PROCEDE DE PREPARATION DE TRIFLUOROMETHYLPHENOLS
A process for preparing a trifluoromethylphenol and trifluoromethylphenyl benzyl ether is described. It comprises heating a trifluoromethylhalobenzene with a sodium benzylate to form a trifluoromethylphenyl benzyl ether of the formulawherein R and R1 when taken individually are C,-C3 alkyl, methoxy...
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creator | P. PRANC B.B. MOLLOY E.R. LAVAGNINO |
description | A process for preparing a trifluoromethylphenol and trifluoromethylphenyl benzyl ether is described. It comprises heating a trifluoromethylhalobenzene with a sodium benzylate to form a trifluoromethylphenyl benzyl ether of the formulawherein R and R1 when taken individually are C,-C3 alkyl, methoxy or nitro and when taken together and occupying adjacent carbon atoms in the phenyl ring, methylenedioxy, and n and m taken individually are 0 or 1, and optionally hydrogenolysing the trifluoromethylphenyl benzyl ether to give the corresponding ether. The trifluoromethylphenyl benzyl ethers are new compounds. |
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It comprises heating a trifluoromethylhalobenzene with a sodium benzylate to form a trifluoromethylphenyl benzyl ether of the formulawherein R and R1 when taken individually are C,-C3 alkyl, methoxy or nitro and when taken together and occupying adjacent carbon atoms in the phenyl ring, methylenedioxy, and n and m taken individually are 0 or 1, and optionally hydrogenolysing the trifluoromethylphenyl benzyl ether to give the corresponding ether. The trifluoromethylphenyl benzyl ethers are new compounds.</description><language>fre</language><subject>ACYCLIC OR CARBOCYCLIC COMPOUNDS ; CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY ; CHEMISTRY ; HETEROCYCLIC COMPOUNDS ; METALLURGY ; ORGANIC CHEMISTRY ; PERFORMING OPERATIONS ; PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL ; THEIR RELEVANT APPARATUS ; TRANSPORTING</subject><creationdate>1979</creationdate><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://worldwide.espacenet.com/publicationDetails/biblio?FT=D&date=19790919&DB=EPODOC&CC=BE&NR=874931A$$EHTML$$P50$$Gepo$$Hfree_for_read</linktohtml><link.rule.ids>230,308,780,885,25564,76547</link.rule.ids><linktorsrc>$$Uhttps://worldwide.espacenet.com/publicationDetails/biblio?FT=D&date=19790919&DB=EPODOC&CC=BE&NR=874931A$$EView_record_in_European_Patent_Office$$FView_record_in_$$GEuropean_Patent_Office$$Hfree_for_read</linktorsrc></links><search><creatorcontrib>P. PRANC</creatorcontrib><creatorcontrib>B.B. MOLLOY</creatorcontrib><creatorcontrib>E.R. LAVAGNINO</creatorcontrib><title>PROCEDE DE PREPARATION DE TRIFLUOROMETHYLPHENOLS</title><description>A process for preparing a trifluoromethylphenol and trifluoromethylphenyl benzyl ether is described. It comprises heating a trifluoromethylhalobenzene with a sodium benzylate to form a trifluoromethylphenyl benzyl ether of the formulawherein R and R1 when taken individually are C,-C3 alkyl, methoxy or nitro and when taken together and occupying adjacent carbon atoms in the phenyl ring, methylenedioxy, and n and m taken individually are 0 or 1, and optionally hydrogenolysing the trifluoromethylphenyl benzyl ether to give the corresponding ether. The trifluoromethylphenyl benzyl ethers are new compounds.</description><subject>ACYCLIC OR CARBOCYCLIC COMPOUNDS</subject><subject>CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY</subject><subject>CHEMISTRY</subject><subject>HETEROCYCLIC COMPOUNDS</subject><subject>METALLURGY</subject><subject>ORGANIC CHEMISTRY</subject><subject>PERFORMING OPERATIONS</subject><subject>PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL</subject><subject>THEIR RELEVANT APPARATUS</subject><subject>TRANSPORTING</subject><fulltext>true</fulltext><rsrctype>patent</rsrctype><creationdate>1979</creationdate><recordtype>patent</recordtype><sourceid>EVB</sourceid><recordid>eNrjZDAICPJ3dnVxVQCigCDXAMcgxxBPfz8QNyTI080n1D_I39c1xCPSJ8DD1c_fJ5iHgTUtMac4lRdKczPIubmGOHvophbkx6cWFyQmp-allsQ7uVqYm1gaGzoaE1QAAHDEJWg</recordid><startdate>19790919</startdate><enddate>19790919</enddate><creator>P. PRANC</creator><creator>B.B. MOLLOY</creator><creator>E.R. 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LAVAGNINO</creatorcontrib><collection>esp@cenet</collection></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext_linktorsrc</fulltext></delivery><addata><au>P. PRANC</au><au>B.B. MOLLOY</au><au>E.R. LAVAGNINO</au><format>patent</format><genre>patent</genre><ristype>GEN</ristype><title>PROCEDE DE PREPARATION DE TRIFLUOROMETHYLPHENOLS</title><date>1979-09-19</date><risdate>1979</risdate><abstract>A process for preparing a trifluoromethylphenol and trifluoromethylphenyl benzyl ether is described. It comprises heating a trifluoromethylhalobenzene with a sodium benzylate to form a trifluoromethylphenyl benzyl ether of the formulawherein R and R1 when taken individually are C,-C3 alkyl, methoxy or nitro and when taken together and occupying adjacent carbon atoms in the phenyl ring, methylenedioxy, and n and m taken individually are 0 or 1, and optionally hydrogenolysing the trifluoromethylphenyl benzyl ether to give the corresponding ether. The trifluoromethylphenyl benzyl ethers are new compounds.</abstract><oa>free_for_read</oa></addata></record> |
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subjects | ACYCLIC OR CARBOCYCLIC COMPOUNDS CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY CHEMISTRY HETEROCYCLIC COMPOUNDS METALLURGY ORGANIC CHEMISTRY PERFORMING OPERATIONS PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL THEIR RELEVANT APPARATUS TRANSPORTING |
title | PROCEDE DE PREPARATION DE TRIFLUOROMETHYLPHENOLS |
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