aminas impedidas por grupos n-alcóxi, substituìdas por hidróxi, processo para sua preparação, uso e composição compreendendo as mesmas, bem como processo de estabilização de polìmero orgánico ou material de registro
1-Alkoxy-substituted hindered 2,2,6,6-tetramethylpiperidine group-containing amines whose alkoxy units are substituted by 1-3 OH groups (or derivatives of such amines) are new. 1-Alkoxy-substituted hindered 2,2,6,6-tetramethylpiperidine group-containing amines whose alkoxy units are substituted by 1...
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creator | ROBERT EDWARD DETLEFSEN HENRY CLANTON GRACE GERALD ANTHONY CAPOCCI MICHAEL PETER DIFAZIO NANCY NASE CLIFF PETER SHELSEY SOLERA RAMANATHAN RAVICHANDRAN JAMES PETER GALBO CHRISTOPHER KUELL |
description | 1-Alkoxy-substituted hindered 2,2,6,6-tetramethylpiperidine group-containing amines whose alkoxy units are substituted by 1-3 OH groups (or derivatives of such amines) are new. 1-Alkoxy-substituted hindered 2,2,6,6-tetramethylpiperidine group-containing amines whose alkoxy units are substituted by 1-3 OH groups (or derivatives of such amines) are new. The amines include (i) those simply substituted with OH-substituted alkoxy groups; (ii) those with the OH-substituted alkoxy forming a bridge between 2 amine groups; or (iii) monomeric, oligomeric or polymeric products formed by reaction with dialkyl esters or isocyanates. 30 substituted hindered amines are claimed e.g. those of formula (I)-(X). [Image] [Image] [Image] [Image] [Image] [Image] [Image] [Image] [Image] G 1 and G 21-4C alkyl or together form pentamethylene; E : 1-18C alkylene, 5-18C cycloalkylene or cycloalkenylene or 1-4C alkylene substituted by phenyl which is itself optionally substituted by one or two 1-4C alkyl; b : 1, 2 or 3, but does not exceed the number of C atoms in E or L and when it is 2 or 3, each OH group is bonded to a different C atom in E and L and the 2 hindered amine groups are not bonded to 2 different C atoms in L; m : 0 or 1; R 1H, OH or CH 2OH; R 2H, 1-12C alkyl or 2-12C alkenyl; R 7 and R 8Cl, 1-8C alkoxy, -OT 1, 2-hydroxyethyl-substituted amino, 1-18C NH(alkyl), -N(1-18C alkyl)T 1 or 2-36C N(alkyl) 2; R 9-O- or = -N- substituted by H, 1-12C alkyl or T 1; T 11-((OH) b-E-O)-2,2,6,6-(G 1) 2(G 2) 2-piperidin-4-yl; R 1 0H or Me; q : 2-8; R 1 3H, phenyl, 1-12C alkyl or alkoxy, phenyl-substituted 1-4C alkyl, 5-8C cycloalk(en)yl, 2-12C alkenyl, glycidyl, allyloxy, 1-4C hydroxyalkyl or silyl or silyloxy substituted 3 times by H, phenyl or 1-4C alkyl or alkoxy; d : 0 or 1; k : 0-5; x : 3-6; y : 1-10; R 1 5morpholino, piperidino, 1-piperazinyl, 1-8C alkylamino (especially octylamino), -N(1-8C alkyl)T 1 substituted by T 1, or 2-16C N(alkyl) 2; R 1 6H, 2-4C acyl, 1-4C alkyl-substituted carbamoyl or s-triazinyl substituted once by Cl or R 1 5 or twice by R 1 5; R 1 7Cl, 1-8C alkyl- or T 1-substituted amino, -N(1-8C alkyl)T 1, 2-16C N(alkyl) 2 or -N(X)-(CH 2) q-N(X)R 1 8, with X = 1-((OH) b-E-O) b)-2,2,6,6-tetra-(G 1) 2(G 2) 2-piperidin-4-yl; R 1 8 = as for R 1 6 but with the s-triazinyl only substituted twice by -N(1-8C alkyl)T 1 or 2-16C N(alkyl) 2; L : 1-8C alkylene, 5-8C cycloalk(en)ylene, 3-18C alkenylene or 1-4C alkylene substituted by phenyl itself optionally substituted once or |
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fullrecord | <record><control><sourceid>epo_EVB</sourceid><recordid>TN_cdi_epo_espacenet_BR0000666B1</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>BR0000666B1</sourcerecordid><originalsourceid>FETCH-epo_espacenet_BR0000666B13</originalsourceid><addsrcrecordid>eNqNjEFKBEEMRXvjQtQ75AA9oAh9gBHFtbgf0lWxDVRViqQKxNuICzez8wh1E09i9Yzi1hDIz_-fdzp8YeSEBhwzefZdZVFYtGYxSBsMrn2-8AhWZytcatv_dp7Z6zHLKo7MBDIq9iZ2h1bdPtq7jFB7ROAkdiYfvMOjRMn3FejESBbRRpgprqH8QT0BWcGZA78eiauVJbR9JBUQXdpbYtdVhYiFlDGsFaWFraicDydPGIwufu7ZAHe3jzf3G8qyI8voKFHZbR8u-0zTtL26_kflG5NLdQc</addsrcrecordid><sourcetype>Open Access Repository</sourcetype><iscdi>true</iscdi><recordtype>patent</recordtype></control><display><type>patent</type><title>aminas impedidas por grupos n-alcóxi, substituìdas por hidróxi, processo para sua preparação, uso e composição compreendendo as mesmas, bem como processo de estabilização de polìmero orgánico ou material de registro</title><source>esp@cenet</source><creator>ROBERT EDWARD DETLEFSEN ; HENRY CLANTON GRACE ; GERALD ANTHONY CAPOCCI ; MICHAEL PETER DIFAZIO ; NANCY NASE CLIFF ; PETER SHELSEY SOLERA ; RAMANATHAN RAVICHANDRAN ; JAMES PETER GALBO ; CHRISTOPHER KUELL</creator><creatorcontrib>ROBERT EDWARD DETLEFSEN ; HENRY CLANTON GRACE ; GERALD ANTHONY CAPOCCI ; MICHAEL PETER DIFAZIO ; NANCY NASE CLIFF ; PETER SHELSEY SOLERA ; RAMANATHAN RAVICHANDRAN ; JAMES PETER GALBO ; CHRISTOPHER KUELL</creatorcontrib><description>1-Alkoxy-substituted hindered 2,2,6,6-tetramethylpiperidine group-containing amines whose alkoxy units are substituted by 1-3 OH groups (or derivatives of such amines) are new. 1-Alkoxy-substituted hindered 2,2,6,6-tetramethylpiperidine group-containing amines whose alkoxy units are substituted by 1-3 OH groups (or derivatives of such amines) are new. The amines include (i) those simply substituted with OH-substituted alkoxy groups; (ii) those with the OH-substituted alkoxy forming a bridge between 2 amine groups; or (iii) monomeric, oligomeric or polymeric products formed by reaction with dialkyl esters or isocyanates. 30 substituted hindered amines are claimed e.g. those of formula (I)-(X). [Image] [Image] [Image] [Image] [Image] [Image] [Image] [Image] [Image] G 1 and G 21-4C alkyl or together form pentamethylene; E : 1-18C alkylene, 5-18C cycloalkylene or cycloalkenylene or 1-4C alkylene substituted by phenyl which is itself optionally substituted by one or two 1-4C alkyl; b : 1, 2 or 3, but does not exceed the number of C atoms in E or L and when it is 2 or 3, each OH group is bonded to a different C atom in E and L and the 2 hindered amine groups are not bonded to 2 different C atoms in L; m : 0 or 1; R 1H, OH or CH 2OH; R 2H, 1-12C alkyl or 2-12C alkenyl; R 7 and R 8Cl, 1-8C alkoxy, -OT 1, 2-hydroxyethyl-substituted amino, 1-18C NH(alkyl), -N(1-18C alkyl)T 1 or 2-36C N(alkyl) 2; R 9-O- or = -N- substituted by H, 1-12C alkyl or T 1; T 11-((OH) b-E-O)-2,2,6,6-(G 1) 2(G 2) 2-piperidin-4-yl; R 1 0H or Me; q : 2-8; R 1 3H, phenyl, 1-12C alkyl or alkoxy, phenyl-substituted 1-4C alkyl, 5-8C cycloalk(en)yl, 2-12C alkenyl, glycidyl, allyloxy, 1-4C hydroxyalkyl or silyl or silyloxy substituted 3 times by H, phenyl or 1-4C alkyl or alkoxy; d : 0 or 1; k : 0-5; x : 3-6; y : 1-10; R 1 5morpholino, piperidino, 1-piperazinyl, 1-8C alkylamino (especially octylamino), -N(1-8C alkyl)T 1 substituted by T 1, or 2-16C N(alkyl) 2; R 1 6H, 2-4C acyl, 1-4C alkyl-substituted carbamoyl or s-triazinyl substituted once by Cl or R 1 5 or twice by R 1 5; R 1 7Cl, 1-8C alkyl- or T 1-substituted amino, -N(1-8C alkyl)T 1, 2-16C N(alkyl) 2 or -N(X)-(CH 2) q-N(X)R 1 8, with X = 1-((OH) b-E-O) b)-2,2,6,6-tetra-(G 1) 2(G 2) 2-piperidin-4-yl; R 1 8 = as for R 1 6 but with the s-triazinyl only substituted twice by -N(1-8C alkyl)T 1 or 2-16C N(alkyl) 2; L : 1-8C alkylene, 5-8C cycloalk(en)ylene, 3-18C alkenylene or 1-4C alkylene substituted by phenyl itself optionally substituted once or twice by 1-4C alkyl; R 2 02-18C alkylene or divalent acyl derived from (i) optionally unsaturated 2-18C aliphatic or 7-12C cycloaliphatic dicarboxylic or dicarbamic acid or (ii) 8-15C aromatic diacid; G : as for L; and R 2 91-18C alkyl or -NH-alkyl or 5-8C -NH-cycloalkyl In formula (I) when b = 1, then E is not Me, Et, 2-propyl or 2-methylpropyl. An independent claim is also included for preparation of certain of the amines.</description><language>por</language><subject>ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAININGELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN,SULFUR, SELENIUM OR TELLURIUM ; ADHESIVES ; APPARATUS THEREFOR ; AUXILIARY PROCESSES IN PHOTOGRAPHY ; CHEMICAL PAINT OR INK REMOVERS ; CHEMISTRY ; CINEMATOGRAPHY ; COATING COMPOSITIONS, e.g. PAINTS, VARNISHES ORLACQUERS ; COMPOSITIONS BASED THEREON ; COMPOSITIONS OF MACROMOLECULAR COMPOUNDS ; CORRECTING FLUIDS ; DYES ; ELECTROGRAPHY ; FILLING PASTES ; GENERAL METHODS OF ORGANIC CHEMISTRY ; HETEROCYCLIC COMPOUNDS ; HOLOGRAPHY ; INKS ; MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FORELSEWHERE ; METALLURGY ; MISCELLANEOUS APPLICATIONS OF MATERIALS ; MISCELLANEOUS COMPOSITIONS ; NATURAL RESINS ; ORGANIC CHEMISTRY ; ORGANIC MACROMOLECULAR COMPOUNDS ; PAINTS ; PASTES OR SOLIDS FOR COLOURING OR PRINTING ; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR,STEREO-PHOTOGRAPHIC PROCESSES ; PHOTOGRAPHY ; PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES ; PHYSICS ; POLISHES ; THEIR PREPARATION OR CHEMICAL WORKING-UP ; USE OF INORGANIC OR NON-MACROMOLECULAR ORGANIC SUBSTANCES ASCOMPOUNDING INGREDIENTS ; USE OF MATERIALS THEREFOR ; WOODSTAINS</subject><creationdate>2011</creationdate><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://worldwide.espacenet.com/publicationDetails/biblio?FT=D&date=20110309&DB=EPODOC&CC=BR&NR=0000666B1$$EHTML$$P50$$Gepo$$Hfree_for_read</linktohtml><link.rule.ids>230,308,776,881,25542,76289</link.rule.ids><linktorsrc>$$Uhttps://worldwide.espacenet.com/publicationDetails/biblio?FT=D&date=20110309&DB=EPODOC&CC=BR&NR=0000666B1$$EView_record_in_European_Patent_Office$$FView_record_in_$$GEuropean_Patent_Office$$Hfree_for_read</linktorsrc></links><search><creatorcontrib>ROBERT EDWARD DETLEFSEN</creatorcontrib><creatorcontrib>HENRY CLANTON GRACE</creatorcontrib><creatorcontrib>GERALD ANTHONY CAPOCCI</creatorcontrib><creatorcontrib>MICHAEL PETER DIFAZIO</creatorcontrib><creatorcontrib>NANCY NASE CLIFF</creatorcontrib><creatorcontrib>PETER SHELSEY SOLERA</creatorcontrib><creatorcontrib>RAMANATHAN RAVICHANDRAN</creatorcontrib><creatorcontrib>JAMES PETER GALBO</creatorcontrib><creatorcontrib>CHRISTOPHER KUELL</creatorcontrib><title>aminas impedidas por grupos n-alcóxi, substituìdas por hidróxi, processo para sua preparação, uso e composição compreendendo as mesmas, bem como processo de estabilização de polìmero orgánico ou material de registro</title><description>1-Alkoxy-substituted hindered 2,2,6,6-tetramethylpiperidine group-containing amines whose alkoxy units are substituted by 1-3 OH groups (or derivatives of such amines) are new. 1-Alkoxy-substituted hindered 2,2,6,6-tetramethylpiperidine group-containing amines whose alkoxy units are substituted by 1-3 OH groups (or derivatives of such amines) are new. The amines include (i) those simply substituted with OH-substituted alkoxy groups; (ii) those with the OH-substituted alkoxy forming a bridge between 2 amine groups; or (iii) monomeric, oligomeric or polymeric products formed by reaction with dialkyl esters or isocyanates. 30 substituted hindered amines are claimed e.g. those of formula (I)-(X). [Image] [Image] [Image] [Image] [Image] [Image] [Image] [Image] [Image] G 1 and G 21-4C alkyl or together form pentamethylene; E : 1-18C alkylene, 5-18C cycloalkylene or cycloalkenylene or 1-4C alkylene substituted by phenyl which is itself optionally substituted by one or two 1-4C alkyl; b : 1, 2 or 3, but does not exceed the number of C atoms in E or L and when it is 2 or 3, each OH group is bonded to a different C atom in E and L and the 2 hindered amine groups are not bonded to 2 different C atoms in L; m : 0 or 1; R 1H, OH or CH 2OH; R 2H, 1-12C alkyl or 2-12C alkenyl; R 7 and R 8Cl, 1-8C alkoxy, -OT 1, 2-hydroxyethyl-substituted amino, 1-18C NH(alkyl), -N(1-18C alkyl)T 1 or 2-36C N(alkyl) 2; R 9-O- or = -N- substituted by H, 1-12C alkyl or T 1; T 11-((OH) b-E-O)-2,2,6,6-(G 1) 2(G 2) 2-piperidin-4-yl; R 1 0H or Me; q : 2-8; R 1 3H, phenyl, 1-12C alkyl or alkoxy, phenyl-substituted 1-4C alkyl, 5-8C cycloalk(en)yl, 2-12C alkenyl, glycidyl, allyloxy, 1-4C hydroxyalkyl or silyl or silyloxy substituted 3 times by H, phenyl or 1-4C alkyl or alkoxy; d : 0 or 1; k : 0-5; x : 3-6; y : 1-10; R 1 5morpholino, piperidino, 1-piperazinyl, 1-8C alkylamino (especially octylamino), -N(1-8C alkyl)T 1 substituted by T 1, or 2-16C N(alkyl) 2; R 1 6H, 2-4C acyl, 1-4C alkyl-substituted carbamoyl or s-triazinyl substituted once by Cl or R 1 5 or twice by R 1 5; R 1 7Cl, 1-8C alkyl- or T 1-substituted amino, -N(1-8C alkyl)T 1, 2-16C N(alkyl) 2 or -N(X)-(CH 2) q-N(X)R 1 8, with X = 1-((OH) b-E-O) b)-2,2,6,6-tetra-(G 1) 2(G 2) 2-piperidin-4-yl; R 1 8 = as for R 1 6 but with the s-triazinyl only substituted twice by -N(1-8C alkyl)T 1 or 2-16C N(alkyl) 2; L : 1-8C alkylene, 5-8C cycloalk(en)ylene, 3-18C alkenylene or 1-4C alkylene substituted by phenyl itself optionally substituted once or twice by 1-4C alkyl; R 2 02-18C alkylene or divalent acyl derived from (i) optionally unsaturated 2-18C aliphatic or 7-12C cycloaliphatic dicarboxylic or dicarbamic acid or (ii) 8-15C aromatic diacid; G : as for L; and R 2 91-18C alkyl or -NH-alkyl or 5-8C -NH-cycloalkyl In formula (I) when b = 1, then E is not Me, Et, 2-propyl or 2-methylpropyl. An independent claim is also included for preparation of certain of the amines.</description><subject>ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAININGELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN,SULFUR, SELENIUM OR TELLURIUM</subject><subject>ADHESIVES</subject><subject>APPARATUS THEREFOR</subject><subject>AUXILIARY PROCESSES IN PHOTOGRAPHY</subject><subject>CHEMICAL PAINT OR INK REMOVERS</subject><subject>CHEMISTRY</subject><subject>CINEMATOGRAPHY</subject><subject>COATING COMPOSITIONS, e.g. PAINTS, VARNISHES ORLACQUERS</subject><subject>COMPOSITIONS BASED THEREON</subject><subject>COMPOSITIONS OF MACROMOLECULAR COMPOUNDS</subject><subject>CORRECTING FLUIDS</subject><subject>DYES</subject><subject>ELECTROGRAPHY</subject><subject>FILLING PASTES</subject><subject>GENERAL METHODS OF ORGANIC CHEMISTRY</subject><subject>HETEROCYCLIC COMPOUNDS</subject><subject>HOLOGRAPHY</subject><subject>INKS</subject><subject>MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FORELSEWHERE</subject><subject>METALLURGY</subject><subject>MISCELLANEOUS APPLICATIONS OF MATERIALS</subject><subject>MISCELLANEOUS COMPOSITIONS</subject><subject>NATURAL RESINS</subject><subject>ORGANIC CHEMISTRY</subject><subject>ORGANIC MACROMOLECULAR COMPOUNDS</subject><subject>PAINTS</subject><subject>PASTES OR SOLIDS FOR COLOURING OR PRINTING</subject><subject>PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR,STEREO-PHOTOGRAPHIC PROCESSES</subject><subject>PHOTOGRAPHY</subject><subject>PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES</subject><subject>PHYSICS</subject><subject>POLISHES</subject><subject>THEIR PREPARATION OR CHEMICAL WORKING-UP</subject><subject>USE OF INORGANIC OR NON-MACROMOLECULAR ORGANIC SUBSTANCES ASCOMPOUNDING INGREDIENTS</subject><subject>USE OF MATERIALS THEREFOR</subject><subject>WOODSTAINS</subject><fulltext>true</fulltext><rsrctype>patent</rsrctype><creationdate>2011</creationdate><recordtype>patent</recordtype><sourceid>EVB</sourceid><recordid>eNqNjEFKBEEMRXvjQtQ75AA9oAh9gBHFtbgf0lWxDVRViqQKxNuICzez8wh1E09i9Yzi1hDIz_-fdzp8YeSEBhwzefZdZVFYtGYxSBsMrn2-8AhWZytcatv_dp7Z6zHLKo7MBDIq9iZ2h1bdPtq7jFB7ROAkdiYfvMOjRMn3FejESBbRRpgprqH8QT0BWcGZA78eiauVJbR9JBUQXdpbYtdVhYiFlDGsFaWFraicDydPGIwufu7ZAHe3jzf3G8qyI8voKFHZbR8u-0zTtL26_kflG5NLdQc</recordid><startdate>20110309</startdate><enddate>20110309</enddate><creator>ROBERT EDWARD DETLEFSEN</creator><creator>HENRY CLANTON GRACE</creator><creator>GERALD ANTHONY CAPOCCI</creator><creator>MICHAEL PETER DIFAZIO</creator><creator>NANCY NASE CLIFF</creator><creator>PETER SHELSEY SOLERA</creator><creator>RAMANATHAN RAVICHANDRAN</creator><creator>JAMES PETER GALBO</creator><creator>CHRISTOPHER KUELL</creator><scope>EVB</scope></search><sort><creationdate>20110309</creationdate><title>aminas impedidas por grupos n-alcóxi, substituìdas por hidróxi, processo para sua preparação, uso e composição compreendendo as mesmas, bem como processo de estabilização de polìmero orgánico ou material de registro</title><author>ROBERT EDWARD DETLEFSEN ; HENRY CLANTON GRACE ; GERALD ANTHONY CAPOCCI ; MICHAEL PETER DIFAZIO ; NANCY NASE CLIFF ; PETER SHELSEY SOLERA ; RAMANATHAN RAVICHANDRAN ; JAMES PETER GALBO ; CHRISTOPHER KUELL</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-epo_espacenet_BR0000666B13</frbrgroupid><rsrctype>patents</rsrctype><prefilter>patents</prefilter><language>por</language><creationdate>2011</creationdate><topic>ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAININGELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN,SULFUR, SELENIUM OR TELLURIUM</topic><topic>ADHESIVES</topic><topic>APPARATUS THEREFOR</topic><topic>AUXILIARY PROCESSES IN PHOTOGRAPHY</topic><topic>CHEMICAL PAINT OR INK REMOVERS</topic><topic>CHEMISTRY</topic><topic>CINEMATOGRAPHY</topic><topic>COATING COMPOSITIONS, e.g. PAINTS, VARNISHES ORLACQUERS</topic><topic>COMPOSITIONS BASED THEREON</topic><topic>COMPOSITIONS OF MACROMOLECULAR COMPOUNDS</topic><topic>CORRECTING FLUIDS</topic><topic>DYES</topic><topic>ELECTROGRAPHY</topic><topic>FILLING PASTES</topic><topic>GENERAL METHODS OF ORGANIC CHEMISTRY</topic><topic>HETEROCYCLIC COMPOUNDS</topic><topic>HOLOGRAPHY</topic><topic>INKS</topic><topic>MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FORELSEWHERE</topic><topic>METALLURGY</topic><topic>MISCELLANEOUS APPLICATIONS OF MATERIALS</topic><topic>MISCELLANEOUS COMPOSITIONS</topic><topic>NATURAL RESINS</topic><topic>ORGANIC CHEMISTRY</topic><topic>ORGANIC MACROMOLECULAR COMPOUNDS</topic><topic>PAINTS</topic><topic>PASTES OR SOLIDS FOR COLOURING OR PRINTING</topic><topic>PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR,STEREO-PHOTOGRAPHIC PROCESSES</topic><topic>PHOTOGRAPHY</topic><topic>PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES</topic><topic>PHYSICS</topic><topic>POLISHES</topic><topic>THEIR PREPARATION OR CHEMICAL WORKING-UP</topic><topic>USE OF INORGANIC OR NON-MACROMOLECULAR ORGANIC SUBSTANCES ASCOMPOUNDING INGREDIENTS</topic><topic>USE OF MATERIALS THEREFOR</topic><topic>WOODSTAINS</topic><toplevel>online_resources</toplevel><creatorcontrib>ROBERT EDWARD DETLEFSEN</creatorcontrib><creatorcontrib>HENRY CLANTON GRACE</creatorcontrib><creatorcontrib>GERALD ANTHONY CAPOCCI</creatorcontrib><creatorcontrib>MICHAEL PETER DIFAZIO</creatorcontrib><creatorcontrib>NANCY NASE CLIFF</creatorcontrib><creatorcontrib>PETER SHELSEY SOLERA</creatorcontrib><creatorcontrib>RAMANATHAN RAVICHANDRAN</creatorcontrib><creatorcontrib>JAMES PETER GALBO</creatorcontrib><creatorcontrib>CHRISTOPHER KUELL</creatorcontrib><collection>esp@cenet</collection></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext_linktorsrc</fulltext></delivery><addata><au>ROBERT EDWARD DETLEFSEN</au><au>HENRY CLANTON GRACE</au><au>GERALD ANTHONY CAPOCCI</au><au>MICHAEL PETER DIFAZIO</au><au>NANCY NASE CLIFF</au><au>PETER SHELSEY SOLERA</au><au>RAMANATHAN RAVICHANDRAN</au><au>JAMES PETER GALBO</au><au>CHRISTOPHER KUELL</au><format>patent</format><genre>patent</genre><ristype>GEN</ristype><title>aminas impedidas por grupos n-alcóxi, substituìdas por hidróxi, processo para sua preparação, uso e composição compreendendo as mesmas, bem como processo de estabilização de polìmero orgánico ou material de registro</title><date>2011-03-09</date><risdate>2011</risdate><abstract>1-Alkoxy-substituted hindered 2,2,6,6-tetramethylpiperidine group-containing amines whose alkoxy units are substituted by 1-3 OH groups (or derivatives of such amines) are new. 1-Alkoxy-substituted hindered 2,2,6,6-tetramethylpiperidine group-containing amines whose alkoxy units are substituted by 1-3 OH groups (or derivatives of such amines) are new. The amines include (i) those simply substituted with OH-substituted alkoxy groups; (ii) those with the OH-substituted alkoxy forming a bridge between 2 amine groups; or (iii) monomeric, oligomeric or polymeric products formed by reaction with dialkyl esters or isocyanates. 30 substituted hindered amines are claimed e.g. those of formula (I)-(X). [Image] [Image] [Image] [Image] [Image] [Image] [Image] [Image] [Image] G 1 and G 21-4C alkyl or together form pentamethylene; E : 1-18C alkylene, 5-18C cycloalkylene or cycloalkenylene or 1-4C alkylene substituted by phenyl which is itself optionally substituted by one or two 1-4C alkyl; b : 1, 2 or 3, but does not exceed the number of C atoms in E or L and when it is 2 or 3, each OH group is bonded to a different C atom in E and L and the 2 hindered amine groups are not bonded to 2 different C atoms in L; m : 0 or 1; R 1H, OH or CH 2OH; R 2H, 1-12C alkyl or 2-12C alkenyl; R 7 and R 8Cl, 1-8C alkoxy, -OT 1, 2-hydroxyethyl-substituted amino, 1-18C NH(alkyl), -N(1-18C alkyl)T 1 or 2-36C N(alkyl) 2; R 9-O- or = -N- substituted by H, 1-12C alkyl or T 1; T 11-((OH) b-E-O)-2,2,6,6-(G 1) 2(G 2) 2-piperidin-4-yl; R 1 0H or Me; q : 2-8; R 1 3H, phenyl, 1-12C alkyl or alkoxy, phenyl-substituted 1-4C alkyl, 5-8C cycloalk(en)yl, 2-12C alkenyl, glycidyl, allyloxy, 1-4C hydroxyalkyl or silyl or silyloxy substituted 3 times by H, phenyl or 1-4C alkyl or alkoxy; d : 0 or 1; k : 0-5; x : 3-6; y : 1-10; R 1 5morpholino, piperidino, 1-piperazinyl, 1-8C alkylamino (especially octylamino), -N(1-8C alkyl)T 1 substituted by T 1, or 2-16C N(alkyl) 2; R 1 6H, 2-4C acyl, 1-4C alkyl-substituted carbamoyl or s-triazinyl substituted once by Cl or R 1 5 or twice by R 1 5; R 1 7Cl, 1-8C alkyl- or T 1-substituted amino, -N(1-8C alkyl)T 1, 2-16C N(alkyl) 2 or -N(X)-(CH 2) q-N(X)R 1 8, with X = 1-((OH) b-E-O) b)-2,2,6,6-tetra-(G 1) 2(G 2) 2-piperidin-4-yl; R 1 8 = as for R 1 6 but with the s-triazinyl only substituted twice by -N(1-8C alkyl)T 1 or 2-16C N(alkyl) 2; L : 1-8C alkylene, 5-8C cycloalk(en)ylene, 3-18C alkenylene or 1-4C alkylene substituted by phenyl itself optionally substituted once or twice by 1-4C alkyl; R 2 02-18C alkylene or divalent acyl derived from (i) optionally unsaturated 2-18C aliphatic or 7-12C cycloaliphatic dicarboxylic or dicarbamic acid or (ii) 8-15C aromatic diacid; G : as for L; and R 2 91-18C alkyl or -NH-alkyl or 5-8C -NH-cycloalkyl In formula (I) when b = 1, then E is not Me, Et, 2-propyl or 2-methylpropyl. An independent claim is also included for preparation of certain of the amines.</abstract><oa>free_for_read</oa></addata></record> |
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subjects | ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAININGELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN,SULFUR, SELENIUM OR TELLURIUM ADHESIVES APPARATUS THEREFOR AUXILIARY PROCESSES IN PHOTOGRAPHY CHEMICAL PAINT OR INK REMOVERS CHEMISTRY CINEMATOGRAPHY COATING COMPOSITIONS, e.g. PAINTS, VARNISHES ORLACQUERS COMPOSITIONS BASED THEREON COMPOSITIONS OF MACROMOLECULAR COMPOUNDS CORRECTING FLUIDS DYES ELECTROGRAPHY FILLING PASTES GENERAL METHODS OF ORGANIC CHEMISTRY HETEROCYCLIC COMPOUNDS HOLOGRAPHY INKS MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FORELSEWHERE METALLURGY MISCELLANEOUS APPLICATIONS OF MATERIALS MISCELLANEOUS COMPOSITIONS NATURAL RESINS ORGANIC CHEMISTRY ORGANIC MACROMOLECULAR COMPOUNDS PAINTS PASTES OR SOLIDS FOR COLOURING OR PRINTING PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR,STEREO-PHOTOGRAPHIC PROCESSES PHOTOGRAPHY PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES PHYSICS POLISHES THEIR PREPARATION OR CHEMICAL WORKING-UP USE OF INORGANIC OR NON-MACROMOLECULAR ORGANIC SUBSTANCES ASCOMPOUNDING INGREDIENTS USE OF MATERIALS THEREFOR WOODSTAINS |
title | aminas impedidas por grupos n-alcóxi, substituìdas por hidróxi, processo para sua preparação, uso e composição compreendendo as mesmas, bem como processo de estabilização de polìmero orgánico ou material de registro |
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