aminas impedidas por grupos n-alcóxi, substituìdas por hidróxi, processo para sua preparação, uso e composição compreendendo as mesmas, bem como processo de estabilização de polìmero orgánico ou material de registro

1-Alkoxy-substituted hindered 2,2,6,6-tetramethylpiperidine group-containing amines whose alkoxy units are substituted by 1-3 OH groups (or derivatives of such amines) are new. 1-Alkoxy-substituted hindered 2,2,6,6-tetramethylpiperidine group-containing amines whose alkoxy units are substituted by 1...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Hauptverfasser: ROBERT EDWARD DETLEFSEN, HENRY CLANTON GRACE, GERALD ANTHONY CAPOCCI, MICHAEL PETER DIFAZIO, NANCY NASE CLIFF, PETER SHELSEY SOLERA, RAMANATHAN RAVICHANDRAN, JAMES PETER GALBO, CHRISTOPHER KUELL
Format: Patent
Sprache:por
Schlagworte:
Online-Zugang:Volltext bestellen
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
container_end_page
container_issue
container_start_page
container_title
container_volume
creator ROBERT EDWARD DETLEFSEN
HENRY CLANTON GRACE
GERALD ANTHONY CAPOCCI
MICHAEL PETER DIFAZIO
NANCY NASE CLIFF
PETER SHELSEY SOLERA
RAMANATHAN RAVICHANDRAN
JAMES PETER GALBO
CHRISTOPHER KUELL
description 1-Alkoxy-substituted hindered 2,2,6,6-tetramethylpiperidine group-containing amines whose alkoxy units are substituted by 1-3 OH groups (or derivatives of such amines) are new. 1-Alkoxy-substituted hindered 2,2,6,6-tetramethylpiperidine group-containing amines whose alkoxy units are substituted by 1-3 OH groups (or derivatives of such amines) are new. The amines include (i) those simply substituted with OH-substituted alkoxy groups; (ii) those with the OH-substituted alkoxy forming a bridge between 2 amine groups; or (iii) monomeric, oligomeric or polymeric products formed by reaction with dialkyl esters or isocyanates. 30 substituted hindered amines are claimed e.g. those of formula (I)-(X). [Image] [Image] [Image] [Image] [Image] [Image] [Image] [Image] [Image] G 1 and G 21-4C alkyl or together form pentamethylene; E : 1-18C alkylene, 5-18C cycloalkylene or cycloalkenylene or 1-4C alkylene substituted by phenyl which is itself optionally substituted by one or two 1-4C alkyl; b : 1, 2 or 3, but does not exceed the number of C atoms in E or L and when it is 2 or 3, each OH group is bonded to a different C atom in E and L and the 2 hindered amine groups are not bonded to 2 different C atoms in L; m : 0 or 1; R 1H, OH or CH 2OH; R 2H, 1-12C alkyl or 2-12C alkenyl; R 7 and R 8Cl, 1-8C alkoxy, -OT 1, 2-hydroxyethyl-substituted amino, 1-18C NH(alkyl), -N(1-18C alkyl)T 1 or 2-36C N(alkyl) 2; R 9-O- or = -N- substituted by H, 1-12C alkyl or T 1; T 11-((OH) b-E-O)-2,2,6,6-(G 1) 2(G 2) 2-piperidin-4-yl; R 1 0H or Me; q : 2-8; R 1 3H, phenyl, 1-12C alkyl or alkoxy, phenyl-substituted 1-4C alkyl, 5-8C cycloalk(en)yl, 2-12C alkenyl, glycidyl, allyloxy, 1-4C hydroxyalkyl or silyl or silyloxy substituted 3 times by H, phenyl or 1-4C alkyl or alkoxy; d : 0 or 1; k : 0-5; x : 3-6; y : 1-10; R 1 5morpholino, piperidino, 1-piperazinyl, 1-8C alkylamino (especially octylamino), -N(1-8C alkyl)T 1 substituted by T 1, or 2-16C N(alkyl) 2; R 1 6H, 2-4C acyl, 1-4C alkyl-substituted carbamoyl or s-triazinyl substituted once by Cl or R 1 5 or twice by R 1 5; R 1 7Cl, 1-8C alkyl- or T 1-substituted amino, -N(1-8C alkyl)T 1, 2-16C N(alkyl) 2 or -N(X)-(CH 2) q-N(X)R 1 8, with X = 1-((OH) b-E-O) b)-2,2,6,6-tetra-(G 1) 2(G 2) 2-piperidin-4-yl; R 1 8 = as for R 1 6 but with the s-triazinyl only substituted twice by -N(1-8C alkyl)T 1 or 2-16C N(alkyl) 2; L : 1-8C alkylene, 5-8C cycloalk(en)ylene, 3-18C alkenylene or 1-4C alkylene substituted by phenyl itself optionally substituted once or
format Patent
fullrecord <record><control><sourceid>epo_EVB</sourceid><recordid>TN_cdi_epo_espacenet_BR0000666B1</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>BR0000666B1</sourcerecordid><originalsourceid>FETCH-epo_espacenet_BR0000666B13</originalsourceid><addsrcrecordid>eNqNjEFKBEEMRXvjQtQ75AA9oAh9gBHFtbgf0lWxDVRViqQKxNuICzez8wh1E09i9Yzi1hDIz_-fdzp8YeSEBhwzefZdZVFYtGYxSBsMrn2-8AhWZytcatv_dp7Z6zHLKo7MBDIq9iZ2h1bdPtq7jFB7ROAkdiYfvMOjRMn3FejESBbRRpgprqH8QT0BWcGZA78eiauVJbR9JBUQXdpbYtdVhYiFlDGsFaWFraicDydPGIwufu7ZAHe3jzf3G8qyI8voKFHZbR8u-0zTtL26_kflG5NLdQc</addsrcrecordid><sourcetype>Open Access Repository</sourcetype><iscdi>true</iscdi><recordtype>patent</recordtype></control><display><type>patent</type><title>aminas impedidas por grupos n-alcóxi, substituìdas por hidróxi, processo para sua preparação, uso e composição compreendendo as mesmas, bem como processo de estabilização de polìmero orgánico ou material de registro</title><source>esp@cenet</source><creator>ROBERT EDWARD DETLEFSEN ; HENRY CLANTON GRACE ; GERALD ANTHONY CAPOCCI ; MICHAEL PETER DIFAZIO ; NANCY NASE CLIFF ; PETER SHELSEY SOLERA ; RAMANATHAN RAVICHANDRAN ; JAMES PETER GALBO ; CHRISTOPHER KUELL</creator><creatorcontrib>ROBERT EDWARD DETLEFSEN ; HENRY CLANTON GRACE ; GERALD ANTHONY CAPOCCI ; MICHAEL PETER DIFAZIO ; NANCY NASE CLIFF ; PETER SHELSEY SOLERA ; RAMANATHAN RAVICHANDRAN ; JAMES PETER GALBO ; CHRISTOPHER KUELL</creatorcontrib><description>1-Alkoxy-substituted hindered 2,2,6,6-tetramethylpiperidine group-containing amines whose alkoxy units are substituted by 1-3 OH groups (or derivatives of such amines) are new. 1-Alkoxy-substituted hindered 2,2,6,6-tetramethylpiperidine group-containing amines whose alkoxy units are substituted by 1-3 OH groups (or derivatives of such amines) are new. The amines include (i) those simply substituted with OH-substituted alkoxy groups; (ii) those with the OH-substituted alkoxy forming a bridge between 2 amine groups; or (iii) monomeric, oligomeric or polymeric products formed by reaction with dialkyl esters or isocyanates. 30 substituted hindered amines are claimed e.g. those of formula (I)-(X). [Image] [Image] [Image] [Image] [Image] [Image] [Image] [Image] [Image] G 1 and G 21-4C alkyl or together form pentamethylene; E : 1-18C alkylene, 5-18C cycloalkylene or cycloalkenylene or 1-4C alkylene substituted by phenyl which is itself optionally substituted by one or two 1-4C alkyl; b : 1, 2 or 3, but does not exceed the number of C atoms in E or L and when it is 2 or 3, each OH group is bonded to a different C atom in E and L and the 2 hindered amine groups are not bonded to 2 different C atoms in L; m : 0 or 1; R 1H, OH or CH 2OH; R 2H, 1-12C alkyl or 2-12C alkenyl; R 7 and R 8Cl, 1-8C alkoxy, -OT 1, 2-hydroxyethyl-substituted amino, 1-18C NH(alkyl), -N(1-18C alkyl)T 1 or 2-36C N(alkyl) 2; R 9-O- or = -N- substituted by H, 1-12C alkyl or T 1; T 11-((OH) b-E-O)-2,2,6,6-(G 1) 2(G 2) 2-piperidin-4-yl; R 1 0H or Me; q : 2-8; R 1 3H, phenyl, 1-12C alkyl or alkoxy, phenyl-substituted 1-4C alkyl, 5-8C cycloalk(en)yl, 2-12C alkenyl, glycidyl, allyloxy, 1-4C hydroxyalkyl or silyl or silyloxy substituted 3 times by H, phenyl or 1-4C alkyl or alkoxy; d : 0 or 1; k : 0-5; x : 3-6; y : 1-10; R 1 5morpholino, piperidino, 1-piperazinyl, 1-8C alkylamino (especially octylamino), -N(1-8C alkyl)T 1 substituted by T 1, or 2-16C N(alkyl) 2; R 1 6H, 2-4C acyl, 1-4C alkyl-substituted carbamoyl or s-triazinyl substituted once by Cl or R 1 5 or twice by R 1 5; R 1 7Cl, 1-8C alkyl- or T 1-substituted amino, -N(1-8C alkyl)T 1, 2-16C N(alkyl) 2 or -N(X)-(CH 2) q-N(X)R 1 8, with X = 1-((OH) b-E-O) b)-2,2,6,6-tetra-(G 1) 2(G 2) 2-piperidin-4-yl; R 1 8 = as for R 1 6 but with the s-triazinyl only substituted twice by -N(1-8C alkyl)T 1 or 2-16C N(alkyl) 2; L : 1-8C alkylene, 5-8C cycloalk(en)ylene, 3-18C alkenylene or 1-4C alkylene substituted by phenyl itself optionally substituted once or twice by 1-4C alkyl; R 2 02-18C alkylene or divalent acyl derived from (i) optionally unsaturated 2-18C aliphatic or 7-12C cycloaliphatic dicarboxylic or dicarbamic acid or (ii) 8-15C aromatic diacid; G : as for L; and R 2 91-18C alkyl or -NH-alkyl or 5-8C -NH-cycloalkyl In formula (I) when b = 1, then E is not Me, Et, 2-propyl or 2-methylpropyl. An independent claim is also included for preparation of certain of the amines.</description><language>por</language><subject>ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAININGELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN,SULFUR, SELENIUM OR TELLURIUM ; ADHESIVES ; APPARATUS THEREFOR ; AUXILIARY PROCESSES IN PHOTOGRAPHY ; CHEMICAL PAINT OR INK REMOVERS ; CHEMISTRY ; CINEMATOGRAPHY ; COATING COMPOSITIONS, e.g. PAINTS, VARNISHES ORLACQUERS ; COMPOSITIONS BASED THEREON ; COMPOSITIONS OF MACROMOLECULAR COMPOUNDS ; CORRECTING FLUIDS ; DYES ; ELECTROGRAPHY ; FILLING PASTES ; GENERAL METHODS OF ORGANIC CHEMISTRY ; HETEROCYCLIC COMPOUNDS ; HOLOGRAPHY ; INKS ; MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FORELSEWHERE ; METALLURGY ; MISCELLANEOUS APPLICATIONS OF MATERIALS ; MISCELLANEOUS COMPOSITIONS ; NATURAL RESINS ; ORGANIC CHEMISTRY ; ORGANIC MACROMOLECULAR COMPOUNDS ; PAINTS ; PASTES OR SOLIDS FOR COLOURING OR PRINTING ; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR,STEREO-PHOTOGRAPHIC PROCESSES ; PHOTOGRAPHY ; PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES ; PHYSICS ; POLISHES ; THEIR PREPARATION OR CHEMICAL WORKING-UP ; USE OF INORGANIC OR NON-MACROMOLECULAR ORGANIC SUBSTANCES ASCOMPOUNDING INGREDIENTS ; USE OF MATERIALS THEREFOR ; WOODSTAINS</subject><creationdate>2011</creationdate><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://worldwide.espacenet.com/publicationDetails/biblio?FT=D&amp;date=20110309&amp;DB=EPODOC&amp;CC=BR&amp;NR=0000666B1$$EHTML$$P50$$Gepo$$Hfree_for_read</linktohtml><link.rule.ids>230,308,776,881,25542,76289</link.rule.ids><linktorsrc>$$Uhttps://worldwide.espacenet.com/publicationDetails/biblio?FT=D&amp;date=20110309&amp;DB=EPODOC&amp;CC=BR&amp;NR=0000666B1$$EView_record_in_European_Patent_Office$$FView_record_in_$$GEuropean_Patent_Office$$Hfree_for_read</linktorsrc></links><search><creatorcontrib>ROBERT EDWARD DETLEFSEN</creatorcontrib><creatorcontrib>HENRY CLANTON GRACE</creatorcontrib><creatorcontrib>GERALD ANTHONY CAPOCCI</creatorcontrib><creatorcontrib>MICHAEL PETER DIFAZIO</creatorcontrib><creatorcontrib>NANCY NASE CLIFF</creatorcontrib><creatorcontrib>PETER SHELSEY SOLERA</creatorcontrib><creatorcontrib>RAMANATHAN RAVICHANDRAN</creatorcontrib><creatorcontrib>JAMES PETER GALBO</creatorcontrib><creatorcontrib>CHRISTOPHER KUELL</creatorcontrib><title>aminas impedidas por grupos n-alcóxi, substituìdas por hidróxi, processo para sua preparação, uso e composição compreendendo as mesmas, bem como processo de estabilização de polìmero orgánico ou material de registro</title><description>1-Alkoxy-substituted hindered 2,2,6,6-tetramethylpiperidine group-containing amines whose alkoxy units are substituted by 1-3 OH groups (or derivatives of such amines) are new. 1-Alkoxy-substituted hindered 2,2,6,6-tetramethylpiperidine group-containing amines whose alkoxy units are substituted by 1-3 OH groups (or derivatives of such amines) are new. The amines include (i) those simply substituted with OH-substituted alkoxy groups; (ii) those with the OH-substituted alkoxy forming a bridge between 2 amine groups; or (iii) monomeric, oligomeric or polymeric products formed by reaction with dialkyl esters or isocyanates. 30 substituted hindered amines are claimed e.g. those of formula (I)-(X). [Image] [Image] [Image] [Image] [Image] [Image] [Image] [Image] [Image] G 1 and G 21-4C alkyl or together form pentamethylene; E : 1-18C alkylene, 5-18C cycloalkylene or cycloalkenylene or 1-4C alkylene substituted by phenyl which is itself optionally substituted by one or two 1-4C alkyl; b : 1, 2 or 3, but does not exceed the number of C atoms in E or L and when it is 2 or 3, each OH group is bonded to a different C atom in E and L and the 2 hindered amine groups are not bonded to 2 different C atoms in L; m : 0 or 1; R 1H, OH or CH 2OH; R 2H, 1-12C alkyl or 2-12C alkenyl; R 7 and R 8Cl, 1-8C alkoxy, -OT 1, 2-hydroxyethyl-substituted amino, 1-18C NH(alkyl), -N(1-18C alkyl)T 1 or 2-36C N(alkyl) 2; R 9-O- or = -N- substituted by H, 1-12C alkyl or T 1; T 11-((OH) b-E-O)-2,2,6,6-(G 1) 2(G 2) 2-piperidin-4-yl; R 1 0H or Me; q : 2-8; R 1 3H, phenyl, 1-12C alkyl or alkoxy, phenyl-substituted 1-4C alkyl, 5-8C cycloalk(en)yl, 2-12C alkenyl, glycidyl, allyloxy, 1-4C hydroxyalkyl or silyl or silyloxy substituted 3 times by H, phenyl or 1-4C alkyl or alkoxy; d : 0 or 1; k : 0-5; x : 3-6; y : 1-10; R 1 5morpholino, piperidino, 1-piperazinyl, 1-8C alkylamino (especially octylamino), -N(1-8C alkyl)T 1 substituted by T 1, or 2-16C N(alkyl) 2; R 1 6H, 2-4C acyl, 1-4C alkyl-substituted carbamoyl or s-triazinyl substituted once by Cl or R 1 5 or twice by R 1 5; R 1 7Cl, 1-8C alkyl- or T 1-substituted amino, -N(1-8C alkyl)T 1, 2-16C N(alkyl) 2 or -N(X)-(CH 2) q-N(X)R 1 8, with X = 1-((OH) b-E-O) b)-2,2,6,6-tetra-(G 1) 2(G 2) 2-piperidin-4-yl; R 1 8 = as for R 1 6 but with the s-triazinyl only substituted twice by -N(1-8C alkyl)T 1 or 2-16C N(alkyl) 2; L : 1-8C alkylene, 5-8C cycloalk(en)ylene, 3-18C alkenylene or 1-4C alkylene substituted by phenyl itself optionally substituted once or twice by 1-4C alkyl; R 2 02-18C alkylene or divalent acyl derived from (i) optionally unsaturated 2-18C aliphatic or 7-12C cycloaliphatic dicarboxylic or dicarbamic acid or (ii) 8-15C aromatic diacid; G : as for L; and R 2 91-18C alkyl or -NH-alkyl or 5-8C -NH-cycloalkyl In formula (I) when b = 1, then E is not Me, Et, 2-propyl or 2-methylpropyl. An independent claim is also included for preparation of certain of the amines.</description><subject>ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAININGELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN,SULFUR, SELENIUM OR TELLURIUM</subject><subject>ADHESIVES</subject><subject>APPARATUS THEREFOR</subject><subject>AUXILIARY PROCESSES IN PHOTOGRAPHY</subject><subject>CHEMICAL PAINT OR INK REMOVERS</subject><subject>CHEMISTRY</subject><subject>CINEMATOGRAPHY</subject><subject>COATING COMPOSITIONS, e.g. PAINTS, VARNISHES ORLACQUERS</subject><subject>COMPOSITIONS BASED THEREON</subject><subject>COMPOSITIONS OF MACROMOLECULAR COMPOUNDS</subject><subject>CORRECTING FLUIDS</subject><subject>DYES</subject><subject>ELECTROGRAPHY</subject><subject>FILLING PASTES</subject><subject>GENERAL METHODS OF ORGANIC CHEMISTRY</subject><subject>HETEROCYCLIC COMPOUNDS</subject><subject>HOLOGRAPHY</subject><subject>INKS</subject><subject>MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FORELSEWHERE</subject><subject>METALLURGY</subject><subject>MISCELLANEOUS APPLICATIONS OF MATERIALS</subject><subject>MISCELLANEOUS COMPOSITIONS</subject><subject>NATURAL RESINS</subject><subject>ORGANIC CHEMISTRY</subject><subject>ORGANIC MACROMOLECULAR COMPOUNDS</subject><subject>PAINTS</subject><subject>PASTES OR SOLIDS FOR COLOURING OR PRINTING</subject><subject>PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR,STEREO-PHOTOGRAPHIC PROCESSES</subject><subject>PHOTOGRAPHY</subject><subject>PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES</subject><subject>PHYSICS</subject><subject>POLISHES</subject><subject>THEIR PREPARATION OR CHEMICAL WORKING-UP</subject><subject>USE OF INORGANIC OR NON-MACROMOLECULAR ORGANIC SUBSTANCES ASCOMPOUNDING INGREDIENTS</subject><subject>USE OF MATERIALS THEREFOR</subject><subject>WOODSTAINS</subject><fulltext>true</fulltext><rsrctype>patent</rsrctype><creationdate>2011</creationdate><recordtype>patent</recordtype><sourceid>EVB</sourceid><recordid>eNqNjEFKBEEMRXvjQtQ75AA9oAh9gBHFtbgf0lWxDVRViqQKxNuICzez8wh1E09i9Yzi1hDIz_-fdzp8YeSEBhwzefZdZVFYtGYxSBsMrn2-8AhWZytcatv_dp7Z6zHLKo7MBDIq9iZ2h1bdPtq7jFB7ROAkdiYfvMOjRMn3FejESBbRRpgprqH8QT0BWcGZA78eiauVJbR9JBUQXdpbYtdVhYiFlDGsFaWFraicDydPGIwufu7ZAHe3jzf3G8qyI8voKFHZbR8u-0zTtL26_kflG5NLdQc</recordid><startdate>20110309</startdate><enddate>20110309</enddate><creator>ROBERT EDWARD DETLEFSEN</creator><creator>HENRY CLANTON GRACE</creator><creator>GERALD ANTHONY CAPOCCI</creator><creator>MICHAEL PETER DIFAZIO</creator><creator>NANCY NASE CLIFF</creator><creator>PETER SHELSEY SOLERA</creator><creator>RAMANATHAN RAVICHANDRAN</creator><creator>JAMES PETER GALBO</creator><creator>CHRISTOPHER KUELL</creator><scope>EVB</scope></search><sort><creationdate>20110309</creationdate><title>aminas impedidas por grupos n-alcóxi, substituìdas por hidróxi, processo para sua preparação, uso e composição compreendendo as mesmas, bem como processo de estabilização de polìmero orgánico ou material de registro</title><author>ROBERT EDWARD DETLEFSEN ; HENRY CLANTON GRACE ; GERALD ANTHONY CAPOCCI ; MICHAEL PETER DIFAZIO ; NANCY NASE CLIFF ; PETER SHELSEY SOLERA ; RAMANATHAN RAVICHANDRAN ; JAMES PETER GALBO ; CHRISTOPHER KUELL</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-epo_espacenet_BR0000666B13</frbrgroupid><rsrctype>patents</rsrctype><prefilter>patents</prefilter><language>por</language><creationdate>2011</creationdate><topic>ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAININGELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN,SULFUR, SELENIUM OR TELLURIUM</topic><topic>ADHESIVES</topic><topic>APPARATUS THEREFOR</topic><topic>AUXILIARY PROCESSES IN PHOTOGRAPHY</topic><topic>CHEMICAL PAINT OR INK REMOVERS</topic><topic>CHEMISTRY</topic><topic>CINEMATOGRAPHY</topic><topic>COATING COMPOSITIONS, e.g. PAINTS, VARNISHES ORLACQUERS</topic><topic>COMPOSITIONS BASED THEREON</topic><topic>COMPOSITIONS OF MACROMOLECULAR COMPOUNDS</topic><topic>CORRECTING FLUIDS</topic><topic>DYES</topic><topic>ELECTROGRAPHY</topic><topic>FILLING PASTES</topic><topic>GENERAL METHODS OF ORGANIC CHEMISTRY</topic><topic>HETEROCYCLIC COMPOUNDS</topic><topic>HOLOGRAPHY</topic><topic>INKS</topic><topic>MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FORELSEWHERE</topic><topic>METALLURGY</topic><topic>MISCELLANEOUS APPLICATIONS OF MATERIALS</topic><topic>MISCELLANEOUS COMPOSITIONS</topic><topic>NATURAL RESINS</topic><topic>ORGANIC CHEMISTRY</topic><topic>ORGANIC MACROMOLECULAR COMPOUNDS</topic><topic>PAINTS</topic><topic>PASTES OR SOLIDS FOR COLOURING OR PRINTING</topic><topic>PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR,STEREO-PHOTOGRAPHIC PROCESSES</topic><topic>PHOTOGRAPHY</topic><topic>PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES</topic><topic>PHYSICS</topic><topic>POLISHES</topic><topic>THEIR PREPARATION OR CHEMICAL WORKING-UP</topic><topic>USE OF INORGANIC OR NON-MACROMOLECULAR ORGANIC SUBSTANCES ASCOMPOUNDING INGREDIENTS</topic><topic>USE OF MATERIALS THEREFOR</topic><topic>WOODSTAINS</topic><toplevel>online_resources</toplevel><creatorcontrib>ROBERT EDWARD DETLEFSEN</creatorcontrib><creatorcontrib>HENRY CLANTON GRACE</creatorcontrib><creatorcontrib>GERALD ANTHONY CAPOCCI</creatorcontrib><creatorcontrib>MICHAEL PETER DIFAZIO</creatorcontrib><creatorcontrib>NANCY NASE CLIFF</creatorcontrib><creatorcontrib>PETER SHELSEY SOLERA</creatorcontrib><creatorcontrib>RAMANATHAN RAVICHANDRAN</creatorcontrib><creatorcontrib>JAMES PETER GALBO</creatorcontrib><creatorcontrib>CHRISTOPHER KUELL</creatorcontrib><collection>esp@cenet</collection></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext_linktorsrc</fulltext></delivery><addata><au>ROBERT EDWARD DETLEFSEN</au><au>HENRY CLANTON GRACE</au><au>GERALD ANTHONY CAPOCCI</au><au>MICHAEL PETER DIFAZIO</au><au>NANCY NASE CLIFF</au><au>PETER SHELSEY SOLERA</au><au>RAMANATHAN RAVICHANDRAN</au><au>JAMES PETER GALBO</au><au>CHRISTOPHER KUELL</au><format>patent</format><genre>patent</genre><ristype>GEN</ristype><title>aminas impedidas por grupos n-alcóxi, substituìdas por hidróxi, processo para sua preparação, uso e composição compreendendo as mesmas, bem como processo de estabilização de polìmero orgánico ou material de registro</title><date>2011-03-09</date><risdate>2011</risdate><abstract>1-Alkoxy-substituted hindered 2,2,6,6-tetramethylpiperidine group-containing amines whose alkoxy units are substituted by 1-3 OH groups (or derivatives of such amines) are new. 1-Alkoxy-substituted hindered 2,2,6,6-tetramethylpiperidine group-containing amines whose alkoxy units are substituted by 1-3 OH groups (or derivatives of such amines) are new. The amines include (i) those simply substituted with OH-substituted alkoxy groups; (ii) those with the OH-substituted alkoxy forming a bridge between 2 amine groups; or (iii) monomeric, oligomeric or polymeric products formed by reaction with dialkyl esters or isocyanates. 30 substituted hindered amines are claimed e.g. those of formula (I)-(X). [Image] [Image] [Image] [Image] [Image] [Image] [Image] [Image] [Image] G 1 and G 21-4C alkyl or together form pentamethylene; E : 1-18C alkylene, 5-18C cycloalkylene or cycloalkenylene or 1-4C alkylene substituted by phenyl which is itself optionally substituted by one or two 1-4C alkyl; b : 1, 2 or 3, but does not exceed the number of C atoms in E or L and when it is 2 or 3, each OH group is bonded to a different C atom in E and L and the 2 hindered amine groups are not bonded to 2 different C atoms in L; m : 0 or 1; R 1H, OH or CH 2OH; R 2H, 1-12C alkyl or 2-12C alkenyl; R 7 and R 8Cl, 1-8C alkoxy, -OT 1, 2-hydroxyethyl-substituted amino, 1-18C NH(alkyl), -N(1-18C alkyl)T 1 or 2-36C N(alkyl) 2; R 9-O- or = -N- substituted by H, 1-12C alkyl or T 1; T 11-((OH) b-E-O)-2,2,6,6-(G 1) 2(G 2) 2-piperidin-4-yl; R 1 0H or Me; q : 2-8; R 1 3H, phenyl, 1-12C alkyl or alkoxy, phenyl-substituted 1-4C alkyl, 5-8C cycloalk(en)yl, 2-12C alkenyl, glycidyl, allyloxy, 1-4C hydroxyalkyl or silyl or silyloxy substituted 3 times by H, phenyl or 1-4C alkyl or alkoxy; d : 0 or 1; k : 0-5; x : 3-6; y : 1-10; R 1 5morpholino, piperidino, 1-piperazinyl, 1-8C alkylamino (especially octylamino), -N(1-8C alkyl)T 1 substituted by T 1, or 2-16C N(alkyl) 2; R 1 6H, 2-4C acyl, 1-4C alkyl-substituted carbamoyl or s-triazinyl substituted once by Cl or R 1 5 or twice by R 1 5; R 1 7Cl, 1-8C alkyl- or T 1-substituted amino, -N(1-8C alkyl)T 1, 2-16C N(alkyl) 2 or -N(X)-(CH 2) q-N(X)R 1 8, with X = 1-((OH) b-E-O) b)-2,2,6,6-tetra-(G 1) 2(G 2) 2-piperidin-4-yl; R 1 8 = as for R 1 6 but with the s-triazinyl only substituted twice by -N(1-8C alkyl)T 1 or 2-16C N(alkyl) 2; L : 1-8C alkylene, 5-8C cycloalk(en)ylene, 3-18C alkenylene or 1-4C alkylene substituted by phenyl itself optionally substituted once or twice by 1-4C alkyl; R 2 02-18C alkylene or divalent acyl derived from (i) optionally unsaturated 2-18C aliphatic or 7-12C cycloaliphatic dicarboxylic or dicarbamic acid or (ii) 8-15C aromatic diacid; G : as for L; and R 2 91-18C alkyl or -NH-alkyl or 5-8C -NH-cycloalkyl In formula (I) when b = 1, then E is not Me, Et, 2-propyl or 2-methylpropyl. An independent claim is also included for preparation of certain of the amines.</abstract><oa>free_for_read</oa></addata></record>
fulltext fulltext_linktorsrc
identifier
ispartof
issn
language por
recordid cdi_epo_espacenet_BR0000666B1
source esp@cenet
subjects ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAININGELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN,SULFUR, SELENIUM OR TELLURIUM
ADHESIVES
APPARATUS THEREFOR
AUXILIARY PROCESSES IN PHOTOGRAPHY
CHEMICAL PAINT OR INK REMOVERS
CHEMISTRY
CINEMATOGRAPHY
COATING COMPOSITIONS, e.g. PAINTS, VARNISHES ORLACQUERS
COMPOSITIONS BASED THEREON
COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
CORRECTING FLUIDS
DYES
ELECTROGRAPHY
FILLING PASTES
GENERAL METHODS OF ORGANIC CHEMISTRY
HETEROCYCLIC COMPOUNDS
HOLOGRAPHY
INKS
MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FORELSEWHERE
METALLURGY
MISCELLANEOUS APPLICATIONS OF MATERIALS
MISCELLANEOUS COMPOSITIONS
NATURAL RESINS
ORGANIC CHEMISTRY
ORGANIC MACROMOLECULAR COMPOUNDS
PAINTS
PASTES OR SOLIDS FOR COLOURING OR PRINTING
PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR,STEREO-PHOTOGRAPHIC PROCESSES
PHOTOGRAPHY
PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES
PHYSICS
POLISHES
THEIR PREPARATION OR CHEMICAL WORKING-UP
USE OF INORGANIC OR NON-MACROMOLECULAR ORGANIC SUBSTANCES ASCOMPOUNDING INGREDIENTS
USE OF MATERIALS THEREFOR
WOODSTAINS
title aminas impedidas por grupos n-alcóxi, substituìdas por hidróxi, processo para sua preparação, uso e composição compreendendo as mesmas, bem como processo de estabilização de polìmero orgánico ou material de registro
url https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-02-06T23%3A05%3A00IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-epo_EVB&rft_val_fmt=info:ofi/fmt:kev:mtx:patent&rft.genre=patent&rft.au=ROBERT%20EDWARD%20DETLEFSEN&rft.date=2011-03-09&rft_id=info:doi/&rft_dat=%3Cepo_EVB%3EBR0000666B1%3C/epo_EVB%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true