CLEANING COMPOSITIONS COMPRISING PH-SWITCHABLE AMINE SURFACTANTS
A cleaning composition comprises a pH-switchable sudsing system and a cleansing system. The pH-switchable sudsing system comprises a primary sudsing agent in combination with a pH-switchable co- surfactant. The pH-switchable co-surfactant is selected from diamine molecules having a general formula R...
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creator | WOS, JOHN AUGUST GARDNER, ROBB RICHARD BATES, TIM OH, HIROSHI |
description | A cleaning composition comprises a pH-switchable sudsing system and a cleansing system. The pH-switchable sudsing system comprises a primary sudsing agent in combination with a pH-switchable co- surfactant. The pH-switchable co-surfactant is selected from diamine molecules having a general formula R1R2-N-R3-N+ (CH3)X, where R1 is a linear or branched C8 to C16 hydrocarbyl, R2 is a linear or branched C1 to C3 hydrocarbyl, R3 is a linear or branched C3 to C6 hydrocarbylene, and X is a counteranion. The tertiary amine nitrogen of the pH-switchable co-surfactant has a pKa value. When the tertiary amine nitrogen is unprotonated, the pH-switchable co-surfactant may provide a suds-boosting effect in washing solutions at a washing pH above the pKa. When the tertiary amine nitrogen is protonated, the pH-switchable co-surfactant may provide a suds-reducing benefit in rinse waters at a rinse pH below the pKa. |
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The pH-switchable sudsing system comprises a primary sudsing agent in combination with a pH-switchable co- surfactant. The pH-switchable co-surfactant is selected from diamine molecules having a general formula R1R2-N-R3-N+ (CH3)X, where R1 is a linear or branched C8 to C16 hydrocarbyl, R2 is a linear or branched C1 to C3 hydrocarbyl, R3 is a linear or branched C3 to C6 hydrocarbylene, and X is a counteranion. The tertiary amine nitrogen of the pH-switchable co-surfactant has a pKa value. When the tertiary amine nitrogen is unprotonated, the pH-switchable co-surfactant may provide a suds-boosting effect in washing solutions at a washing pH above the pKa. When the tertiary amine nitrogen is protonated, the pH-switchable co-surfactant may provide a suds-reducing benefit in rinse waters at a rinse pH below the pKa.</description><language>eng ; fre</language><subject>ANIMAL AND VEGETABLE OILS, FATS, FATTY SUBSTANCES AND WAXES ; CANDLES ; CHEMISTRY ; DETERGENT COMPOSITIONS ; DETERGENTS ; FATTY ACIDS THEREFROM ; METALLURGY ; RECOVERY OF GLYCEROL ; RESIN SOAPS ; SOAP OR SOAP-MAKING ; USE OF SINGLE SUBSTANCES AS DETERGENTS</subject><creationdate>2016</creationdate><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://worldwide.espacenet.com/publicationDetails/biblio?FT=D&date=20160927&DB=EPODOC&CC=CA&NR=2867296C$$EHTML$$P50$$Gepo$$Hfree_for_read</linktohtml><link.rule.ids>230,308,780,885,25564,76547</link.rule.ids><linktorsrc>$$Uhttps://worldwide.espacenet.com/publicationDetails/biblio?FT=D&date=20160927&DB=EPODOC&CC=CA&NR=2867296C$$EView_record_in_European_Patent_Office$$FView_record_in_$$GEuropean_Patent_Office$$Hfree_for_read</linktorsrc></links><search><creatorcontrib>WOS, JOHN AUGUST</creatorcontrib><creatorcontrib>GARDNER, ROBB RICHARD</creatorcontrib><creatorcontrib>BATES, TIM</creatorcontrib><creatorcontrib>OH, HIROSHI</creatorcontrib><title>CLEANING COMPOSITIONS COMPRISING PH-SWITCHABLE AMINE SURFACTANTS</title><description>A cleaning composition comprises a pH-switchable sudsing system and a cleansing system. The pH-switchable sudsing system comprises a primary sudsing agent in combination with a pH-switchable co- surfactant. The pH-switchable co-surfactant is selected from diamine molecules having a general formula R1R2-N-R3-N+ (CH3)X, where R1 is a linear or branched C8 to C16 hydrocarbyl, R2 is a linear or branched C1 to C3 hydrocarbyl, R3 is a linear or branched C3 to C6 hydrocarbylene, and X is a counteranion. The tertiary amine nitrogen of the pH-switchable co-surfactant has a pKa value. When the tertiary amine nitrogen is unprotonated, the pH-switchable co-surfactant may provide a suds-boosting effect in washing solutions at a washing pH above the pKa. 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The pH-switchable sudsing system comprises a primary sudsing agent in combination with a pH-switchable co- surfactant. The pH-switchable co-surfactant is selected from diamine molecules having a general formula R1R2-N-R3-N+ (CH3)X, where R1 is a linear or branched C8 to C16 hydrocarbyl, R2 is a linear or branched C1 to C3 hydrocarbyl, R3 is a linear or branched C3 to C6 hydrocarbylene, and X is a counteranion. The tertiary amine nitrogen of the pH-switchable co-surfactant has a pKa value. When the tertiary amine nitrogen is unprotonated, the pH-switchable co-surfactant may provide a suds-boosting effect in washing solutions at a washing pH above the pKa. When the tertiary amine nitrogen is protonated, the pH-switchable co-surfactant may provide a suds-reducing benefit in rinse waters at a rinse pH below the pKa.</abstract><oa>free_for_read</oa></addata></record> |
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subjects | ANIMAL AND VEGETABLE OILS, FATS, FATTY SUBSTANCES AND WAXES CANDLES CHEMISTRY DETERGENT COMPOSITIONS DETERGENTS FATTY ACIDS THEREFROM METALLURGY RECOVERY OF GLYCEROL RESIN SOAPS SOAP OR SOAP-MAKING USE OF SINGLE SUBSTANCES AS DETERGENTS |
title | CLEANING COMPOSITIONS COMPRISING PH-SWITCHABLE AMINE SURFACTANTS |
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