ISOCYANATE MODIFIED CELLULOSE PRODUCTS AND METHOD FOR THEIR MANUFACTURE

The invention is a method of making a cellulose based polymeric material arid the products of the invention. A cellulosic substrate is impregnated with an essentially uncatalyzed polyfunctional isocyanate and pressed at elevated temperature and pressure. The substrate may be a chemical or thermomech...

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1. Verfasser: HUNTER, FRANK R
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description The invention is a method of making a cellulose based polymeric material arid the products of the invention. A cellulosic substrate is impregnated with an essentially uncatalyzed polyfunctional isocyanate and pressed at elevated temperature and pressure. The substrate may be a chemical or thermomechanical pulp or paper while the isocyanate is preferably diphenylmethane diisocyanate or its oligomers. Pressing conditions are preferably in the range of about 150°-245 °C at pressures in the range of about 2700-8300 kPa for times less than 2 minutes. Moisture content of the cellulosic substrate is not highly critical and may be as high as 7 % without adverse effects. The product is especially useful as overlays and for forming strong, water resistant laminates which can be molded in either flat or three dimensional forms. Méthode servant à fabriquer un matériau polymère à base de cellulose et les produits de la présente invention. Un substrat cellulosique est imprégné d'un isocyanate polyfonctionnel essentiellement non catalysé et comprimé à des températures et des pressions élevées. Le substrat peut être une pâte chimique ou thermomécanique ou du papier, tandis que l'isocyanate est de préférence du diisocyanate de diphénylméthane ou ses oligomères. Les conditions de compression sont de préférence comprises entre environ 150° et 245 °C avec des pressions appliquées allant d'environ 2700 à environ 8300 kPa pendant une durée inférieure à 2 minutes. La teneur en humidité du substrat cellulosique ne joue pas un rôle décisif et peut aller jusqu'à 7 % sans avoir d'effets négatifs. Le produit est particulièrement utile comme revêtement et permet de former des stratifiés solides qui résistent à l'eau et qui peuvent être moulés en formes plates ou tridimentionnelles.
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A cellulosic substrate is impregnated with an essentially uncatalyzed polyfunctional isocyanate and pressed at elevated temperature and pressure. The substrate may be a chemical or thermomechanical pulp or paper while the isocyanate is preferably diphenylmethane diisocyanate or its oligomers. Pressing conditions are preferably in the range of about 150°-245 °C at pressures in the range of about 2700-8300 kPa for times less than 2 minutes. Moisture content of the cellulosic substrate is not highly critical and may be as high as 7 % without adverse effects. The product is especially useful as overlays and for forming strong, water resistant laminates which can be molded in either flat or three dimensional forms. Méthode servant à fabriquer un matériau polymère à base de cellulose et les produits de la présente invention. Un substrat cellulosique est imprégné d'un isocyanate polyfonctionnel essentiellement non catalysé et comprimé à des températures et des pressions élevées. Le substrat peut être une pâte chimique ou thermomécanique ou du papier, tandis que l'isocyanate est de préférence du diisocyanate de diphénylméthane ou ses oligomères. Les conditions de compression sont de préférence comprises entre environ 150° et 245 °C avec des pressions appliquées allant d'environ 2700 à environ 8300 kPa pendant une durée inférieure à 2 minutes. La teneur en humidité du substrat cellulosique ne joue pas un rôle décisif et peut aller jusqu'à 7 % sans avoir d'effets négatifs. Le produit est particulièrement utile comme revêtement et permet de former des stratifiés solides qui résistent à l'eau et qui peuvent être moulés en formes plates ou tridimentionnelles.</abstract><edition>5</edition><oa>free_for_read</oa></addata></record>
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subjects CHEMISTRY
COMPOSITIONS BASED THEREON
COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
IMPREGNATING OR COATING OF PAPER
LAYERED PRODUCTS
LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT ORNON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONSONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
METALLURGY
ORGANIC MACROMOLECULAR COMPOUNDS
PAPER NOT OTHERWISE PROVIDED FOR
PAPER-MAKING
PERFORMING OPERATIONS
PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D
PRODUCTION OF CELLULOSE
PULP COMPOSITIONS
TEXTILES
THEIR PREPARATION OR CHEMICAL WORKING-UP
TRANSPORTING
TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G
title ISOCYANATE MODIFIED CELLULOSE PRODUCTS AND METHOD FOR THEIR MANUFACTURE
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