AQUEOUS DISPERSIONS OF POLYMER PARTICLES

The invention provides a method for preparing an aqueous dispersion of polymer particles comprising the following steps: (i) preparing a dispersion having a continuous aqueous phase, a dispersed organic phase comprising one or more ethylenically unsaturated monomers, and an amphiphilic RAFT agent as...

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Hauptverfasser: SUCH, CHRISTOPHER HENRY, HAWKETT, BRIAN STANLEY, GILBERT, ROBERT GOULSTON, HUGHES, ROBERT JOHN, SERELIS, ALGIRDAS KAZIMIERAS, FERGUSON, CHRISTOPHER JAMES, RIZZARDO, EZIO
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creator SUCH, CHRISTOPHER HENRY
HAWKETT, BRIAN STANLEY
GILBERT, ROBERT GOULSTON
HUGHES, ROBERT JOHN
SERELIS, ALGIRDAS KAZIMIERAS
FERGUSON, CHRISTOPHER JAMES
RIZZARDO, EZIO
description The invention provides a method for preparing an aqueous dispersion of polymer particles comprising the following steps: (i) preparing a dispersion having a continuous aqueous phase, a dispersed organic phase comprising one or more ethylenically unsaturated monomers, and an amphiphilic RAFT agent as a stabiliser for said organic phase, and (ii) polymerising said one or more ethylenically unsaturated monomers under the control of said amphiphilic RAFT agent to form said aqueous dispersion of polymer particles, novel amphiphilic RAFT agents for use in this method, novel RAFT agents useful in making these amphiphilic RAFT agents and methods for their manufacture. L'invention concerne un procédé de préparation d'une dispersion aqueuse de particules de polymère consistant (i) à préparer une dispersion comprenant une phase continue, une phase organique dispersée contenant un ou plusieurs monomères à insaturations éthyléniques et un agent amphiphile de transfert de chaîne par fragmentation-addition réversible (RAFT) en tant qu'agent de stabilisation de la phase organique, et (ii) à polymériser les monomères à insaturations éthyléniques sous régulation de l'agent amphiphile RAFT afin d'obtenir la dispersion aqueuse de particules de polymère. L'invention concerne aussi des agents amphiphiles RAFT utilisés dans le procédé, des agents RAFT utiles dans la fabrication de ces agents amphiphiles RAFT, ainsi que leurs procédés de fabrication.
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L'invention concerne un procédé de préparation d'une dispersion aqueuse de particules de polymère consistant (i) à préparer une dispersion comprenant une phase continue, une phase organique dispersée contenant un ou plusieurs monomères à insaturations éthyléniques et un agent amphiphile de transfert de chaîne par fragmentation-addition réversible (RAFT) en tant qu'agent de stabilisation de la phase organique, et (ii) à polymériser les monomères à insaturations éthyléniques sous régulation de l'agent amphiphile RAFT afin d'obtenir la dispersion aqueuse de particules de polymère. L'invention concerne aussi des agents amphiphiles RAFT utilisés dans le procédé, des agents RAFT utiles dans la fabrication de ces agents amphiphiles RAFT, ainsi que leurs procédés de fabrication.</abstract><oa>free_for_read</oa></addata></record>
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language eng ; fre
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subjects ACYCLIC OR CARBOCYCLIC COMPOUNDS
ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE
ADHESIVES
CHEMICAL PAINT OR INK REMOVERS
CHEMISTRY
COATING COMPOSITIONS, e.g. PAINTS, VARNISHES ORLACQUERS
COMPOSITIONS BASED THEREON
CORRECTING FLUIDS
DYES
FILLING PASTES
INKS
MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVINGCARBON-TO-CARBON UNSATURATED BONDS
MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FORELSEWHERE
METALLURGY
MISCELLANEOUS APPLICATIONS OF MATERIALS
MISCELLANEOUS COMPOSITIONS
NATURAL RESINS
NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL
ORGANIC CHEMISTRY
ORGANIC MACROMOLECULAR COMPOUNDS
PAINTS
PASTES OR SOLIDS FOR COLOURING OR PRINTING
POLISHES
THEIR PREPARATION OR CHEMICAL WORKING-UP
USE OF INORGANIC OR NON-MACROMOLECULAR ORGANIC SUBSTANCES ASCOMPOUNDING INGREDIENTS
USE OF MATERIALS AS ADHESIVES
USE OF MATERIALS THEREFOR
WOODSTAINS
title AQUEOUS DISPERSIONS OF POLYMER PARTICLES
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