PROCESS FOR RECOVERY OF PRECIOUS METALS

A process for the recovery of metals (hereinafter PM) from solids includes dissolving the PM and base metals in acid. The PM are precipitated using substituted quaternary ammonium salts (hereinafter SQAS). The PM may be oxidized or reduced. The substituted quaternary ammonium salts are generally sta...

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Hauptverfasser: THOMAS, JOSEPH L, BREM, GERALD F
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creator THOMAS, JOSEPH L
BREM, GERALD F
description A process for the recovery of metals (hereinafter PM) from solids includes dissolving the PM and base metals in acid. The PM are precipitated using substituted quaternary ammonium salts (hereinafter SQAS). The PM may be oxidized or reduced. The substituted quaternary ammonium salts are generally stated as H R NX where H = hydrogen, R = organic group, N = nitrogen and X = halide, tetramethylammonium chloride being employed in the Examples. Au-SQAS is separated by washing with solvent. Rh-SQAS is dissolved in acid, oxidized to precipitate salts and separated. SQAS is added to the filtrate, heated and cooled to precipitate Rh- SQAS which is separated. Rh-SQAS is purified before forming a final product. Other metals are separated by boiling the initial acidic solution of metals to precipitate metal salts, cooling and separating. The filtrate is oxidized. Pd-SQAS is dissolved and separated. A slurry is separated by dissolving and separating.
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The PM may be oxidized or reduced. The substituted quaternary ammonium salts are generally stated as H R NX where H = hydrogen, R = organic group, N = nitrogen and X = halide, tetramethylammonium chloride being employed in the Examples. Au-SQAS is separated by washing with solvent. Rh-SQAS is dissolved in acid, oxidized to precipitate salts and separated. SQAS is added to the filtrate, heated and cooled to precipitate Rh- SQAS which is separated. Rh-SQAS is purified before forming a final product. Other metals are separated by boiling the initial acidic solution of metals to precipitate metal salts, cooling and separating. The filtrate is oxidized. Pd-SQAS is dissolved and separated. 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subjects CHEMISTRY
CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION ORPROCESSING OF GOODS
FERROUS OR NON-FERROUS ALLOYS
GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS
METALLURGY
PRETREATMENT OF RAW MATERIALS
PRODUCTION AND REFINING OF METALS
TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINSTCLIMATE CHANGE
TREATMENT OF ALLOYS OR NON-FERROUS METALS
title PROCESS FOR RECOVERY OF PRECIOUS METALS
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