SURFACE COATINGS

A method of coating a surface with a polymer layer, which method comprises exposing said surface to a plasma comprising a monomeric unsaturated organic compound which comprises a chain of carbon atoms, which are optionally substituted by halogen; provided that where the compound is a perhalogenated...

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Hauptverfasser: BREWER, STUART ANSON, WILLIS, COLIN ROBERT, COULSON, STEPHEN RICHARD, BADYAL, JAS PAL SINGH
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creator BREWER, STUART ANSON
WILLIS, COLIN ROBERT
COULSON, STEPHEN RICHARD
BADYAL, JAS PAL SINGH
description A method of coating a surface with a polymer layer, which method comprises exposing said surface to a plasma comprising a monomeric unsaturated organic compound which comprises a chain of carbon atoms, which are optionally substituted by halogen; provided that where the compound is a perhalogenated alkene, it has a chain of at least 5 carbon atoms; so as to form an oil or water repellent coating on said substrate. Suitable compounds for use in the methods are compounds of formula (I) where R1, R2 a nd R3 are independently selected from hydrogen, alkyl, haloalkyl or aryl optionally substituted by halo; provided that at least one of R1, R2 or R3 is hydrogen, and R4 is a group X-R5 where R5 is an alkyl or haloalkyl group and X is a bond; a group of formula -C(O)O(CH2)n Y- where n is an integer of from 1 to 10 and Y is a bond or a sulphonamide group; or a group -(O)p R6(O)q(CH2)t- where R6 is aryl optionally substituted by halo, p is 0 or 1, q is 0 or 1 and t is 0 or an integer of from 1 to 10, provided that where q is 1, t is other than 0. The method is particularly useful in the production of oil- and/or water repellent fabrics.
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Suitable compounds for use in the methods are compounds of formula (I) where R1, R2 a nd R3 are independently selected from hydrogen, alkyl, haloalkyl or aryl optionally substituted by halo; provided that at least one of R1, R2 or R3 is hydrogen, and R4 is a group X-R5 where R5 is an alkyl or haloalkyl group and X is a bond; a group of formula -C(O)O(CH2)n Y- where n is an integer of from 1 to 10 and Y is a bond or a sulphonamide group; or a group -(O)p R6(O)q(CH2)t- where R6 is aryl optionally substituted by halo, p is 0 or 1, q is 0 or 1 and t is 0 or an integer of from 1 to 10, provided that where q is 1, t is other than 0. 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provided that where the compound is a perhalogenated alkene, it has a chain of at least 5 carbon atoms; so as to form an oil or water repellent coating on said substrate. Suitable compounds for use in the methods are compounds of formula (I) where R1, R2 a nd R3 are independently selected from hydrogen, alkyl, haloalkyl or aryl optionally substituted by halo; provided that at least one of R1, R2 or R3 is hydrogen, and R4 is a group X-R5 where R5 is an alkyl or haloalkyl group and X is a bond; a group of formula -C(O)O(CH2)n Y- where n is an integer of from 1 to 10 and Y is a bond or a sulphonamide group; or a group -(O)p R6(O)q(CH2)t- where R6 is aryl optionally substituted by halo, p is 0 or 1, q is 0 or 1 and t is 0 or an integer of from 1 to 10, provided that where q is 1, t is other than 0. The method is particularly useful in the production of oil- and/or water repellent fabrics.</abstract><oa>free_for_read</oa></addata></record>
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subjects ADHESIVES
AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
APPLYING LIQUIDS OR OTHER FLUENT MATERIALS TO SURFACES, IN GENERAL
CHEMICAL SURFACE TREATMENT
CHEMISTRY
COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATIONOR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY IONIMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
COATING MATERIAL WITH METALLIC MATERIAL
COATING METALLIC MATERIAL
DIFFUSION TREATMENT OF METALLIC MATERIAL
DYES
FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
IMPREGNATING OR COATING OF PAPER
INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION INGENERAL
LAUNDERING
MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FORELSEWHERE
METALLURGY
MISCELLANEOUS APPLICATIONS OF MATERIALS
MISCELLANEOUS COMPOSITIONS
NATURAL RESINS
PAINTS
PAPER NOT OTHERWISE PROVIDED FOR
PAPER-MAKING
PERFORMING OPERATIONS
POLISHES
PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D
PROCESSES FOR APPLYING LIQUIDS OR OTHER FLUENT MATERIALS TOSURFACES, IN GENERAL
PRODUCTION OF CELLULOSE
PULP COMPOSITIONS
SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDEDFOR
SHAPING OR JOINING OF PLASTICS
SPRAYING OR ATOMISING IN GENERAL
SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THESURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION
TEXTILES
TRANSPORTING
TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G
TREATMENT OF TEXTILES OR THE LIKE
TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS,FABRICS, FEATHERS, OR FIBROUS GOODS MADE FROM SUCH MATERIALS
WORKING OF PLASTICS
WORKING OF SUBSTANCES IN A PLASTIC STATE, IN GENERAL
title SURFACE COATINGS
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