"remoção do cianeto de hidrogênico do gás de síntese

A process (10) for at least partially removing hydrogen cyanide from synthesis gas includes feeding a synthesis gas (30) containing hydrogen cyanide to a gas-liquid contacting stage (18) and, in the gas-liquid contacting stage (18), contacting the synthesis gas with an aqueous washing solution (36)...

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Hauptverfasser: DENISE LOUISETTE VENTER, ANDRE PETER STEYNBERG, BAVANETHAN PILLAY, TREVOR DAVID PHILLIPS, RONEL COMBRINK, HENDRIK JOHANNES VAN DER WESTHUIZEN, JOHN MARRIOTT, BRAAM VAN DYK
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creator DENISE LOUISETTE VENTER
ANDRE PETER STEYNBERG
BAVANETHAN PILLAY
TREVOR DAVID PHILLIPS
RONEL COMBRINK
HENDRIK JOHANNES VAN DER WESTHUIZEN
JOHN MARRIOTT
BRAAM VAN DYK
description A process (10) for at least partially removing hydrogen cyanide from synthesis gas includes feeding a synthesis gas (30) containing hydrogen cyanide to a gas-liquid contacting stage (18) and, in the gas-liquid contacting stage (18), contacting the synthesis gas with an aqueous washing solution (36) comprising at least one dissolved metal salt, with metal cations of the metal salt being capable of forming metal cyanide complexes and/or metal cyanide precipitates, and weak acid anions of the metal salt serving to buffer the pH of the washing solution in a range between 6 and 10. Hydrogen cyanide is washed from the synthesis gas by the washing solution to form a treated synthesis gas (38) and a spent washing solution (40). From time to time or continuously, at least a portion of the spent washing solution is withdrawn from the gas-liquid contacting stage. The treated synthesis gas (38) is also withdrawn from the gas-liquid contacting stage.
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Hydrogen cyanide is washed from the synthesis gas by the washing solution to form a treated synthesis gas (38) and a spent washing solution (40). From time to time or continuously, at least a portion of the spent washing solution is withdrawn from the gas-liquid contacting stage. 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subjects CHEMISTRY
FUELS
LUBRICANTS
METALLURGY
PEAT
PERFORMING OPERATIONS
PETROLEUM, GAS OR COKE INDUSTRIES
PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLEGASES CONTAINING CARBON MONOXIDE
SEPARATION
TECHNICAL GASES CONTAINING CARBON MONOXIDE
TRANSPORTING
title "remoção do cianeto de hidrogênico do gás de síntese
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