AZOCARBONYL-FUNCTIONALIZED SILANES

The invention provides azocarbonyl-functionalized silanes of the general formula I (R1)3-a(R2)a Si-R l-NH-C(O)-N=N-R4. They are prepared by a procedure in which in a first step hydrazine of the formula H2N-NH-R4 reacts with an isocyanatosilane of the general formula (R1)3-a(R2)a Si-R l-NCO, and in a...

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Bibliographische Detailangaben
Hauptverfasser: KECK, JULIA, ERHARDT, SASCHA, PETERLE, TORSTEN, BLUME, ANKE, ROBEN, CAREN
Format: Patent
Sprache:eng ; fre
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Zusammenfassung:The invention provides azocarbonyl-functionalized silanes of the general formula I (R1)3-a(R2)a Si-R l-NH-C(O)-N=N-R4. They are prepared by a procedure in which in a first step hydrazine of the formula H2N-NH-R4 reacts with an isocyanatosilane of the general formula (R1)3-a(R2)a Si-R l-NCO, and in a second step the product of the first step is oxidized with an oxidant, or in which in a first step hydrazine of the formula H2N-NH-R4 reacts with an acyl halide of the general formula CI-C(O)-O-R5, in a second step the product of the first step is oxidized with an oxidant and in a third step the product of the second step reacts with an aminosilane of the general formula (R1)3-a(R2)a Si-R l-NH2. It may be used for moldings.