
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L'invention concerne des sels d'un cation et d'un anion, ledit cation comprenant (i) une fraction silsesquioxane de formule (1) (ii) une fraction chromophore D, qui peut être substituée ou non par un ou plusieurs substituants choisis dans le groupe constitué par C1-10-alkyl, phényl, halogène, OC1-6-alkyle, OH, NH2 et NO2, et (iii) une fraction de formule (2), L4 étant C1-20-alkylène, phénylène-C1-20-alkylène ou C1-20-alkylène-phénylène-C1-20-alkylène, R11, R12, R13 et R14 étant indépendamment les uns des autres hydrogène ou C1-4-alkyle, R15, R16, R17 et R18 étant indépendamment les uns des autres C1-4-alkyle, R19 étant C1-20-alkyle, qui peut être substitué par phényle, O-C1-6-alkyle ou NO2, et d un nombre entier compris entre 1 et 25. 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L'invention concerne des sels d'un cation et d'un anion, ledit cation comprenant (i) une fraction silsesquioxane de formule (1) (ii) une fraction chromophore D, qui peut être substituée ou non par un ou plusieurs substituants choisis dans le groupe constitué par C1-10-alkyl, phényl, halogène, OC1-6-alkyle, OH, NH2 et NO2, et (iii) une fraction de formule (2), L4 étant C1-20-alkylène, phénylène-C1-20-alkylène ou C1-20-alkylène-phénylène-C1-20-alkylène, R11, R12, R13 et R14 étant indépendamment les uns des autres hydrogène ou C1-4-alkyle, R15, R16, R17 et R18 étant indépendamment les uns des autres C1-4-alkyle, R19 étant C1-20-alkyle, qui peut être substitué par phényle, O-C1-6-alkyle ou NO2, et d un nombre entier compris entre 1 et 25. 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L'invention concerne des sels d'un cation et d'un anion, ledit cation comprenant (i) une fraction silsesquioxane de formule (1) (ii) une fraction chromophore D, qui peut être substituée ou non par un ou plusieurs substituants choisis dans le groupe constitué par C1-10-alkyl, phényl, halogène, OC1-6-alkyle, OH, NH2 et NO2, et (iii) une fraction de formule (2), L4 étant C1-20-alkylène, phénylène-C1-20-alkylène ou C1-20-alkylène-phénylène-C1-20-alkylène, R11, R12, R13 et R14 étant indépendamment les uns des autres hydrogène ou C1-4-alkyle, R15, R16, R17 et R18 étant indépendamment les uns des autres C1-4-alkyle, R19 étant C1-20-alkyle, qui peut être substitué par phényle, O-C1-6-alkyle ou NO2, et d un nombre entier compris entre 1 et 25. L'invention concerne également des dispositifs électrophorèse comprenant les sels.</abstract><oa>free_for_read</oa></addata></record>
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subjects ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAININGELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN,SULFUR, SELENIUM OR TELLURIUM
CHEMISTRY
COMPOSITIONS BASED THEREON
DEVICES OR ARRANGEMENTS, THE OPTICAL OPERATION OF WHICH ISMODIFIED BY CHANGING THE OPTICAL PROPERTIES OF THE MEDIUM OF THEDEVICES OR ARRANGEMENTS FOR THE CONTROL OF THE INTENSITY,COLOUR, PHASE, POLARISATION OR DIRECTION OF LIGHT, e.g.SWITCHING, GATING, MODULATING OR DEMODULATING
FREQUENCY-CHANGING
MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONSONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
METALLURGY
NON-LINEAR OPTICS
OPTICAL ANALOGUE/DIGITAL CONVERTERS
OPTICAL LOGIC ELEMENTS
OPTICS
ORGANIC CHEMISTRY
ORGANIC MACROMOLECULAR COMPOUNDS
PHYSICS
TECHNIQUES OR PROCEDURES FOR THE OPERATION THEREOF
THEIR PREPARATION OR CHEMICAL WORKING-UP
title COLORED CHARGED SILSESQUIOXANES
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