SISTEMA DE VULCANIZACAO, MISTURA VULCANIZAVEL E PROCESSO DE VULCANIZACAO

A vulcanization system consisting of (a) 20-50 parts by weight of sulphur or 20-50 parts by weight of a sulphur donor, (b) 20-50 parts by weight of an accelerator of the mercapto or sulphenamide group, (c) 0-10 parts by weight of a conventional accelerator additive, and (d) 20-50 parts by weight of a compound corresponding to the general formula (i): (I) wherein R1 to R5 are identical or different and denote hydrogen, halogen, nitro, cyano, CF3, CCl3, carboxyl, an alkoxy group containing 1-4 C-atoms in the alkyl part, or a C1-C4 alkyl group but the groups R1-R5 must not all be hydrogen; x represents 1-4, preferably 2-3, y represents 0 or 1, and Z denotes divalent groups such as C1-C12 alkylene, C4-C12 cycloalkylene, C6-C10 arylene or C8-C12 arylalkylene, and R6 denotes the group corresponding to the formula: wherein R1-R5 have the meaning indicated above and may all be hydrogen; C1-C12 alkyl or a C4-C12 cycloalkylene optionally substituted by OH and/or alkoxy with 1-4 C-atoms in the alkoxy group; benzyl or trichloromethyl, whereby the sum of the components (a)-(d) is 100 can be used for vulcanizing natural or synthetic rubber.