NOVEL PROCESS FOR PREPARING 2,6-DI(4,6-DIMETHOXYPYRIMIDIN-2-YL) OXYBENZOIC ACID OXIME ESTER DERIVATIVES

A process for preparing a 2,6-di(4,6-dimethoxy-pyrimidin-2-yl)oxybenzoic acid oxime ester derivative, having a herbicidal activity and the following formula (I), (see fig. I) (I) in which R1 represents hydrogen halogen, cyano, nitro, alkyl, cycloalkyl, alkoxy, alkenyloxy, alkylthio, amino which can...

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Hauptverfasser: CHOI, NAK-HEE, KANG, CHANG-MO, AHN, SEIANG, LEE, SANG-HO, JOE, GOON-HO, KIM, KUN-TAI, SA, JONG-SIN, CHO, JIN-HO, LEE, BYOUNG-BAE, BAE, JAE-SOON, LEE, SEONG-MIN
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creator CHOI, NAK-HEE
KANG, CHANG-MO
AHN, SEIANG
LEE, SANG-HO
JOE, GOON-HO
KIM, KUN-TAI
SA, JONG-SIN
CHO, JIN-HO
LEE, BYOUNG-BAE
BAE, JAE-SOON
LEE, SEONG-MIN
description A process for preparing a 2,6-di(4,6-dimethoxy-pyrimidin-2-yl)oxybenzoic acid oxime ester derivative, having a herbicidal activity and the following formula (I), (see fig. I) (I) in which R1 represents hydrogen halogen, cyano, nitro, alkyl, cycloalkyl, alkoxy, alkenyloxy, alkylthio, amino which can be substituted with alkyl, aryl, aryloxy, acyl or acyloxy, n denotes an integer of 1 to 5, and R2 represents hydrogen, halogen, cyano, nitro, alkyl, alkoxy, alkylthio, alkoxycarbonyl, alkenyloxycarbonyl, arylmethoxycarbonyl, heteroarylmethoxy carbonyl, alkylaminocarbonyl, di (alkyl) aminocarbonyl, arylmethylaminocarbonyl, heteroarylmethylaminocarbonyl, or phenyl which can be substituted with R1. The process comprise reacting a compound having the following formula (V), (see fig II) (V) in which R represents hydrogen or alkali metal cation, with a pyrimidine derivative having the following formula (VI), (see fig. III) (VI) in which Z represents halogen, alkylsulfonyl or arylsulfonyl.
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I) (I) in which R1 represents hydrogen halogen, cyano, nitro, alkyl, cycloalkyl, alkoxy, alkenyloxy, alkylthio, amino which can be substituted with alkyl, aryl, aryloxy, acyl or acyloxy, n denotes an integer of 1 to 5, and R2 represents hydrogen, halogen, cyano, nitro, alkyl, alkoxy, alkylthio, alkoxycarbonyl, alkenyloxycarbonyl, arylmethoxycarbonyl, heteroarylmethoxy carbonyl, alkylaminocarbonyl, di (alkyl) aminocarbonyl, arylmethylaminocarbonyl, heteroarylmethylaminocarbonyl, or phenyl which can be substituted with R1. The process comprise reacting a compound having the following formula (V), (see fig II) (V) in which R represents hydrogen or alkali metal cation, with a pyrimidine derivative having the following formula (VI), (see fig. III) (VI) in which Z represents halogen, alkylsulfonyl or arylsulfonyl.</abstract><edition>6</edition><oa>free_for_read</oa></addata></record>
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subjects CHEMISTRY
HETEROCYCLIC COMPOUNDS
METALLURGY
ORGANIC CHEMISTRY
title NOVEL PROCESS FOR PREPARING 2,6-DI(4,6-DIMETHOXYPYRIMIDIN-2-YL) OXYBENZOIC ACID OXIME ESTER DERIVATIVES
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